Prof. Sawamura / Papers

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Prof. Masaya Sawamura (Original papers/Reviews/ Environment and Safety)

Original papers
197.
Boron-Catalyzed α-Amination of Carboxylic Acids
Morisawa, T.; Sawamura, M.; Shimizu, Y.
Org. Lett. 2019, in press.
DOI: 10.1021/acs.orglett.9b02769

196.
Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor
Zhang, D.; Iwai, T.; Sawamura, M.
Org. Lett. 2019, in press.
DOI: 10.1021/acs.orglett.9b01989

195.
Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines.
Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M.
J. Am. Chem. Soc. 2019, 141, 7261–7265.
DOI: 10.1021/jacs.9b02751


 

194.
Iridium-catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds
Reyes, R. L.; Iwai, T.; Maeda, S.; Sawamura, M.
J. Am. Chem. Soc. 2019, 141, 6817–6821.
DOI: 10.1021/jacs.9b01952

 

193.
Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes
Ueda, Y.; Iwai, T.; Sawamura, M
Chem. Eur. J. 2019, 25, 9410–9414.
DOI: 10.1002/chem.201900822.

192.
Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand
Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M.
Adv. Synth. Catal. 2019, 361, 2250–2254.
DOI: 10.1002/adsc.201801713

191.
Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M.
Org. Lett. 2019, 21, 1717–1721.
DOI:10.1021/acs.orglett.9b00276

190.
A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides
Arashima, J.; Iwai, T.; Sawamura, M.
Chem. Asian J. 2019, 14, 411–415.
DOI: 10.1002/asia.201801651

189.
P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization
Iwai, T.; Shibaike, M.; Sawamura, M.
Chem. Lett. 2018, 47, 1162–1164.
DOI: 10.1246/cl.180501

188.
Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines
Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M.
Angew. Chem. Int. Ed. 2018, 57, 9465–9469.
DOI: 10.1002/anie.201802821

187.
Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand
Konishi, S.; Iwai, T.; Sawamura, M.
Organometallics 2018, 37, 1876–1883.
DOI: 10.1021/acs.organomet.8b00113
186.
Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2018, 20, 1861–1865.
DOI: 10.1021/acs.orglett.8b00390
185.
Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of  a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
Chem. Sci. 2018, 9, 3484–3493.
DOI: 10.1039/C8SC00527C
184.
Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M.
Chem. Lett. 2018, 47, 632–635.
DOI: 10.1246/cl.180147

183.
Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
Yasuda, Y.; Ohmiya, H.; Sawamura, M.
Synthesis 2018, 50, 2235–2246.
DOI: 10.1055/s-0036-1591548

182.
Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted g-Borylallylboranes
Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2018, 57, 3196–3199.
DOI: 10.1002/anie.201712351

181.
Nickel-Catalyzed Amination of Aryl Fluorides with Primary Amines
Harada, T.; Ueda, Y.; Iwai, T.; Sawamura, M.
Chem. Commun. 2018, 54, 1718–1721.
DOI: 10.1039/C7CC08181B
180.
Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition
Iwai, T.; Ueno, M.; Okochi, H.; Sawamura, M.
Adv. Synth. Catal. 2018, 360, 670–675.
DOI: 10.1002/adsc.201701193
179.
Enantioselective Rh- or Ir-Catalyzed Directed C(sp3)–H Borylation with Phosphoramidite Chiral Ligands
Reyes, R. L.; Harada, T.; Taniguchi, T.; Monde, K.; Iwai, T.; Sawamura, M.
Chem. Lett. 2017, 46, 1747–1750.
DOI: 10.1246/cl.170853


178.
Polystyrene-Cross-Linking Ortho-Substituted Triphenylphosphines: Synthesis, Coordination Properties, and Application to Pd-Catalyzed Cross-Coupling of Aryl Chlorides
Iwai, T.; Asano, K.; Harada, T.; Sawamura, M.
Bull. Chem. Soc. Jpn. 2017, 90, 943–949.
DOI: 10.1246/bcsj.20170141
177.
Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.
Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M.
Chem. Eur. J. 2017, 23, 8400–8404.
DOI: 10.1002/chem.201702070
 
176.
Exploring the Full Catalytic Cycle of Rhodium(I)–BINAP-Catalysed Isomerization of Allylic Amines: A Graph Theory Approach for Path Optimisation.
Yoshimura, T.; Maeda, S.; Taketsugu, T.; Sawamura, M.; Morokuma, K.; Mori, S.
Chem. Sci. 2017, 8, 4475–4488.
DOI: 10.1039/C7SC00401J
 
175.
Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides.
Hojoh, K.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2017, 139, 2184–2187.
DOI: 10.1021/jacs.6b12881
 
174.
A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis.
Iwai, T.; Harada, T.; Shimada, H.; Asano, K.; Sawamura, M.
ACS Catal. 2017, 7, 1681–1692.
DOI: 10.1021/acscatal.6b02988
173.
Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines.
Iwai, T.; Tanaka, R.; Sawamura, M.
Organometallics, 2016, 35, 3959-3969.
DOI: 10.1021/acs.organomet.6b00752

172.
Copper-Catalyzed Enantioselective Allyl–Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand.
Yasuda, Y.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed., 2016, 55, 10816-10820.
DOI: 10.1002/anie.201605125
171.
Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates.                                    
Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Org. Lett., 2016, 181706-1709.
DOI: 10.1021/acs.orglett.6b00677

170.
Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen.
Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Organometallics, 2016, 35, 1354-1357.
DOI: 10.1021/acs.organomet.6b00126
169.
Site-selective and Stereoselective C(sp3)–H Borylation of Alkyl Side Chains of 1,3-Azoles with a Silica-Supported Monophosphine-Ir Catalyst.
Murakami, R.; Iwai, T.; Sawamura, M.
Synlett., 2016, 27, 1187-1192.
DOI: 10.1055/s-0035-1561599

168.
Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles.
Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
Angew. Chem. Int. Ed., 2016, 55, 4777-4780.
DOI:10.1002/anie.201600619

167.
Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Beilstein J. Org. Chem., 2015, 11, 2444–2450.
DOI:10.3762/bjoc.11.265
166.
Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-coupling of Chloroarenes.
Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
ACS Catal., 2015, 5, 7254–7264.
DOI: 10.1021/acscatal.5b00904
165.
Synthesis of 1,1-Diborylalkenes through a Brønsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed., 2015, 54, 15859-15862.
DOI: 10.1002/anie.201509218


164.
Synthesis and Structures of a Chiral Phosphine-Phosphoric Acid Ligand and Its Rhodium(I) Complexes.
Iwai, T.; Akiyama, Y.; Tsunoda, K.; Sawamura, M.
Tetrahedron:Asymmetry, 2015, 26, 1245–1250.
DOI: 10.1016/j.tetasy.2015.09.016

163.
Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
Tetrahedron, 2015, 71, 6519–6533.
DOI:10.1016/j.tet.2015.05.048
162.
Copper-Catalyzed g-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
Yasuda, Y.; Nagao, K.; Shido, Y.;  Mori, S.; Ohmiya, H.; Sawamura, M.
Chem. Eur. J. 2015, 21, 9666-9670.
 DOI: 10.1002/chem.201501055
161.
Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes

Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2015, 17,  2039–2041.
DOI: 10.1021/acs.orglet.5b00758
160.
Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
Nagao, K.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2015, 17, 1304–1307.
DOI: 10.1021/acs.orglett.5b00305

 
159.
Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2014, 136, 13932–13939.
DOI: 10.1021/ja508433

 
158.
Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
Nagao, K.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2014, 136, 10605–10608.
DOI: 10.1021/ja506310v


157.
Stereoselective C–H Borylations of Cyclopropanes and Cyclobutanes with Silica-supported Monophosphane-Ir Catalysts.
Murakami, R.; Tsunoda,K.; Iwai, T.; Sawamura, M.
Chem. Eur. J. 2014, 20, 13127–13131.
DOI: 10.1002/chem.201404362
 
156.
Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. 
Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper).
DOI: 10.1002/anie.201402386.

155.
Silica-Supported Tripod Triarylphosphane: Application to Transition Metal Catalyzed C(sp3)–H Borylations.
Iwai, T.; Murakami, R.; Harada,T.; Kawamorita, S.; Sawamura, M.
Adv. Synth. Catal. 2014, 356, 1563–1570.
DOI: 10.1002/adsc.201301147
154.
Silica-supported Tripod Triarylphosphines: Application to Palladium Catalyzed Borylation of Chloroarenes.
Iwai, T.; Harada, T.; Tanaka, R.; Sawamura, M.
Chem. Lett. 2014, 43, 584–586.
DOI: 10.1246/cl.131161
153.
Tripod Immobilization of Triphenylphosphane on a Silica Gel Surface to Enable Selective Mono-P-ligation to Palladium: Application to Suzuki–Miyaura Cross-Coupling with Chloroarenes.
Iwai, T.; Tanaka, R.; Harada, T.; Sawamura, M.
Chem. Eur. J. 2014, 20, 1057–1065.
DOI: 10.1002/chem.201304081
152.
Site-selective C–H Borylation of Quinolines at the C-8 Position Catalyzed by a Silica-supported Phosphane-Iridium System.
Konishi, S.; Kawamorita, S.; Iwai, T.; Steel, P. G.; Marder, T. B.; Sawamura, M.
Chem. Asian J. 2014, 9, 434-438.
DOI: 10.1002/asia.201301423
151.
Friedel-Crafts Functionalization of Cyclopentadienyl Ligand in Bucky Metallocenes.
Matsuo, Y.; Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura ,E.
Dalton Trans. 2014, 43, 7407–7412.
DOI: 10.1039/C3DT52002A
 
150.
Threefold Cross-Linked Polystyrene-Triphenylphosphane Hybrids: Mono-P-Ligating Behaviors and Catalytic Applications for Aryl Chloride Cross-Coupling and C(sp3)–H Borylation.
Iwai, T.; Harada, T.; Hara, K.; Sawamura, M.
Angew. Chem. Int. Ed. 2013, 52, 12322–12326.
DOI: 10.1002/anie.201306769
149.
Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2013, 52, 11620–11623.
DOI: 10.1002/anie.201305973
148.
Cooperative Catalysis of Metal and O–H···O/sp3-C–H···O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H.; Mori, S.; Sawamura,M.
Chem. Eur. J. 2013, 19, 13547–13553.
DOI: 10.1002/chem.201301280
147.
Synthesis of a Chiral N-Heterocyclic Carbene Bearing a m-Terphenyl-Based Phosphate Moiety as an Anionic N-Substituent and Its Application to Copper-Catalyzed Enantioselective Boron Conjugate Addition.
Iwai, T.; Akiyama, Y.; Sawamura, M.
Tetrahedron: Asymmetry 2013, 24, 729–735.
DOI: 10.1016/j.tetasy.2013.05.013
146.
Copper-Catalyzed g-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes.
Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2013, 52, 5350–5354.
DOI: 10.1002/anie.201300785
145.
Synthesis of Primary and Secondary Alkylboronates through Site-Selective C(sp3)–H Activation with Silica-Supported Monophosphine–Ir Catalysts
Kawamorita, S.; Murakami, R; Iwai, T.; Sawamura, M.
J. Am. Chem. Soc. 2013, 135, 2947–2950.
DOI: 10.1021/ja3126239
144.
Construction of Eight-Membered Carbocycles via Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers.
Iwai, T.; Okochi, H.; Ito, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2013, 52, 4239-4242.
DOI: 10.1002/anie.201300265
143.
Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters.
Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M.
Adv. Synth. Cat. 2013, 355, 647–652.
DOI: 10.1002/adsc.201200949
142.
Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.
Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2012, 134, 18573–18576.
DOI: 10.1021/ja3093955
141.
Conjugate Reduction of a,b-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane–Copper Complex.
Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.;  Sawamura, M.
Adv. Synth. Catal. 2012, 354, 3440–3444.
DOI: 10.1002/adsc.201200555
140.
Rh-Catalyzed Borylation of N–Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand.
Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.;  Sawamura, M.
J. Am. Chem. Soc. 2012, 134, 12924–12927.
DOI: 10.1021/ja305694r
139.
Synthesis of Allenylsilanes through Copper-Catalyzed g-Selective Coupling between g-Silylated Propargylic Phosphates and Alkylboranes.
Yokobori, U.; Ohmiya, H.; Sawamura, M.
Organometallics 2012, 31, 7909-7913.
DOI: 10.1021/om300552f
138.
Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper–N-Heterocyclic Carbene Complex.
Yoshida, M.; Ohmiya, H.; Sawamura, M. 
J. Am. Chem. Soc. 2012, 134, 11896–11899.
DOI: 10.1021/ja304481a
137.
Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes. 
Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M. 
J. Am. Chem. Soc. 2012, 134, 8982–8987.
DOI: 10.1021/ja302520h
136.
Practical Procedure for Copper(I)-Catalyzed Allylic Boryl Substitution with Stoichiometric Alkoxide Base.  

Ito, H.; Miya, T.; Sawamura, M. 
Tetrahedron 2012, 68, 3423-3427.
DOI: 10.1016/j.tet.2011.08.081
135.
Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Allylic Phosphates and Alkylboranes.
Nagao, K.; Ohmiya, H.; Sawamura, M. 
Synthesis 2012, 44, 1535-1541.
DOI: 10.1055/s-0031-1290818
134.
Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation.
Makida, Y.; Ohmiya, H.; Sawamura, M. 
Angew. Chem. Int. Ed. 2012, 51, 4122-4127.
DOI: 10.1002/anie.201200809
133.
Synthesis of Conjugated Allenes through Copper-Catalyzed g-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.
Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M. 
Org. Lett. 2012, 14, 816-819.
DOI: 10.1021/ol2033465
132.
Copper(I)-Catalyzed Allylic Substitution of Silyl Nucleophiles through Si–Si Bond Activation.

Ito, H.; Horita, M.; Sawamura, M. 
Adv. Synth. Catal. 2012, 354, 813-817.
DOI: 10.1002/adsc.201100819
131.
Efficient Preparation of b-Branched g,d-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal.
Li, D.; Ohmiya, H.; Sawamura, M. 
Synthesis 201244, 1304-1307.
DOI: 10.1055/s-0031-1289712
130.
Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands.
Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M.
J. Am. Chem. Soc. 2011,133, 19310-19313.
DOI: 10.1021/ja208364a
129.
General Approach to Allenes through Copper-Catalyzed g-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes.
Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
Org. Lett. 2011, 13, 6312-6315.
DOI: 10.1021/ol202866h
128.
Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand.
Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M.
Angew. Chem. Int. Ed. (VIP) 2011,50, 8363-8366.
DOI: 10.1002/anie.201103224
127.
Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization.
Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M.
Beilstein. J. Org. Chem. 2011, 7, 951-959.
DOI: 10.3762/bjoc.7.106
126.
Mechanistic Insight into the Anomalous syn-Selectivity Observed During the Addition of Allenylboronates to Aromatic Aldehydes.
Sasaki, Y.; Sawamura, M.; Ito, H.
Chem. Lett. 2011, 40, 1044-1046.
DOI: 10.1246/cl.2011.1044 
125.
Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl a,b-Unsaturated Ketones.
Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M.
Chem. Lett. 2011, 40, 928-930.
DOI: 10.1246/cl.2011.928
124.
Copper-Catalyzed g-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals.
Li, D.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2011, 133, 5672-5675.
DOI: 10.1021/ja111645q
123.
Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes.
Ohmiya, H.; Tanabe, M.; Sawamura, M.
Org. Lett. 2011, 13, 1086-1088.
DOI: 10.1021/ol103128x
122.
Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronate.
Sasaki, Y.; Horita, Y.; Zhong, C.; Sawamura, M.; Ito, H.
Angew. Chem. Int. Ed. 2011, 50, 2778-2782.
DOI: 10.1002/anie.201007182 
121.
Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl a,b-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes.
Ohmiya, H.; Yoshida, M.; Sawamura, M.
Org. Lett. 2011, 13, 482-485.
DOI: 10.1021/ol102819k
120.
Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids.
Makida, Y.; Ohmiya, H.; Sawamura, M.
Chem. Asian J.2011, 6, 410-414.
DOI: 10.1002/asia.201000721

119.
Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex.
Ito, H.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2010, 12, 4380-4383.
DOI: 10.1021/ol101860j
118.
Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex.
Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2010, 12, 3978-3981.
DOI: 10.1021/ol101493m
117.
Direct Enantio-convergent Transformation of Racemic Substrates without Racemization or Symmetrization.
Ito, H.; Kunii, S.; Sawamura, M.
Nature Chem. 2010, 2, 972-976.
DOI: 10.1038/nchem.801 
116.
Enantioselective Synthesis of trans-Aryl- and Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative.
Zhong, C.; Kuni, S.; Kosaka, Y.; Sawamura, M.; Ito, H.
J. Am. Chem. Soc. 2010, 132, 11140-11142.
DOI: 10.1021/ja103783p 
115.
Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes.
Ohmiya, H.; Yoshida, M.; Sawamura, M.
Synlett, 2010, 2136-2140.
DOI: 10.1055/s-0030-1258527
114.
Synthesis of a-Arylated Allylsilanes through Palladium-Catalyzed g-Selective Allyl-Aryl Coupling.
Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2010, 12, 3344-3347.
DOI: 10.1021/ol101114r
113.
Copper-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates
Ohmiya, H.; Yokokawa, N.; Sawamura, M.
Org. Lett. 2010, 12, 2438-2440.
DOI: 10.1021/ol100841y
 
112.
Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex.
Kawamorita, S.; Ohmiya, H.; Sawamura, M.
J. Org. Chem. 2010, 75, 3855-3858.
DOI: 10.1021/jo100352b 
111.
Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative.
Ito, H.; Toyoda, T.; Sawamura, M.
J. Am. Chem. Soc. 2010, 132, 5990-5992.
DOI: 10.1021/ja101793a 
110.
Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.
Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M.
Org. Lett. 2010, 12, 1796-1799.
DOI: 10.1021/ol100405k
109.
Copper-Catalyzed g-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
J. Am. Chem. Soc. 2010, 132, 2895-2897.
DOI: 10.1021/ja9109105
108.
Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantio-Enriched Cyclic Homoally- and Allylboronates.
Sasaki, Y.; Zhong, C.; Sawamura, M.; Ito, H.
J. Am. Chem. Soc. 2010, 132, 1226-1227.
DOI: 10.1021/ja909640b 
107.
Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids.
Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.
J. Am. Chem. Soc. 2010, 132, 879-889.
DOI: 10.1021/ja9092264
106.
Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes.
Ito, H.; Okura, T.; Matsuura, K.; Sawamura, M.
Angew. Chem. Int. Ed. 2010, 49, 560-563.
DOI: 10.1002/anie.200905993 
105.
General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate.
Ohmiya, H.; Ito, H.; Sawamura, M.
Org. Lett. 2009, 11, 5618-5620.
DOI: 10.1021/ol902339a
104.
The Synthesis of Allenes by Cu(I)-Catalyzed Regio- and Stereoselective Reduction of Propargylic Carbonates with Hydrosilanes.
Zhong, C.; Sasaki, Y.; Ito, H.; Sawamura, M.
Chem. Commun.2009, 5850-5852.
DOI: 10.1039/b910192f
103.
Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex.
Ito, H.; Saito, T.; Miyahara, T.; Zhong, C.; Sawamura, M.
Organometallics 2009, 28, 4829-4840.
DOI: 10.1021/om900445w
  
102.
Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents.
Ohmiya, H.; Moriya, T.; Sawamura, M.
Org. Lett. 2009, 11, 2145-2147.
DOI: 10.1021/ol9007712
101.
Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System.
Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
J. Am. Chem. Soc. 2009, 131, 5058-5059.
DOI: 10.1021/ja9008419
100.
Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids.
Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M.
J. Am. Chem. Soc. 2008, 130, 17276-17277.
DOI: 10.1021/ja808673n
99.
Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multi-Substituted Allenylboronates.
Ito, H.; Sasaki, Y.; Sawamura, M.
J. Am. Chem. Soc. 2008, 130, 15774-15775.
DOI: 10.1021/ja806602h 
98.
Cyclization of Non-Terminal Alkynic b-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand.
Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2008, 10, 5051-5054.
DOI: 10.1021/ol802079r
97.
Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes.
Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M.
Organometallics 2008, 27, 6495-6506.
DOI: 10.1021/om800683g
96.
Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
Org. Lett. 2008,10, 4697-4700.
DOI: 10.1021/ol801996r
95.
Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Catalyzed by Cu(I) Complexes with Wide Bite-Angle Chiral Bisphosphine Ligands: Optimization, Scope and Mechanistic Studies
Asano, Y.; Ito, H.; Hara, K.; Sawamura, M.
Organometallics 2008, 27, 5984-5996. DOI: 10.1021/om800667c 
94.
Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M.
Organometallics 2008, 27, 5494-5503. DOI: 10.1021/om8005728 
93.
Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative
Ito, H.; Kosaka, Y.; Nonoyama, K.; Sasaki, Y.; Sawamura, M.
Angew. Chem., Int. Ed. 2008, 47, 7424-7427. DOI: 10.1002/anie.200802342 
92.
Conductance of Single 1,4-Benzenediamine Molecule Bridging between Au and Pt Electrodes
Kiguchi, M.; Miura, S.; Takahashi, T.; Hara, K.; Sawamura, M.; Murakoshi, K.
J. Phys. Chem. C 2008, 112, 13349-13352. DOI: 10.1021/jp806129u 
91.
Reversible Mechanochromic Luminescence of
Ito, H.; Saito, T.; Oshima, N.; Kitamura, N.; Ishizaki, S.; Hinatsu, Y.; Wakeshima, M.; Kato, M.; Tsuge, K.; Sawamura, M.
J. Am. Chem. Soc. 2008, 129, 10044-10045. DOI: 10.1021/ja8019356 
90.
Synthesis of Metal Fullerene Complexes by the Use of Fullerene Halides
Matsuo, Y.; Kuninobu, Y.; Muramatsu, A.; Sawamura, M.; Nakamura, E.
Organometallics 2008, 27, 3403-3409. DOI: 10.1021/om8001262 
89.
Self-Assembled Monolayer of Compact Phosphane with Alkanethiole Pendant: Remarkable Reusability and Substrate Selectivity in Rh Catalysis
Hara, K.; Akiyama, R.; Takakusagi, S.; Uosaki, K.; Yoshino, T.; Kagi, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2008, 47, 5627-5630. DOI: 10.1002/anie.200800884 
88.
Copper-Catalyzed Enantioselective Substitution of Allylic Carbonates with Diboron: An Efficient Route to Optically Active a-Chiral Allylboronates
Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M.
J. Am. Chem. Soc. 2007, 129, 14856-14857. DOI: 10.1021/ja076634o 
87.
Construction of Self-assembled Monolayer Terminated with N-Heterocyclic Carbene-Rhodium(I) Complex Moiety
Hara, K.; Iwahashi, K.; Takakusagi, S.; Uosaki, K.; Sawamura, M.
Surf. Sci. 2007, 601, 5127-5132. DOI :10.1016/j.susc.2007.04.158 
86.
Design and Synthesis of Isocyanide Ligands for Catalysis: Application to Rh-catalyzed Hydrosilylation of Ketones
Ito, H.; Kato, T.; Sawamura, M.
Chem. Asian J. 2007, 2, 1436-1446. DOI: 10.1002/asia.200700215 
85.
Functionalization of Silicon Surface with Catalytically Active Pd Complex and Application to the Aerobic Oxidation of Benzylic Alcohols
Hara, K.; Tayama, S.; Kano, H.; Masuda, T.; Takakusagi, S.; Kondo, T.; Uosaki, K.; Sawamura, M.
Chem. Commun. 2007, 4280-4282. DOI: 10.1039/b710820f 
84.
Synthesis and Structural Characterization of Tetranuclear Platinum(II) Metallamacrocycle Containing 1,3-Diisocyanoarene Ligands
Ito, H.; Maeda, T.; Sawamura, M.
Bull. Chem. Soc. Jpn. 2007, 80, 1981-1986. DOI: 10.1246/bcsj.80.1981 
83.
Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)-TRAP Complex
Asano, Y.; Hara, K.; Ito, H.; Sawamura, M.
Org. Lett. 2007, 9, 3901-3904. DOI: 10.1021/ol701534n 
82.
Conductance of Single 1,4-Disubstituted Benzene Molecules Anchored to Pt Electrodes
Kiguchi, M.; Miura, S.; Hara, K.; Sawamura, M.; Murakoshi, K.
App. Phys. Lett. 2007, 91, 053110. DOI: 10.1063/1.2757592 
81.
Monocoordinating, Compact Phosphane Immobilized on Silica Surface: Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones
Hamasaka, G.; Ochida, A.; Hara, K.; Sawamura, M.
Angew. Chem. Int. Ed. 2007, 46, 5381-5383. DOI: 10.1002/anie.200700947 
80.
Phosphorus Ligands with a Large Cavity: Synthesis of Triethynylphosphines with Bulky End Caps and Application to the Rhodium-Catalyzed Hydrosilylation of Ketones
Ochida, A.; Sawamura, M.
Chem. Asian J. 2007, 2, 609-618. DOI: 10.1002/asia.200700006
79.
Using Triethynylphosphine Ligands Bearing Bulky End Caps to Create a Holey Catalytic Environment: Application to Gold(I)-Catalyzed Alkyne Cyclizations
Ochida, A.; Ito, H.; Sawamura, M.
J. Am. Chem. Soc., 2006, 128, 16486-16487. DOI: 10.1021/ja066800c  
78.
Conductance of a Single Molecule Anchored by an Isocyanide Substituent to Gold Electrodes
Kiguchi, M.; Miura, S.; Hara, K.; Sawamura, M.; Murakoshi, K.
Appl. Phys. Lett. 2006, 89, 213104. DOI: 10.1063/1.2392816 
77.
Synthesis of New Bulky Isocyanide Ligands and Their Use for Rh-catalyzed Hydrosilylation
Ito, H.; Kato, T.; Sawamura, M.
Chem. Lett. 2006, 35, 1038-1039. DOI: 10.1246/cl.2006.1038 
76.
Ring Carbon Functionalization of N-Heterocyclic Carbene Ligand with Ester Groups: Electronic Effect of the Ester Groups on Coordination Properties
Hara, K.; Kanamori, Y.; Sawamura, M.
Bull. Chem. Soc. Jpn. 2006, 79, 1781-1786. DOI: 10.1246/bcsj.79.1781 
75.
Cyclic Diaminocarbene-Rhodium(I) Complex Tethered to Disulfide: Synthesis and Application to Gold Surface Modification
Hara, K.; Iwahashi, K.; Kanamori, Y.; Naito, S.; Takakusagi, S.; Uosaki, K.; Sawamura, M.
Chem. Lett. 2006, 35, 870-871. DOI: 10.1246/cl.2006.870 
74.
Electronically Tunable Compact Trialkylphosphines: SMAPs Bridged Bicylic Phosphines
Ochida, A.; Ito, S.; Miyahara, T.; Ito, H.; Sawamura, M.
Chem. Lett. 2006, 35, 294-295. DOI: 10.1246/cl.2006.294 
73.
Strong Counter Anion Effects on the Catalytic Activity of Cationic Silicon Lewis Acids in Mukaiyama Aldol and Diels-Alder Reactions
Hara, K.; Akiyama, R.; Sawamura, M.
Org. Lett. 2005, 7, 5621- 5623. DOI: 10.1021/ol052206g 
72.
Copper-Catalyzed g-Selective and Sterespecific Substitution Reaction of Allylic Carbonates with Diboron: Efficient Route to Chiral Allylboron Compounds
Ito, H.; Kawakami, C.; Sawamura, M.
J. Am. Chem. Soc. 2005, 127, 16034-16035. DOI: 10.1021/ja056099x 
71.
Gold(I)-Phosphine Catalyst for the Highly Chemoselective Dehydrogenative Silylation of Alcohols
Ito, H.; Takagi, K.; Miyahara, T.; Sawamura, M.
Org. Lett. 2005, 7, 3001-3004. DOI: 10.1021/ol050979z 
70.
Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)-Phosphine Complex
Ito, H.; Watanabe, A.; Sawamura, M.
Org. Lett. 2005, 7, 1869-1871. DOI: 10.1021/ol050559+ 
69.
Creation of Hoop- and Bowl-Shaped Benzenoid Systems by Selective Detraction of [60]Fullerene Conjugation. [10]Cyclophenacene and Fused Corannulene Derivatives
Matsuo, Y.; Tahara, K.; Sawamura, M.; Nakamura, E.
J. Am. Chem. Soc. 2004, 126, 8725-8734. 
68.
Nickel, Palladium and Platinum Complexes of 5- Cyclopentadienide C60R5 Ligands. Kinetic and Thermodynamic Stabilization Effects of C60Ph5 Ligand
Kuninobu, Y.; Matsuo, Y.; Toganoh, M.; Sawamura, M.; Nakamura, E.
Organometallics 2004, 23, 3259-3266. 
67.
Multilayer Vesicless and Vesicle Clusters Formed by the Fullerene-based Surfactant C60(CH3)5K
Burger, C.; Hao, J.; Ying, Q.; Isobe, H.; Sawamura, M.; Nakamura, E.; Chu, B.
J. Colloid Interface Sci. 2004, 275, 632-641. 
66.
Non-volatile Me3P-like P-Donor Ligand: Synthesis and Properties of 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Ochida, A.; Hara, K.; Ito, H.; Sawamura, M.
Org. Lett. 2003, 5, 2671-2674. DOI: 10.1021/ol0349099 
65.
Regioselective Synthesis of [60]Fullerene 5-Indenide R3C60- and 5-Cyclopentadienide R5C60-Bearing Different R Groups
Toganoh, M.; Suzuki, K.; Udagawa, R.; Hirai, A.; Sawamura, M.; Nakamura, E.
Org. Biomol. Chem. 2003, 1, 2604-2611. 
64.
Synthesis, Structure, and Aromaticity of a Hoop-Shaped Cyclic Benzenoid [10]Cyclophenacene
Nakamura, E.; Tahara, K.; Matsuo, Y.; Sawamura, M.
J. Am. Chem. Soc. 2003, 125, 2834-2835. 
63.
Stacking of Conical Molecules with Fullerene Apex into Polar Columns in Crystals and Liquid Crystals
Sawamura, M.; Kawai, K.; Matsuo, Y.; Kanie, K.; Kato, T.; Nakamura, E.
Nature 2002, 419, 702-705. 
62.
Hybrid of Ferrocene and Fullerene
Sawamura, M.; Kuninobu, Y.; Toganoh, M.; Matsuo, Y.; Yamanaka, M.; Nakamura, E.
J. Am. Chem. Soc. 2002, 124, 9354-9355. 
61.
Cu(I)-Mediated Regioselective Tri-addition of Grignard Reagent to [70]Fullerene. Synthesis of Indenyl-type Metal Ligand Embedded into Graphitic Structure
Sawamura, M.; Toganoh, M.; Iikura, H.; Matsuo, Y.; Hirai, A.; Nakamura, E.
J. Mat. Chem. 2002, 12, 2109-2115. 
60.
Regioselective Penta-addition of 1-Alkenyl Copper Reagent to [60]Fullerene. Synthesis of Penta-alkenyl FCp Ligand
Sawamura, M.; Nagahama, N.; Toganoh, M.; Nakamura, E.
J. Organomet. Chem. 2002, 652, 31-35. 
59.
Epitaxial Growth and Electronic Structure of a C60 Derivative Prepared by Solution Spray Technique
Shimada, T.; H., N.; Ueno, K.; Koma, A.; Kuninobu, Y.; Sawamura, M.; Nakamura, E.
J. Appl. Phys. 2001, 90, 209-212. 
58.
Spherical Bilayer Vesicles of Fullerene-Based Surfactants in Water: A Laser Light Scattering Study
Zhou, S.-Q.; Burger, C.; Chu, B.; Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U. E.; Isobe, H.; Nakamura, E.
Science
2001, 291, 1944. 
57.
Palladium-Catalysed Asymmetric [4+2] Cycloaddition of Vinylallene with 1,3-Diene
Murakami, M.; Minamida, R.; Itami, K.; Sawamura, M.; Ito, Y.
Chem. Commun.
2000, 2293-2294.
56.
Functionalized Fullerene as a New Artificial Vector for Transfection
Nakamura, E.; Isobe, H.; Tomita, N.; Sawamura, M.; Jinno, S.; Okayama, H.
Angew. Chem. Int. Ed. Engl. 2000, 39, 4254-4257.
55.
Half-Sandwich Metallocene Embedded in a Spherically Extended -Conjugate System. Synthesis, Structure, and Electrochemistry of Rh(5-C60Me5)(CO)2
Sawamura, M.; Kuninobu, Y.; Nakamura, E.
J. Am. Chem. Soc. 2000, 122, 12407-12408.
54.
Pentaorgano[60]fullerene R5C60-. A Water Soluble Hydrocarbon Anion
Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U., E.; Isobe, H.; Nakamura, E.; Zhou, S.-Q.; Chu, B.
Chem. Lett.
2000, 1098-1099.
53.
Catalytic Asymmetric Hydrogenation of -Acetamidoacrylates Using TRAP Trans-Chelating Chiral Diphosphine Ligands: Remarkable Effects of Ligand P-substituent and Hydrogen Pressure on Enantioselectivity
Kuwano, R.; Sawamura, M.; Ito, Y.
Bull. Chem. Soc. Jpn. 2000, 73, 2571-2578.
52.
Rhodium-Catalyzed Enantioselective Michael Addition of (1-Cyanoethyl)-phosphonate: Synthesis of Optically Active Phosphonic Acid Derivatives with Phosphorus-Substituted Quaternary Asymmetric Carbon Center
Sawamura, M.; Hamashima, H.; Ito, Y.
Bull. Chem. Soc. Jpn. 2000, 73, 2559-2562.
51.
Stepwise Synthesis of Fullerene Cyclopentadienide R5C60- and Indenide R3C60-. An Approach to Fully Unsymmetrically Substituted Derivatives
Sawamura, M.; Toganoh, M.; Suzuki, K.; Hirai, A.; Iikura, H.; Nakamura, E.
Org. Lett.
2000, 2, 1919-1921.
50.
A Cage with Fullerene End Caps
Isobe, H.; Ohbayashi, A.; Sawamura, M.; Nakamura, E.
J. Am. Chem. Soc. 2000, 122, 2669-2670.
49.
Synthesis of Pentamethyl-monohydro[60]fullerene C60Me5H and Its Use as Cyclopentadienyl-type Ligand Precursor
Sawamura, M.; Toganoh, M.; Kuninobu, Y.; Kato, S.; Nakamura, E.
Chem. Lett. 2000, 270-271.
48.
Asymmetric Hydrosilylation of Ketones Using Trans-Chelating Chiral Peralkyldiphosphine Ligands Bearing Primary Alkyl Substituents on Phosphorus Atoms
Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y.
Bull. Chem. Soc. Jpn.
2000, 73, 485-496.
47.
Single-Step Synthesis of Pentaaryl-monohydro[60]fullerenes through Five-Fold Addition of Organocopper Reagent to C60
Sawamura, M.; Iikura, H.; Ohama, T.; Hackler, U., E.; Nakamura, E.
J. Organometal. Chem. 2000, 599, 32-36.
46.
Optical Resolution of Chirrally Functionalized [60]Fullerene through Formation of Diastereomeric Methoxyphenyacetic Acid Esters
Isobe, H.; Sawamura, M.; Nakamura, E.
Fullerene Sci. Technol.
1999, 7, 519-528.
45.
Synthesis of p-Indenyl-type Fullerene Ligand and Its Metal Complexes via Quantative Trisarylation of C70
Sawamura, M.; Iikura, H.; Hirai, A.; Nakamura, E.
J. Am. Chem. Soc. 1998, 120, 8285-8286.
44.
Endohedral Homoconjugation in Cyclopentadiene Embedded in C60
Iikura, H.; Mori, S.; Sawamura, M.; Nakamura, E.
J. Org. Chem. 1997, 62, 7912-7913.
43.
Trans-Chelating Chiral Peralkyldiphosphine Ligands (R,R)-(S,S)-2,2"-Bis[1-(dialkylphosphino)ethyl]-1,1"-biferrocenes (AlkylTRAPs) and Their Transition Metal Complexes
Kuwano, R.; Sawamura, M.; Okuda, S.; Asai, T.; Ito, Y.; Redon, M.; Krief, A.
Bull. Chem. Soc. Jpn.
1997, 70, 2807-2822.
42.
Synthetic and Computational Studies on Symmetry-Defined Double Cycloaddition of a New Tris-Annulating Reagent to C60
Isobe, H.; Tokuyama, H.; Sawamura, M.; Nakamura, E.
J. Org. Chem. 1997, 62, 5034-5041.
41.
Sonochemical, Aerobic Conversion of Alkyl Halides into Alcohols Promoted by Trialkyltin Halide/NaBH3CN Catalytic System
Sawamura, M.; Kawaguchi, Y.; Sato, K.; Nakamura, E.
Chem. Lett.
1997, 705-706.
40.
Conversion of Alkyl Halides into Alcohols Using a Near Stoichiometric Amount of Molecular Oxygen: An Efficient Route to 18O- and 17O-Labeled Alcohols
Sawamura, M.; Kawaguchi, Y.; Nakamura, E.
Synlett
1997, 801-802.
39.
Enantioselective Allylation of Nitro Group-Stabilized Carbanions Catalyzed by Chiral Crown Ether Phosphine-Palladium Complexes
Sawamura, M.; Nakayama, Y.; Tang, W.-M.; Ito, Y.
J. Org. Chem.
1996, 61, 9090-9096.
38.
The First Pentahaptofullerene Metal Complexes
Sawamura, M.; Iikura, H.; Nakamura, E.
J. Am. Chem. Soc. 1996, 118, 12850-12851.
37.
Regio- and Diastereo-controlled Double Cycloaddition to [60]fullerene. One-Step Synthesis of Cs and C2 Chiral Organofullerenes with New Tris-Annulating Reagents
Nakamura, E.; Isobe, H.; Tokuyama, H.; Sawamura, M.
Chem. Commun.
1996, 1747-1748.
36.
An Enantioselective Two-Component Catalyst System: Rh-Pd-Catalyzed Allylic Alkylation of Activated Nitriles
Sawamura, M.; Sudoh, M.; Ito, Y.
J. Am. Chem. Soc.
1996, 118, 3309-3310.
35.
Enantioselective Cycloisomerization of 1,6-Enynes Catalyzed by Chiral Diphosphine-Palladium Complexes
Goeke, A.; Sawamura, M.; Kuwano, R.; Ito, Y.
Angew. Chem. Int. Ed. Engl.
1996, 35, 662-663.
34.
Catalytic Asymmetric Hydrogenation of Dimethy Itaconate with Trans-Chelating Chiral Diphosphine Ligands TRAP-Rhodium Complexes
Kuwano, R.; Sawamura, M.; Ito, Y.
Tetrahedron: Asymmetry
1995, 6, 2521-2526.
33.
Enantioselective Hydrogenation of -Disubstituted -Acetamidoacrylates Catalyzed by Rhodium Complexes with TRAP Trans-Chelating Chiral Phosphine Ligands
Sawamura, M.; Kuwano, R.; Ito, Y.
J. Am. Chem. Soc. 1995, 117, 9602-9603.
32.
Synthesis and Structures of Trans-Chelating Chiral Diphosphine Ligands Bearing Aromatic P-Substituents, (S,S)-(R,R)- and (R,R)-(S,S)-2,2"-Bis[1-(diarylphosphino)ethyl]-1,1"-biferrocenes (ArylTRAPs) and Their Transition Metal Complexes
Sawamura, M.; Hamashima, H.; Sugawara, M.; Kuwano, R.; Ito, Y.
Organometallics
1995, 14, 4549-4558.
31.
Asymmetric Michael Reaction of an -Cyano Weinreb Amide Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP
Sawamura, M.; Hamashima, H.; Shinoto, H.; Ito, Y.
Tetrahedron Lett.
1995, 36, 6479-6482.
30.
Synthesis and Cellular Characterization of the Detransformation Agent, (-)-Depudecin
Shimada, J.; Kwon, H. J.; Sawamura, M.; Schreiber, S. L.
Chem. Biol.
1995, 2, 517-525.
29.
Asymmetric Hydrosilylation of Symmetrical Diketones Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP
Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y.
Tetrahedron Lett.
1995, 36, 5239-5242.
28.
Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP
Sawamura, M.; Kuwano, R.; Shirai, J.; Ito, Y.
Synlett
1995, 347-348.
27.
Gold(I)-Catalyzed Asymmetric Aldol Reaction of an -Isocyano Weinreb Amide. An Efficient Synthesis of Optically Active -Hydroxy -Amino Aldehydes and Ketone
Sawamura, M.; Nakayama, Y.; Kato, T.; Ito, Y.
J. Org. Chem. 1995, 60, 1727-1732.
26.
Asymmetric Michael Reaction of -Cyano Carboxylates Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP
Sawamura, M.; Hamashima, H.; Ito, Y.
Tetrahedron
1994, 50, 4439-4454.
25.
Trans-Chelating Chiral Diphosphine Ligands Bearing Flexible P-Alkyl Substituents (AlkylTRAPs). An Application to Rhodium-Catalyzed Asymmetric Hydrosilylation of Simple Ketones
Sawamura, M.; Kuwano, R.; Ito, Y.
Angew. Chem. Int. Ed. Engl.
1994, 33, 111-113.
24.
Synthesis of Optically Active Ferrocene Analogues of Salicylic Acid Derivatives and Rhodium(II)-Catalyzed Asymmetric Intramolecular C-H Insertion of -Diazo -Keto Esters Using New Chiral Carboxylato Ligands
Sawamura, M.; Sasaki, H.; Nakata, T.; Ito, Y.
Bull. Chem. Soc. Jpn.
1993, 66, 2725-2729.
23.
Synthesis and Properties of a New Chiral Diphosphine Ligand Bearing a Cyclodextrin-Based Molecular Recognition Site and Its Palladium(II) Complex
Sawamura, M.; Kitayama, K.; Ito, Y.
Tetrahedron: Asymmetry
1993, 4, 1829-1832.
22.
Structure of (R)-1-[(S)-1',2-Bis(diphenylphosphino)ferrocenyl]ethyl Acetate.
Shawkataly, O. B.; Fun, H.-K.; Chinnakali, K.; Yip, B.-C.; Tooh, S.-G.; Ito, Y.; Sawamura, M.
Acta Cryst. C.
1993, C49, 1898-1900.
21.
Structure of 1-[(R)-1',2-Bis(diphenylphosphino)ferrocenyl]-(S)-N,N-dimethylethylamine
Shawkataly, O. B.; Khalil, H.; Fun, H.-K.; Chinnakali, K.; Tooh, S.-G.; Ito, Y.; Sawamura, M.
Acta Cryst. C.
1993, C49, 139-141.
20.
Catalytic Asymmetric Synthesis with Trans-Chelating Chiral Diphosphine Ligand TRAP: Rhodium-Catalyzed Asymmetric Michael Addition of α-Cyanocarboxylates
Sawamura, M.; Hamashima, H.; Ito, Y.
J. Am. Chem. Soc.
1992, 114, 8295-8296.
19.
Chiral Phosphine Ligands Functionalized by Crown Ethers: An Application to Palladium-Catalyzed Asymmetric Allylation of -Diketones
Sawamura, M.; Nagata, H.; Sakamoto, H.; Ito, Y.
J. Am. Chem. Soc.
1992, 114, 2586-2592.
18.
Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. 10: Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
Hayashi, T.; Sawamura, M.; Ito, Y.
Tetrahedron 1992, 48, 1999-2012.
17.
A Trans-Chelating Chiral Diphosphine Ligand: 2,2"-Bis[1-(diphenylphosphino)-ethyl]-1,1"-biferrocene and its Complexes with Platinum(II) and Palladium(II)
Sawamura, M.; Hamashima, H.; Ito, Y.
Tetrahedron: Asymmetry
1991, 2, 593-596.
16.
Synthesis of 2,2"-Bis(diphenylphosphino)-1,1"-biferrocene, a Planar Chiral Bisphosphine, and its Palladium(II) Complex
Sawamura, M.; Yamauchi, A.; Takegawa, T.; Ito, Y.
Chem. Commun.
1991, 874-875.
15.
The Asymmetric Aldol Reaction of Tosylmethyl Isocyanide and Aldehydes Catalyzed by Chiral Silver(I) Complexes
Sawamura, M.; Hamashima, H.; Ito, Y.
J. Org. Chem.
1990, 55, 5935-5936.
14.
Silver(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
Hayashi, T.; Uozumi, Y.; Yamazaki, A.; Sawamura, M.; Hamashima, H.; Ito, Y.
Tetrahedron Lett.
1991, 32, 2799-2802.
13.
NMR Studies of the Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
Sawamura, M.; Ito, Y.; Hayashi, T.
Tetrahedron Lett.
1990, 31, 2723-2726.
12.
Asymmetric Aldol Reaction of -Ketoesters with Isocyanoacetate and Isocyanoacetamide Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Ito, Y.; Sawamura, M.; Hamashima, H.; Emura, T.; Hayashi, T.
Tetrahedron Lett.
1989, 30, 4681-4684.
11.
Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Sawamura, M.; Ito, Y.; Hayashi, T.
Tetrahedron Lett.
1989, 30, 2247-2250.
10.
Asymmetric Aldol Reaction of -Isocyanoacetamides with Aldehydes Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Kobayashi, M.; Hayashi, T.
Tetrahedron Lett. 1988, 29, 6321-6324.
9.
Asymmetric Synthesis of -Hydroxy--alkylamino Acids by Asymmetric Aldol Reaction of -Isocyanocarboxylates Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes
Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.
Tetrahedron
1988, 44, 5253-5262.
8.
Asymmetric Synthesis of Threo- and Erythro-Sphingosines by Asymmetric Aldol Reaction of -Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Ito, Y.; Sawamura, M.; Hayashi, T.
Tetrahedron Lett. 1988, 29, 239-240.
7.
Asymmetric Aldol Reaction of -Isocyanocarboxylates with Paraformaldehyde Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Catalytic Asymmetric Synthesis of -Alkylserines
Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.
Tetrahedron Lett.
1988, 29, 235-238.
6.
Selective C-Alkylation of -Diketones
Shono, T.; Kashimura, S.; Sawamura, M.; Soejima, T.
J. Org. Chem. 1988, 53, 907-910.
5.
Asymmetric Aldol Reaction of an Isocyanoacetate with Aldehydes Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes
Ito, Y.; Sawamura, M.; Hayashi, T.
Tetrahedron Lett. 1987, 28, 6215-6218.
4.
Palladium-Catalyzed Allylation of -Isocyanocarboxylates
Ito, Y.; Sawamura, M.; Matsuoka, M.; Matsumoto, Y.; Hayashi, T.
Tetrahedron Lett.
1987, 28, 4849-4852.
3.
Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Ito, Y.; Sawamura, M.; Hayashi, T.
J. Am. Chem. Soc. 1986, 108, 6405-6406.
2.
Trimethylchlorosilane Induced Ring Opening of 2-Alkyloxazolidines to Enamine Derivatives
Ito, Y.; Sawamura, M.; Kominami, K.; Saegusa, T.
Tetrahedron Lett. 1985, 26, 5303-5306.
1.
New Systems for the Storage of Electricity Using Nitrile and Iodine as the Anodic Active Substances
Shono, T.; Sawamura, M.; Kashimura, S.
Chem. Commun.
1984, 1204-1205.
Reviews
31.
anti Boron Addition to Alkynes
Sawamura, M.; Ohmiya, H.
In Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, Fernández, E., Ed.; Thieme: Stuttgart,; Chapter 5, pp 105-130 (2019). DOI: 10.1055/sos-SD-230-00048
30.
固体表面を利用した配位子設計:活性サイトの孤立化に基づく高活性金属錯体触媒の開発
岩井智弘,澤村正也
触媒技術の動向と展望2019, 触媒学会(編), 113–123 (2019)
29.
配位子つくって30年
澤村正也
OM News, 12–17 (2018).
28.
ナノと有機合成(巻頭言)
澤村正也
有機合成化学協会誌, 74, 581 (2016).
27.
銅触媒の機能化に基づく高選択的合成反応の開発T
大宮寛久・ 澤村正也
月刊「化学工業」(特集「戦略的触媒開発と応用」),67, pp 361– 366 (2016).
26.
Transition-metal-catalyzed Site-selective C–H Functionalization of Quinolines beyond C2 Selectivity.
Iwai, T.; Sawamura, M.
ACS Catal. 2015, 5, 5031–5040. DOI 10.1021/acscatal.5b01143
25.
Transition Metal Catalysis with Hollow-shaped Triethynylphosphine Ligands.
Iwai, T.; Sawamura, M.
Bull. Chem. Soc. Jpn. 2014, 87, 1147–1160. (Award Account) DOI: 10.1246/bcsj.20140186
24.
Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes.
Ohmiya, H.; Sawamura, M.
 J. Synth. Org. Chem. Jpn.  2014, 72 (Special Issue in English), 1207–1217.
23.
High-Density Monolayer of Metal Complex: Preparation and Catalysis.
Hara, K.; Sawamura, M.; Fukuoka, A..
Chem. Rec. 2014, 14, 869–878. DOI: 10.1002/tcr.201402031
22.
Carbon–Boron and Carbon–Silicon Bond Formation.
M. Sawamura, H. Ito, In Copper-Catalyzed Asymmetric Synthesis;
A. Alexakis, N. Krause, S. Woodword, Ed.; Wiley-VCH: Weinheim, Chapter 6, pp 157–177, 2014.
21.
シリカ固定化かご型ホスフィンSilica-SMAPおよびSilica-TRIPに基づく有機合成触媒反応の開発.
澤村正也
和光純薬時報82, pp 2-6, 2014.
20.
不活性sp3-C–H結合の化学変換—触媒設計によるチャレンジ
川守田創一郎・澤村正也
化学,68, pp 72–73, 2013.
19.
Development of Heterogeneous Catalysts through Immobilization of Caged Phosphine Ligand SMAP
Sawamura, M.
Catalysts and Catalysis.
2010, 52, 249-254.
18.
γ位選択的ボリル化反応
澤村正也・伊藤肇
使える!有機合成反応241実践ガイド,丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著,化学同人,pp 314-315, 2010.
17.
γ位選択的アリル-アリール結成生成反応
澤村正也
使える!有機合成反応241実践ガイド,丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著,化学同人,pp 164-165, 2010.
16.
Air-Stable, Compact, Caged Trialkylphosphines (SMAPs): Synthesis, Properties and Applications to Homogeneous and Heterogeneous Catalysis
Sawamura, M.
J. Synth. Org. Chem., Jpn. 2009, 67, 1125-1135.
15.
Copper-Catalyzed Substitution of Allylic Carbonates with Diboron: A New Approach to Allylboronate Synthesis
Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M.
Pure Appl. Chem.
2008, 80, 1039-1045.
14.
Rhodium-Catalyzed Asymmetric Hydrogenation of Indoles.
Kuwano, R.; Sawamura, M. In Catalysts for Fine Chemical Synthesis; Regio- and Stereo- Controlled Oxidations and Reductions
Roberts, S. M., Whittall, J., Eds.; John Wiley & Sons: West Sussex, 2007; Vol. 5, p 73-86.
13.
Synthesis and Properties of SMAPs 1-Phospha-4-silabicyclo[2.2.2]octane Derivatives
Ochida, A.; Sawamura, M.
ARKIVOC 2006, 359-369.
12.
L-プロリン触媒を用いる不斉アルドール反応
澤村正也
有機合成のための触媒反応103,檜山為次郎・野崎京子編,東京化学同人,pp 90-91, 2004.
11.
遷移金属錯体を用いるアルドール反応
澤村正也
有機合成のための触媒反応103,檜山為次郎・野崎京子編,東京化学同人,pp 88-89, 2004.
10.
(Au)澤村正也・伊藤肇有機金属反応剤ハンドブック-3Liから83Biまで,玉尾皓平編著,化学同人,pp 243-245, 2003.
9.
有機フラーレンの形作る超分子構造-膜と液晶-
中村栄一・松尾豊・磯部寛之・澤村正也
未来材料, 2003, 3, 6-12.
8.
(I)ヒドリド錯体の触媒作用における不斉配位子加速効果
澤村正也
Organometallic News, 2002, 15.
7.
Chemistry of 5-Fullerene Metal Complexes.
E. Nakamura, M. Sawamura
Pure Appl. Chem.
, 2001, 73, 355-359.
6.
フラーレン類の反応-化学修飾と機能分子設計
中村栄一・澤村正也・磯部寛之
季刊化学総説「炭素第三の同素体フラーレンの化学」,日本化学会編,学会出版センターVol.43, chapter III-13, pp 165-171, 1999.
5.
Silver and Gold Reagents.
M. Sawamura, In Lewis Acid reagents: A Practical Approach
H. Yamamoto, Ed.; Oxford University Press.: Oxford, chapter 9, pp 169-176, 1999.
4.
Fullerene That Binds a Metal on the Pentagon.
E. Nakamura, M. Sawamura, H. Iikura, S. Mori
Proc. Electrochem. Soc. 97-14 (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials) 1997, 97-14, 298-308
3.
金-α-イソシアノカルボン酸類の不斉アルドール反応
澤村正也
季刊化学総説「金属反応剤を用いる不斉化学合成」,日本化学会編,学会出版センターVol. 19, chapter 11, pp 129-141, 1993.
2.
Asymmetric Aldol Reaction.
M. Sawamura, Y. Ito, In Catalytic Asymmetric SynthesisI. Ojima, Ed.; VCH, Publishers, Inc.: New York, Chapter 7, pp 367-388, 1993.
1.
Catalytic Asymmetric Synthesis by Means of Secondary Interaction between Chiral Ligands and Substrates.
M. Sawamura, Y. Ito
Chem. Rev.
, 1992, 92, 857-871.

Environment and Safety
5.
化学物質管理システム運用に関する課題整理と管理システム診断マップの開発
川上貴教・中村修・藤井邦彦・中山政勝・榊原洋子・澤村正也
環境と安全, 3, pp 175–185, 2016
4.
Manegement of Chemicals for Safety and Education in Laboratory
T. Kinoshita, K. Tonokura, I. Shibata, E. Yamada, S. Murata, M. Matsumoto, M. Sawamura, H. Nakagawa, K. Morimoto, A. Koyama
Journal of Environment and Safety
, 2015, 6, 81-84.
3.
北海道大学における動物実験実施者等の実験動物への感作状況
吉村彩・武蔵学・金子壮郎・大西俊介・折戸智恵子・川原由佳子・橋野聡・森松正美・今野哲・有川二郎・石井哲也・澤村正也・上田一郎
アレルギー, 63, pp 1132-11398, 2014
2.
かけがえのないもののために(巻頭言)
澤村 正也
北海道大学環境保全センター報, 16, 1, 2007
1.
北海道大学化学物質管理システムの運用について
江見清次郎・宮北貴志・澤村正也
北海道大学環境保全センター報, 15, pp 12-15, 2006