{"id":328,"date":"2014-03-20T00:52:26","date_gmt":"2014-03-19T15:52:26","guid":{"rendered":"http:\/\/barato.sci.hokudai.ac.jp\/~inorg\/?page_id=5"},"modified":"2017-12-28T10:39:07","modified_gmt":"2017-12-28T01:39:07","slug":"research-outline","status":"publish","type":"page","link":"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/research-outline\/","title":{"rendered":"\u7814\u7a76\u6982\u8981"},"content":{"rendered":"\u7121\u6a5f\u56fa\u4f53\u5316\u5b66\u306e\u5206\u91ce\u3067\u306f\u3001\u4e3b\u3068\u3057\u3066\u30013d\u8ecc\u9053\u306b\u4e0d\u5bfe\u96fb\u5b50\u3092\u6301\u3064\u9077\u79fb\u91d1\u5c5e\u3092\u542b\u3080\u5316\u5408\u7269\u306b\u3064\u3044\u3066\u3001\u53e4\u304f\u304b\u3089\u7814\u7a76\u304c\u306a\u3055\u308c\u3066\u304a\u308a\u3001\u6700\u8fd1\u3067\u306f\u3001\u9ad8\u6e29\u8d85\u4f1d\u5c0e\u3001\u5de8\u5927\u78c1\u6c17\u62b5\u6297\u3068\u3044\u3063\u305f\u3088\u308a\u30a8\u30ad\u30be\u30c1\u30c3\u30af\u306a\u7269\u6027\u3092\u793a\u3059\u3082\u306e\u306b\u4e3b\u773c\u304c\u304a\u304b\u308c\u3001\u7cbe\u529b\u7684\u306a\u7814\u7a76\u304c\u306a\u3055\u308c\u3066\u3044\u308b\u304c\u30014d\u3042\u308b\u3044\u306f5d\u9077\u79fb\u91d1\u5c5e\u3092\u542b\u3080\u5316\u5408\u7269\u306e\u7269\u6027\u306b\u3064\u3044\u3066\u306f\u3001\u307e\u3060\u3001\u672a\u89e3\u660e\u306a\u90e8\u5206\u304c\u591a\u3044\u3002\r\n\r\n&nbsp;\r\n\r\n\u305d\u3053\u3067\u3001\u6211\u3005\u306e\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u3067\u306f\u30014d(5d)\u9077\u79fb\u91d1\u5c5e\u3068\u3001\u5e0c\u571f\u985e\u5143\u7d20(4f\u96fb\u5b50\u7cfb)\u3092\u5171\u306b\u542b\u3080\u5316\u5408\u7269\u306b\u6ce8\u76ee\u3057\u3001\u3053\u308c\u3089\u306e\u7269\u8cea\u7fa4\u304c\u7e54\u308a\u6210\u3059\u591a\u7a2e\u591a\u69d8\u306a\u7269\u6027\u306b\u3064\u3044\u3066\u89e3\u660e\u3057\u3001\u3055\u3089\u306b\u3001\u65b0\u305f\u306a\u305d\u3057\u3066\u8208\u5473\u6df1\u3044\u7269\u6027\u3092\u793a\u3059\u7269\u8cea\u7fa4\u306e\u63a2\u7d22\u304a\u3088\u3073\u958b\u767a\u3059\u308b\u3053\u3068\u3092\u76ee\u7684\u3068\u3057\u3066\u3044\u308b\u3002\u3053\u308c\u307e\u3067\u3001\u3053\u306e\u3088\u3046\u306a\u8996\u70b9\u304b\u3089\u65b0\u898f\u8907\u5408\u9178\u5316\u7269\u3001\u30ab\u30eb\u30b3\u30b2\u30ca\u30a4\u30c9\u306e\u63a2\u7d22\u3001\u5408\u6210\u3001\u7269\u6027\u8a55\u4fa1\u3092\u884c\u3044\u3001\u767d\u91d1\u65cf\u5143\u7d20\u3092\u542b\u3080\u9178\u5316\u7269\u4e2d\u306b\u304a\u3044\u3066\u3001\u767d\u91d1\u65cf\u5143\u7d20\u306ed\u96fb\u5b50\u3068\u5e0c\u571f\u985e\u5143\u7d20\u306ef\u96fb\u5b50\u3068\u306e\u9593\u306b\u5354\u540c\u7684\u306a\u78c1\u6c17\u7684\u76f8\u4e92\u4f5c\u7528\u304c\u751f\u3058\u3001\u305d\u306e\u7d50\u679c\u3001\u8208\u5473\u3042\u308b\u69d8\u3005\u306a\u78c1\u6c17\u7684\u6319\u52d5\u3092\u793a\u3059\u3053\u3068\u3092\u898b\u3044\u51fa\u3057\u3066\u304d\u305f\u3002\r\n\r\n&nbsp;\r\n\r\n\u3053\u308c\u3089\u306e\u5316\u5408\u7269\u306b\u3064\u3044\u3066\u306f\u3001\u65e5\u672c\u539f\u5b50\u529b\u7814\u7a76\u6240\u306e\u539f\u5b50\u7089JRR-3\u3092\u7528\u3044\u3066\u4e2d\u6027\u5b50\u56de\u6298\u5b9f\u9a13\u3092\u884c\u3044\u3001\u78c1\u6c17\u69cb\u9020\u306e\u89e3\u6790\u3082\u884c\u3063\u3066\u3044\u308b\u3002\u307e\u305f\u3001\u3053\u308c\u3089\u306e\u7814\u7a76\u306f\u65e5\u672c\u539f\u5b50\u529b\u7814\u7a76\u6240\u6771\u6d77\u7814\u7a76\u6240\u3084\u6771\u5317\u5927\u5b66\u91d1\u5c5e\u6750\u6599\u7814\u7a76\u6240\u306a\u3069\u5916\u90e8\u7814\u7a76\u6a5f\u95a2\u3068\u306e\u5171\u540c\u7814\u7a76\u3068\u3044\u3046\u5f62\u3067\u3082\u5c55\u958b\u3057\u3066\u3044\u308b\u3002\r\n\r\n&nbsp;\r\n<p style=\"text-align: center;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-102 colorbox-328\" src=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/504d273632ccd674a04e9aadadfddd331.jpg\" alt=\"\u7814\u7a76\u6982\u8981\" width=\"460\" height=\"438\" srcset=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/504d273632ccd674a04e9aadadfddd331.jpg 460w, https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/504d273632ccd674a04e9aadadfddd331-300x285.jpg 300w, https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/504d273632ccd674a04e9aadadfddd331-340x323.jpg 340w, https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/504d273632ccd674a04e9aadadfddd331-223x212.jpg 223w, https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/504d273632ccd674a04e9aadadfddd331-124x118.jpg 124w\" sizes=\"(max-width: 460px) 100vw, 460px\" \/><\/p>\r\n\r\n<h2 style=\"text-align: left;\">\u7814\u7a76\u30c6\u30fc\u30de<\/h2>\r\n<ul>\r\n \t<li>\u9077\u79fb\u91d1\u5c5e\u304a\u3088\u3073\u5e0c\u571f\u985e\u5143\u7d20\u3092\u542b\u3080\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u9178\u5316\u7269\u306e\u96fb\u6c17\u4f1d\u5c0e\u6027\u304a\u3088\u3073\u78c1\u6027<\/li>\r\n \t<li>\u9077\u79fb\u91d1\u5c5e\u304a\u3088\u3073\u5e0c\u571f\u985e\u5143\u7d20\u3092\u542b\u3080\u786b\u5316\u7269\u306e\u96fb\u6c17\u4f1d\u5c0e\u6027\u304a\u3088\u3073\u78c1\u6027<\/li>\r\n \t<li>\u5e0c\u571f\u985e\u5143\u7d20\u3092\u542b\u3080\u8907\u5408\u9178\u5316\u7269\u4e2d\u306b\u304a\u3051\u308b\u96fb\u5b50\u72b6\u614b(EPR\u7684\u7814\u7a76)\u3001etc.<\/li>\r\n<\/ul>\r\n&nbsp;\r\n\r\n&nbsp;\r\n<h2>\u6700\u8fd1\u306e\u7814\u7a76\u3088\u308a<\/h2>\r\n<h3>\u30e1\u30ea\u30e9\u30a4\u30c8\u578b\u9178\u5316\u7269\u306e\u78c1\u6c17\u7684\u6027\u8cea<\/h3>\r\n<p style=\"text-align: center; margin-bottom: 10px;\"><img class=\"colorbox-328\"  loading=\"lazy\" decoding=\"async\" src=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/Sr2MGe2O71.gif\" alt=\"Sr2MGe2O7\" width=\"544\" height=\"274\" \/><\/p>\r\n\u30e1\u30ea\u30e9\u30a4\u30c8\u69cb\u9020\u3092\u6301\u3064\u9178\u5316\u7269A<sub>2<\/sub>MM&#8217;<sub>2<\/sub>O<sub>7<\/sub>\uff08A = Sr, Eu; M = \u9077\u79fb\u91d1\u5c5e; M&#8217; = Si, Ge\uff09\u306f\u3001\u9077\u79fb\u91d1\u5c5e\u306e\u4e8c\u6b21\u5143\u914d\u5217\u3068\u305d\u308c\u306b\u8d77\u56e0\u3059\u308b\u4f4e\u6b21\u5143\u78c1\u6027\u3092\u6301\u3064\u3002\u305d\u308c\u306b\u52a0\u3048\u3066A\u30b5\u30a4\u30c8\u306b4f\u96fb\u5b50\u3092\u6301\u30642\u4fa1\u306e\u30e6\u30fc\u30ed\u30d4\u30a6\u30e0\u3092\u5c0e\u5165\u3059\u308b\u3053\u3068\u3067\u3001\u3053\u306e\u7cfb\u3067\u521d\u3081\u3066\u30d5\u30a7\u30ea\u78c1\u6027\u3092\u793a\u3059\u5316\u5408\u7269Eu<sub>2<\/sub>MnSi<sub>2<\/sub>O<sub>7<\/sub>\u3092\u767a\u898b\u3057\u305f\u3002\u3055\u3089\u306b\u3001\u9077\u79fb\u91d1\u5c5e\u30b5\u30a4\u30c8\u9593\u306e\u78c1\u6c17\u7684\u76f8\u4e92\u4f5c\u7528\u306b\u95a2\u3059\u308b\u77e5\u898b\u3092\u5f97\u308b\u305f\u3081\u306b\u3001Sr<sub>2<\/sub>MSi<sub>2<\/sub>O<sub>7<\/sub>\uff08M = Mn, Co\uff09\u306e\u69d8\u3005\u306a\u7269\u6027\u6e2c\u5b9a\u3084\u4e2d\u6027\u5b50\u56de\u6298\u5b9f\u9a13\u3092\u884c\u3044\u3001\u9077\u79fb\u91d1\u5c5e\u30a4\u30aa\u30f3\u306e\u78c1\u6c17\u7570\u65b9\u6027\u3092\u53cd\u6620\u3057\u305f\u7279\u5fb4\u7684\u306a\u78c1\u6c17\u69cb\u9020\u3092\u6301\u3064\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\r\n\r\n&nbsp;\r\n\r\n&nbsp;\r\n<h3>\u65b0\u898f\u5c64\u72b6\u30aa\u30ad\u30b7\u30bb\u30ec\u30ca\u30a4\u30c9\u306e\u78c1\u6c17\u7684\u6027\u8cea<\/h3>\r\n<p style=\"text-align: center; margin-bottom: 10px;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-110 colorbox-328\" src=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/La2Fe2O3X21.gif\" alt=\"La2Fe2O3X2\" width=\"534\" height=\"281\" \/><\/p>\r\n\u9077\u79fb\u91d1\u5c5e\u3092\u542b\u3093\u3060\u65b0\u898f\u5c64\u72b6\u30aa\u30ad\u30b7\u30bb\u30ec\u30ca\u30a4\u30c9Ln<sub>2<\/sub>M<sub>2<\/sub>O<sub>3<\/sub>Se<sub>2<\/sub>\uff08Ln = \u30e9\u30f3\u30bf\u30ce\u30a4\u30c9; M = Fe, Co\uff09\u3092\u5408\u6210\u3057\u3001\u305d\u306e\u7d50\u6676\u69cb\u9020\u3092\u6c7a\u5b9a\u3059\u308b\u3068\u3068\u3082\u306b\u3001\u78c1\u6c17\u3001\u6bd4\u71b1\u3001\u4e2d\u6027\u5b50\u56de\u6298\u6e2c\u5b9a\u7b49\u3092\u884c\u3063\u305f\u3002\u3053\u308c\u3089\u306e\u5316\u5408\u7269\u7fa4\u3067\u306f\u3001\u9077\u79fb\u91d1\u5c5e\u306e\u78c1\u6c17\u30e2\u30fc\u30e1\u30f3\u30c8\u306f\u3044\u305a\u308c\u30822\u6b21\u5143\u7684\u306a\u53cd\u5f37\u78c1\u6027\u6319\u52d5\u3092\u793a\u3057\u305f\u3002\u307e\u305f\u3001\u4f4e\u6e29\u3067\u306f\u3001\u9577\u8ddd\u96e2\u78c1\u6c17\u79e9\u5e8f\u3092\u793a\u3059\u3053\u3068\u3092\u898b\u51fa\u3057\u3001\u305d\u306e\u78c1\u6c17\u69cb\u9020\u3092\u6c7a\u5b9a\u3057\u305f\u3002\u7279\u306b\u3001Co\u30a4\u30aa\u30f3\u306e\u5834\u5408\u306b\u306f\u3001\u6700\u8fd1\u63a5\u30a4\u30aa\u30f3\u9593\u306e\u78c1\u6c17\u30e2\u30fc\u30e1\u30f3\u30c8\u304c\u76f4\u4ea4\u3057\u305f\u7279\u7570\u306a\u69cb\u9020\u3092\u3068\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\r\n\r\n&nbsp;\r\n\r\n&nbsp;\r\n<h3>\u5e0c\u571f\u985e\u5143\u7d20\u3092\u542b\u30806H-\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u9178\u5316\u7269\u306e\u78c1\u6027<\/h3>\r\n<p style=\"text-align: center; margin-bottom: 10px;\"><img class=\"colorbox-328\"  loading=\"lazy\" decoding=\"async\" src=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/ba3lnru2o9_mag1.gif\" alt=\"ba3lnru2o9_mag\" width=\"232\" height=\"368\" \/><\/p>\r\n6H-\u30da\u30ed\u30d6\u30b9\u30ab\u30a4\u30c8\u578b\u30eb\u30c6\u30cb\u30a6\u30e0\u9178\u5316\u7269Ba<sub>3<\/sub>LnRu<sub>2<\/sub>O<sub>9<\/sub> (Ln = lanthanides)\u306e\u7d50\u6676\u69cb\u9020\u306f\u3001Ru\u30a4\u30aa\u30f3\u304c\u3064\u304f\u308b\u516b\u9762\u4f53\u304c\u9762\u5171\u6709\u3057\u3066Ru<sub>2<\/sub>O<sub>9<\/sub>\u30c0\u30a4\u30de\u30fc\u3092\u5f62\u6210\u3057\u3066\u3044\u308b\u3002\u3053\u308c\u3089\u306e\u5316\u5408\u7269\u306f\u5e0c\u571f\u985e\u5143\u7d20\u306b\u3088\u3063\u3066\u4f4e\u6e29\u3067\u69d8\u3005\u306a\u78c1\u6c17\u79e9\u5e8f\u3092\u793a\u3059\u3053\u3068\u3092\u898b\u51fa\u3057\u305f\u3002\r\n\r\n&nbsp;\r\n\r\n&nbsp;\r\n<h3>\u9077\u79fb\u91d1\u5c5e\u9178\u5316\u7269\u306b\u304a\u3051\u308b\u30af\u30e9\u30b9\u30bf\u30fc\u78c1\u6027<\/h3>\r\n<p style=\"text-align: center; margin-bottom: 10px;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-108 colorbox-328\" src=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/ba6la2fe4o15_magt1.gif\" alt=\"ba6la2fe4o15_magt\" width=\"314\" height=\"387\" 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style=\"text-align: center; margin-bottom: 10px;\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-109 colorbox-328\" src=\"https:\/\/wwwchem.sci.hokudai.ac.jp\/~inorg\/wp-content\/uploads\/2014\/03\/bi2rh3se21.gif\" alt=\"bi2rh3se2\" width=\"239\" height=\"262\" 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