無機化学研究室 北海道大学理学部化学科 理学研究院化学部門

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Notes: Lab members; Corresponding authors*

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2024

Article

  1. Acetonitrile-Based Highly Concentrated Electrolytes for High-Power Organic Sodium-Ion Batteries
    Yoshiyuki Gambe, Hiroaki Kobayashi,* Itaru Honma*
    ACS Appl. Mater. Interfaces, (accepted)
    DOI: 10.1021/acsami.4c16866

  2. Self-Reinforced Cathode Interface to Prolong the Cyclic Stability of Zn-MnO2 Batteries
    Xiangru Si, Ruijie Zhu,* Cheng Yang, Tanghao Shi, Peixing Du, Min Li, Yang Yang, Wei Cui, Huijun Yang,* Hiroaki Kobayashi, Masaki Matsui, Nan Sheng, Chunyu Zhu*
    Nano Lett., (2024) (in press).
    DOI: 10.1021/acs.nanolett.4c03390

  3. A Nanoparticle ZnMn2O4/Graphene Composite Cathode Doubles the Reversible Capacity in an Aqueous Zn-Ion Battery
    Yuto Katsuyama, Chie Ooka, Ruijie Zhu, Reona Iimura, Masaki Matsui, Richard B. Kaner, Itaru Honma, Hiroaki Kobayashi*
    Adv. Funct. Mater., 34, 2405551 (2024).
    DOI: 10.1002/adfm.202405551
    Press Release : リチウムイオン電池に置き換わる水系電池～次世代亜鉛イオン電池をナノテクノロジーで高エネルギー化～

  4. Chemical Compatibility of Solid-State Electrolytes with Hydroflux Cathode-Coating Process
    Kana Onoue, Tomoyuki Watanabe, Christopher C. John, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui*
    Electrochemistry, 92, 077002 (2024).
    DOI: 10.5796/electrochemistry.24-00046

  5. An Electrically Conductive CuMn2O4 Ultrananospinel Cathode for Room-Temperature Magnesium Rechargeable Batteries
    Reona Iimura, Hiroto Watanabe, Toshihiko Mandai, Itaru Honma, Hiroaki Imai, Hiroaki Kobayashi*
    ACS Appl. Energy Mater., 7, 5308–5314 (2024).
    DOI: 10.1021/acsaem.4c01211

  6. Effect of Vanadium Doping on α-KxMnO2 as a Positive Electrode Active Material for Rechargeable Magnesium Batteries
    Isaac Oda-Bayliss, Shunsuke Yagi,* Masao Kamiko, Kai Shimada, Hiroaki Kobayashi, Tetsu Ichitsubo
    J. Mater. Chem. A, 12, 17510–17519 (2024).
    DOI: 10.1039/D4TA00659C

  7. Synthesis of High-Sodium-Content Oxythiosilicate Glass Electrolytes Via Sodium Polysulfide
    Tomoya Otono, Akira Nasu, Taichi Asakura, Hiroe Kowada, Kota Motohashi, Atsushi Sakuda,* Masahiro Tatsumisago, Akitoshi Hayashi*
    Adv. Sustain. Syst., 8, 2400130 (2024).
    DOI: 10.1002/adsu.202400130

  8. Toward Cost-Effective High-Energy Lithium-Ion Battery Cathodes: Covalent Bond Formation Empowers Solid-State Oxygen Redox in Antifluorite-Type Lithium-Rich Iron Oxide
    Hiroaki Kobayashi,* Yuki Nakamura, Yumika Yokoyama, Itaru Honma, Masanobu Nakayama
    ACS Mater. Lett., 6, 2072–2076 (2024).
    DOI: 10.1021/acsmaterialslett.4c00268
    Press Release : 蓄電池材料の低コスト・高容量・寿命の共立に成功～鉄と酸素を有効に利用しリチウムイオン電池の資源リスク回避に期待～

  9. High-Sodium-Concentration Sodium Oxythioborosilicate Glass Synthesized via Ambient Pressure Method with Sodium Polysulfides
    Tomoya Otono, Akira Nasu, Taichi Asakura, Hiroe Kowada, Kota Motohashi, Masahiro Tatsumisago, Atsushi Sakuda,* Akitoshi Hayashi*
    Inorg. Chem., 63, 4589–4594 (2024).
    DOI: 10.1021/acs.inorgchem.3c04101

  10. Utilizing reactive polysulfides flux Na2Sx for the synthesis of sulfide solid electrolytes for all-solid-state sodium batteries
    Akira Nasu, Tomoya Otono, Takuma Takayanagi, Minako Deguchi, Atsushi Sakuda,* Masahiro Tatsumisago, Akitoshi Hayashi*
    Energy Stor. Mater., 67, 103307 (2024).
    DOI: 10.1016/j.ensm.2024.103307

  11. Heat Treatment of Mechanochemically Prepared Amorphous LiNi0.5Mn1.5O4–Li2SO4 as High-Voltage Positive-Electrode Material
    Neung Kwon, Akira Nasu, Hiroe Kowada, Kota Motohashi, Masahiro Tatsumisago, Atsushi Sakuda,* Akitoshi Hayashi
    ACS Appl. Energy Mater., 7, 1687–1692 (2024).
    DOI: 10.1021/acsaem.3c02698

  12. Ether molecule decomposition on MgM2O4 (M = Mn, Fe, Co) spinel surface: A first-principles study
    Tomoaki Kaneko,* Yui Fujihara, Toshihiko Mandai, Hiroaki Kobayashi, Keitaro Sodeyama*
    Electrochemistry, 92, 027003 (2024).
    DOI: 10.5796/electrochemistry.23-00087

  13. A 3.5 V-class organic sodium-ion battery using a croconate cathode
    Yoshiyuki Gambe, Hiroaki Kobayashi,* Itaru Honma*
    Chem. Eng. J., 479, 147760 (2024).
    DOI: 10.1016/j.cej.2023.147760

Review

  1. Development of Oxide-Type Cathode Materials towards Room-Temperature Magnesium Rechargeable Batteries
    Hiroaki Kobayashi*
    Electrochemistry, 92, 101004 (2024).
    DOI: 10.5796/electrochemistry.24-00068

  2. All-Solid-State Sodium-ion Batteries: A Leading Contender in the Next-Generation Battery Race
    Ruijie Zhu,* Zechen Li, Wei Zhang, Akira Nasu, Hiroaki Kobayashi, Masaki Matsui
    J. Electrochem., (2024) (in press).
    DOI: 10.61558/2993-074X.3476

Book and other publication

  1. Trigger of the Highly Resistive Layer Formation at the Cathode-Electrolyte Interface in All-Solid-State Lithium Batteries
    Masaki Matsui
    Interface Ionics, Springer
    ISBN: 978-981-97-6039-8

2023

Article

  1. Trigger of the Highly Resistive Layer Formation at the Cathode–Electrolyte Interface in All-Solid-State Lithium Batteries Using a Garnet-Type Lithium-Ion Conductor
    Kana Onoue, Akira Nasu, Kazuhiko Matsumoto, Rika Hagiwara, Hiroaki Kobayashi, Masaki Matsui*
    ACS Appl. Mater. Interfaces, 15, 52333–52341 (2023).
    DOI: 10.1021/acsami.3c07177

  2. Kinetically Enhanced Reaction Pathway to Form Highly Crystalline Layered LiCoO2 at Low Temperatures Below 300 °C
    Rannosuke Maeda, Ryo Nakanishi, Minoru Mizuhata, Masaki Matsui*
    Inorg. Chem., 62, 18830–18838 (2023).
    DOI: 10.1021/acs.inorgchem.3c01704
    Press Release : 蓄電池材料を省エネルギーで合成する手法の開発に成功〜リチウムイオン電池の製造時のコスト及びCO2排出量低減への貢献に期待～

  3. Mechanochemical Synthesis and Characterization of K2+xZr1–xYxCl6: Potassium-Ion-Conducting Chloride
    Yuya Okada, Akira Nasu, Takuya Kimura, Hirofumi Tsukasaki, Shigeo Mori, Hamdi Ben Yahia, Kota Motohashi, Atsushi Sakuda, Akitoshi Hayashi*
    Chem. Mater., 35, 7422–7429 (2023).
    DOI: 10.1021/acs.chemmater.3c00185

  4. Correlation among crystal and local structure, phase transition, and Li–ion conduction of solid electrolyte Li7La3Zr2O12
    Takanori Itoh,* Qiuyi Yuan, Chulho Song, Koji Ohara, Satoshi Hiroi, Toru Ishigaki, Masaki Matsui
    J. Solid State Chem., 327, 124274 (2023).
    DOI: 10.1016/j.jssc.2023.124274

  5. Hard Carbon–Sulfide Solid Electrolyte Interface in All-Solid-State Sodium Batteries
    Wataru Yoshida, Akira Nasu, Kota Motohashi, Masahiro Tatsumisago, Atsushi Sakuda,* Akitoshi Hayashi
    Electrochemistry, 91, 037009 (2023).
    DOI: 10.5796/electrochemistry.23-00009

Book and other publication

  1. 逆蛍石型リチウム鉄酸化物を利用した高容量正極の開発
    小林弘明
    EV用電池の安全性向上、高容量化と劣化抑制技術, 技術情報協会
    ISBN: 978-4-86104-992-7

  2. ナノ結晶酸化物の開発とマグネシウム二次電池正極応用
    小林弘明, 本間格
    次世代二次電池の開発動向, シーエムシー出版
    ISBN: 978-4-7813-1730-4

2022

Article

  1. Disproportionation Phenomenon at the Silica Interface of Propylene Carbonate–1,2-Dimethoxyethane Binary Solvent Containing Lithium Perchlorate
    Yoshimasa Suzuki, Nobuaki Kunikata, Motohiro Kasuya, Hideshi Maki, Masaki Matsui, Kazue Kurihara,* Minoru Mizuhata*
    J. Phys. Chem. C, 126, 11810–11821 (2022).
    DOI: 10.1021/acs.jpcc.2c02980

  2. The Effect of the Solvation Ability Towards Mg2+-ion on the Kinetic Behavior of Mg3Bi2 Electrode
    Fumihiro Sagane,* Masaki Matsui, Kiyoshi Kanamura
    J. Electrochem. Soc., 169, 030517 (2022).
    DOI: 10.1149/1945-7111/ac593a

Review

  1. Electrochemical In Situ/operando Spectroscopy and Microscopy Part 2: Battery Applications
    Masaki Matsui,* Yuki Orikasa, Tomoki Uchiyama, Naoya Nishi, Yuto Miyahara, Misae Otoyama, Tetsuya Tsuda
    Electrochemistry, 90, 102010 (2022).
    DOI: 10.5796/electrochemistry.22-66109

  2. Electrochemical In Situ/operando Spectroscopy and Microscopy Part 1: Fundamentals
    Masaki Matsui,* Yuki Orikasa, Tomoki Uchiyama, Naoya Nishi, Yuto Miyahara, Misae Otoyama, Tetsuya Tsuda
    Electrochemistry, 90, 102009 (2022).
    DOI: 10.5796/electrochemistry.22-66093

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