Publications
Original papers
- Roles of Divinylbenzene Co-Cross-Linker in a Threefold Cross-Linked Polystyrene-Phosphine Hybrid Monolith: Impact of Cross-Linking Degree on Catalytic Performance.
Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
Eur. J. Org. Chem., 2024, e202400974.
DOI:10.1002/ejoc.202400974
- Photoinduced Enantioselective Triplet Radical Reaction on Metal: Copper-Catalyzed Conjugate Addition of Acylsilanes to α,β-Unsaturated Ketones and Aldehydes.
Masuda, Y.; Ueda, Y.; Sueki, A.; Shimosato, J.; Nishimura, K.; Gao, M.; Hasegawa, J.; Sawamura, M.
Chem. Eur. J., 2024, Accepted Article.
DOI: 10.1002/chem.202402564
- Boron-Catalyzed Michael Reaction of Donor-Acceptor Carboxylic Acid Pairs Enabling Direct Synthesis of 1,5-Dicarboxylic Acids.
Yoshida, Y.; Sawamura, M.; Shimizu, Y.
Org. Lett., 2024, in press.
DOI: 10.1021/acs.orglett.4c01542
- Gold-Zinc Co-Catalyzed Alkynoate Hydrocarboxylation with N-Protected Amino Acids for Preparation of Storable Acylating Reagents and Racemization-Free Peptide Synthesis
Sakurada, A.; Sato, M.; Higashida, K.; Sawamura, M.
Adv. Synth. Catal., 2024, 366, 2507-2513.
DOI: 10.1002/adsc.202400286
- Photoinduced Platinum-catalyzed Reductive Allylation of α-Diketones with Allylic Carbonates.
Shimosato, J.; Sawamura, M.; Masuda, Y.
Org. Lett., 2024,26, 2023-2028.
DOI: 10.1021/acs.orglett.4c00091
- Photocatalytic Aldehyde C–H Bond Phosphonioethylation with Vinylphosphonium Bromide.
Mori, H.; Yoshida, M.; Sawamura, M.; Masuda, Y.
Asian J. Org. Chem., 2024, 13, e202300532.
DOI:10.1002/ajoc.202300532
- Photocatalytic 1,2-Phosphorus-Migrative [3+2] Cycloaddition of Tri(t-butyl)phosphine with Terminal Alkynes.
Masuda, Y.; Ikeshita, D.; Higashida, K.; Yoshida, M.; Ishida, N.; Murakami, M.; Sawamura, M.
J. Am. Chem. Soc., 2023,145, 19060–19066.
DOI:10.1021/jacs.3c06760
- Gold-Zinc Cooperative Catalysis for Seven-exo–dig Hydrocarboxylation of Internal Alkynes.
Sato, M.; Rawat, V. K.; Higashida, K.; Sawamura, M.
Chem. Eur. J., 2023, 29, e202301917.
DOI: 10.1002/chem.202301917
- Sheltering Mono-P-Ligated Metal Complexes in Porous Polystyrene Monolith: Effect of Aryl Pendant Stabilizers on Catalytic Durability.
Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
Chem. Eur. J., 2023,29, e202301847.
DOI:10.1002/chem.202301847
- Dimetal-Binding Scaffold 2-(Pyridin-2-yl)imidazo[1,5-b]pyridazine-7-ylidene: Synthesis of Trinuclear Heterobimetallic Complexes Involving Gold–Metal Interactions.
Kitabayashi, A.; Ono, Y.; Taketsugu, T.; Sawamura, M.; Higashida, K.
Chem. Eur. J., 2023, 29, Early View, e202301673(Hot Paper).
DOI:10.1002/chem.202301673
- Sequence-selective Three-component Reactions of Alkyltrifluoroborates with α,β-Unsaturated Carbonyl Compounds and Vinylphosphonium Salts.
Yoshida, M.; Sawamura, M.; Masuda, Y.
Org. Chem. Front., 2023,10, 3654-3661.
DOI: 10.1039/D3QO00631J
- Visible-Light-Induced Aminochlorination of Alkenes.
Mejri, E.; Higashida, K.; Kondo,Y.; Nawachi, A.; Morimoto, H.; Ohshima, T.;
Sawamura, M.; Shimizu, Y.
Org. Lett., 2023, 25,in press.
DOI: 10.1021/acs.orglett.3c01645
- Direct α-Trifluoromethylthiolation of Carboxylic Acids Enabled by Boron Catalysis.
Sun, K.; Huang, C.-Y.(Dennis) ; Sawamura, M.; Shimizu, Y.
Synlett, 2023, 34,2210–2214.
DOI:10.1055/a-2071-4465
- Nickel-Catalyzed Defluorophosphonylation of Aryl Fluorides.
You, Z.; Masuda, Y.; Iwai, T.; Higashida, K.; Sawamura, M.
J. Org. Chem., 2022, 87,14731-14737.
DOI: 10.1021/acs.joc.2c02048
- Photoinduced Alcoholic α-C–H Bond Anti-Markovnikov Addition to Vinylphosphonium Bromides Followed by Wittig Olefination: Two-step Protocol for α-C–H Allylic Alkylation of Alcohols.
Yoshida, M.; Sawamura, M.; Masuda, Y.
ChemCatChem., 2022, 14, e202200744(VIP).
DOI: 10.1002/cctc.202200744
- Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold-Zinc Two-Metal Catalysis for Intermolecular Addition of O-Nucleophiles to Non-activated Alkynes.
Rawat, V. K.; Higashida, K.; Sawamura, M.
ACS Catal., 2022, 12, 8325-8330.
DOI: 10.1021/acscatal.2c01701
- Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetic Acid Derivatives Enabled by Cooperative Participation of Classical and Nonclassical Hydrogen Bonds.
Sakai, S.; Fujioka, A.; Imai, K.; Uchiyama, K.; Shimizu, Y.;
Higashida, K.; Sawamura, M.
Adv. Synth. Catal., 2022, 364, 2333-2339.
DOI: 10.1002/adsc.202200327
- Insights into the Mechanism of Enantioselective Copper-Catalyzed Ring-Opening Allylic Alkylation of Cyclopropanols.
Kitabayashi, A.; Mizushima, S.; Higashida, K.;
Yasuda, Y.; Shimizu, Y.; Sawamura, M.
Adv. Synth. Catal., 2022, 364,1855-1862.
DOI: 10.1002/adsc.202200157
- Visible Light-Induced Reductive Allylation of Aldehydes by Umpolung Approach.
Tanaka, I.; Sawamura, M.; Shimizu, Y.
Org. Lett., 2022, 24, 520–524.
DOI: 10.1021/acs.orglett.1c03927
- Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes.
Ueda, Y.; Masuda, Y.; Iwai, T.; Imaeda, K.; Takeuchi, H.; Ueno, K.; Gao, M.; Hasegawa, J.; Sawamura, M.
J. Am. Chem. Soc., 2022, 144, 2218–2224.
DOI: 10.1021/jacs.1c11526
- Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands
Niizeki, R.; Higashida, K.; Mejri, E.; Sawamura, M.; Shimizu, Y.
Synlett, 2022,33, 288-292.
DOI: 10.1055/a-1673-9236
- Visible-Light-Driven α-Allylation of Carboxylic Acids
Sun, K.; Ueno, M.; Imaeda, K.; Ueno, K.; Sawamura, M.; Shimizu, Y.
ACS Catal., 2021,11, 9722-9728.
DOI: 10.1021/acscatal.1c02558
- Access to Indole-Fused Benzannulated Medium-Sized Rings through Gold(I)-Catalyzed Cascade Cyclization of Azido-Alkynes
Greiner, L. C.; Inuki, S.; Arichi, N.; Oishi, S.; Rikito, S.; Iwai, T.; Sawamura, M.; Hashmi, A. S. K.; Ohno, H.
Chem. Eur. J., 2021, 27, 12992-12997.
DOI: 10.1002/chem.202101824
- Nickel-catalyzed Homo-coupling of Aryl Ethers with Magnesium Anthracene Reductant
Rawat, V. K.; Higashida, K.; Sawamura, M.
Synthesis, 2021, 53, 3397-3403.
DOI: 10.1055/a-1509-5954
- A Hollow-Shaped Caged Triarylphosphine: Synthesis, Characterization and Applications to Gold(I)-Catalyzed 1,8-Enyne Cycloisomerization
Iwai,T.; Goto,Y.; You, Z.; Sawamura, M.
Chem. Lett., 2021, 50, 1236-1239.
DOI: 10.1246/cl.210176
- Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids
Rawat, V. K.; Higashida, K.; Sawamura, M.
Adv. Synth. Cat., 2021, 363, 1631–1637.
DOI: 10.1002/adsc.202001515
- Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms
You, Z.; Higashida, K.; Iwai,T.; Sawamura, M.
Angew. Chem. Int. Ed., 2021, 90, 5778–5782.
DOI: 10.1002/anie.202013544
- Synthesis of 2-Hydroxy-2-pyridinone Derivatives and Evaluation of Their Antioxidant/Anticancer ActivitiesHamama, W. S.; Ghaith, E. A.; Ibrahim, M. E.; Sawamura, M.; Zoorob, H. H.
ChemistrySelect, 2021, 6, 1430–1439.
DOI: 10.1002/slct.202004682
- Dumbbell-Shaped 2,2’-Bipyridines: Controlled Metal Monochelation and Application to Ni-Catalyzed Cross-CouplingsKim, Y.; Iwai T.; Fujii,S.; Ueno, K.; Sawamura, M.
Chem. Eur. J., 2021, 27, 2289–2293.
DOI: 10.1002/chem.202004053
- Convenient Synthesis of Binary and Fused Pyrazole Ring Systems: Accredited by Molecular Modeling and Biological Evaluation
Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S.ChemistrySelect. 2020, 5, 14917–14923.
DOI: 10.1002/slct.202004014
- Polystyrene-Cross-Linking Triphenylphosphine on Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic FlowMatsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
Ind. Eng. Chem. Res. 2020, 59, 15179–15187.
DOI: 10.1021/acs.iecr.0c02404
- Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions
Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.; Mori, S.; Sawamura, M.
Adv. Synth. Catal. 2020, 362, 4655–4661.
DOI: 10.1002/adsc.202000615
- Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine
Zhang, D.; Iwai, T.; Sawamura, M.
Org. Lett. 2020, 22, 5240–5245.
DOI: 10.1021/acs.orglett.0c01905
- Polystyrene‐Supported PPh3 in Macroporous Monolith: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C‐C Cross‐Coupling of Aryl Chlorides
Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
ChemCatChem 2020, 12, 4034–4037.
DOI: 10.1002/cctc.202000651
- Copper-Catalyzed Enantioselective Conjugate Reduction of α,β-Unsaturated Esters with Phenol-Carbene Chiral Ligand
Mimura, S.; Mizushima, S.; Shimizu, Y.; Sawamura, M.
Beilstein J. Org. Chem. 2020, 16, 537–543.
DOI: 10.3762/bjoc.16.50
- Boron-Catalyzed α-Amination of Carboxylic Acids
Morisawa, T.; Sawamura, M.; Shimizu, Y.
Org. Lett. 2019, 21, 7466–7469.
DOI: 10.1021/acs.orglett.9b02769
- Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor
Zhang, D.; Iwai, T.; Sawamura, M.
Org. Lett. 2019, 21, 5867–5872
DOI: 10.1021/acs.orglett.9b01989
- Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines.
Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M.
J. Am. Chem. Soc. 2019, 141, 7261–7265.
DOI: 10.1021/jacs.9b02751
- Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes
Ueda, Y.; Iwai, T.; Sawamura, M
Chem. Eur. J. 2019, 25, 9410–9414.
DOI: 10.1002/chem.201900822
- Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand
Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M.
Adv. Synth. Catal. 2019, 361, 2250–2254.
DOI: 10.1002/adsc.201801713
- Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M.
Org. Lett. 2019, 21, 1717–1721.
DOI:10.1021/acs.orglett.9b00276
- A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides
Arashima, J.; Iwai, T.; Sawamura, M.
Chem. Asian J. 2019, 14, 411–415.
DOI: 10.1002/asia.201801651
- P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization
Iwai, T.; Shibaike, M.; Sawamura, M.
Chem. Lett. 2018, 47, 1162–1164.
DOI: 10.1246/cl.180501
- Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines
Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M.
Angew. Chem. Int. Ed. 2018, 57, 9465–9469.
DOI: 10.1002/anie.201802821
- Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand
Konishi, S.; Iwai, T.; Sawamura, M.
Organometallics 2018, 37, 1876–1883.
DOI: 10.1021/acs.organomet.8b00113
- Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2018, 20, 1861–1865.
DOI: 10.1021/acs.orglett.8b00390
- Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
Chem. Sci. 2018, 9, 3484–3493.
DOI: 10.1039/C8SC00527C
- Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M.
Chem. Lett. 2018, 47, 632–635.
DOI: 10.1246/cl.180147
- Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
Yasuda, Y.; Ohmiya, H.; Sawamura, M.
Synthesis 2018, 50, 2235–2246.
DOI: 10.1055/s-0036-1591548
- Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted g-Borylallylboranes
Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2018, 57, 3196–3199.
DOI: 10.1002/anie.201712351
- Nickel-Catalyzed Amination of Aryl Fluorides with Primary Amines
Harada, T.; Ueda, Y.; Iwai, T.; Sawamura, M.
Chem. Commun. 2018, 54, 1718–1721.
DOI: 10.1039/C7CC08181B
- Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition
Iwai, T.; Ueno, M.; Okochi, H.; Sawamura, M.
Adv. Synth. Catal. 2018, 360, 670–675.
DOI: 10.1002/adsc.201701193
- Polystyrene-Cross-Linking Ortho-Substituted Triphenylphosphines: Synthesis, Coordination Properties, and Application to Pd-Catalyzed Cross-Coupling of Aryl Chlorides
Iwai, T.; Asano, K.; Harada, T.; Sawamura, M.Bull. Chem. Soc. Jpn. 2017, 90, 943–949.
DOI: 10.1246/bcsj.20170141
- Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.
Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M.
Chem. Eur. J. 2017, 23, 8400–8404.
DOI: 10.1002/chem.201702070
- Exploring the Full Catalytic Cycle of Rhodium(I)–BINAP-Catalysed Isomerization of Allylic Amines: A Graph Theory Approach for Path Optimisation.
Yoshimura, T.; Maeda, S.; Taketsugu, T.; Sawamura, M.; Morokuma, K.; Mori, S.
Chem. Sci. 2017, 8, 4475–4488.
DOI: 10.1039/C7SC00401J
- Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides.
Hojoh, K.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2017, 139, 2184–2187.
DOI: 10.1021/jacs.6b12881
- A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis.
Iwai, T.; Harada, T.; Shimada, H.; Asano, K.; Sawamura, M.
ACS Catal. 2017, 7, 1681–1692.
DOI: 10.1021/acscatal.6b02988
- Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines.
Iwai, T.; Tanaka, R.; Sawamura, M.
Organometallics, 2016, 35, 3959-3969.
DOI: 10.1021/acs.organomet.6b00752
- Copper-Catalyzed Enantioselective Allyl–Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand.
Yasuda, Y.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed., 2016, 55,10816-10820.
DOI: 10.1002/anie.201605125
- Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates.
Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Org. Lett., 2016, 18, 1706-1709.
DOI: 10.1021/acs.orglett.6b00677
- Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen.
Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Organometallics, 2016, 35, 1354-1357.
DOI: 10.1021/acs.organomet.6b00126
- Site-selective and Stereoselective C(sp3)–H Borylation of Alkyl Side Chains of 1,3-Azoles with a Silica-Supported Monophosphine-Ir Catalyst.
Murakami, R.; Iwai, T.; Sawamura, M.
Synlett., 2016, 27, 1187-1192.
DOI: 10.1055/s-0035-1561599
- Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles.
Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
Angew. Chem. Int. Ed., 2016, 55, 4777-4780.
DOI:10.1002/anie.201600619
- Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Beilstein J. Org. Chem., 2015, 11, 2444–2450.
DOI:10.3762/bjoc.11.265
- Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-coupling of Chloroarenes.
Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
ACS Catal., 2015, 5, 7254–7264.
DOI: 10.1021/acscatal.5b00904
- Synthesis of 1,1-Diborylalkenes through a Brønsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed., 2015, 54, 15859-15862.
DOI: 10.1002/anie.201509218
- Synthesis and Structures of a Chiral Phosphine-Phosphoric Acid Ligand and Its Rhodium(I) Complexes.
Iwai, T.; Akiyama, Y.; Tsunoda, K.; Sawamura, M.
Tetrahedron:Asymmetry, 2015, 26, 1245–1250.
DOI: 10.1016/j.tetasy.2015.09.016
- Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
Tetrahedron, 2015, 71, 6519–6533.
DOI:10.1016/j.tet.2015.05.048
- Copper-Catalyzed g-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M.
Chem. Eur. J. 2015, 21, 9666-9670.
DOI: 10.1002/chem.201501055
- Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes
Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2015, 17, 2039–2041.
DOI: 10.1021/acs.orglet.5b00758
- Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
Nagao, K.; Ohmiya, H.; Sawamura, M.
Org. Lett. 2015, 17, 1304–1307.
DOI: 10.1021/acs.orglett.5b00305
- Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2014, 136, 13932–13939.
DOI: 10.1021/ja508433
- Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
Nagao, K.; Ohmiya, H.; Sawamura, M.
J. Am. Chem. Soc. 2014, 136, 10605–10608.
DOI: 10.1021/ja506310v
- Stereoselective C–H Borylations of Cyclopropanes and Cyclobutanes with Silica-supported Monophosphane-Ir Catalysts.
Murakami, R.; Tsunoda,K.; Iwai, T.; Sawamura, M.
Chem. Eur. J. 2014, 20, 13127–13131.
DOI: 10.1002/chem.201404362
- Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper).
DOI: 10.1002/anie.201402386.
- Silica-Supported Tripod Triarylphosphane: Application to Transition Metal Catalyzed C(sp3)–H Borylations.
Iwai, T.; Murakami, R.; Harada,T.; Kawamorita, S.; Sawamura, M.
Adv. Synth. Catal. 2014, 356, 1563–1570.
DOI: 10.1002/adsc.201301147
- Silica-supported Tripod Triarylphosphines: Application to Palladium Catalyzed Borylation of Chloroarenes.
Iwai, T.; Harada, T.; Tanaka, R.; Sawamura, M.Chem. Lett. 2014, 43, 584–586.
DOI: 10.1246/cl.131161
- Tripod Immobilization of Triphenylphosphane on a Silica Gel Surface to Enable Selective Mono-P-ligation to Palladium: Application to Suzuki–Miyaura Cross-Coupling with Chloroarenes.
Iwai, T.; Tanaka, R.; Harada, T.; Sawamura, M.
Chem. Eur. J. 2014, 20, 1057–1065.
DOI: 10.1002/chem.201304081
- Site-selective C–H Borylation of Quinolines at the C-8 Position Catalyzed by a Silica-supported Phosphane-Iridium System.
Konishi, S.; Kawamorita, S.; Iwai, T.; Steel, P. G.; Marder, T. B.; Sawamura, M.
Chem. Asian J. 2014, 9, 434-438.
DOI: 10.1002/asia.201301423
- Friedel-Crafts Functionalization of Cyclopentadienyl Ligand in Bucky Metallocenes.
Matsuo, Y.; Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura ,E.
Dalton Trans. 2014, 43, 7407–7412.
DOI: 10.1039/C3DT52002A
- Threefold Cross-Linked Polystyrene-Triphenylphosphane Hybrids: Mono-P-Ligating Behaviors and Catalytic Applications for Aryl Chloride Cross-Coupling and C(sp3)–H Borylation.
Iwai, T.; Harada, T.; Hara, K.; Sawamura, M.
Angew. Chem. Int. Ed. 2013, 52, 12322–12326.
DOI: 10.1002/anie.201306769
- Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
Angew. Chem. Int. Ed. 2013, 52, 11620–11623.
DOI: 10.1002/anie.201305973
- Cooperative Catalysis of Metal and O–H···O/sp3-C–H···O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
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J. Am. Chem. Soc. 2003, 125, 2834-2835.
- Stacking of Conical Molecules with Fullerene Apex into Polar Columns in Crystals and Liquid Crystals
Sawamura, M.; Kawai, K.; Matsuo, Y.; Kanie, K.; Kato, T.; Nakamura, E.
Nature 2002, 419, 702-705.
- Hybrid of Ferrocene and Fullerene
Sawamura, M.; Kuninobu, Y.; Toganoh, M.; Matsuo, Y.; Yamanaka, M.; Nakamura, E.
J. Am. Chem. Soc. 2002, 124, 9354-9355.
- Cu(I)-Mediated Regioselective Tri-addition of Grignard Reagent to [70]Fullerene. Synthesis of Indenyl-type Metal Ligand Embedded into Graphitic Structure
Sawamura, M.; Toganoh, M.; Iikura, H.; Matsuo, Y.; Hirai, A.; Nakamura, E.
J. Mat. Chem. 2002, 12, 2109-2115.
- Regioselective Penta-addition of 1-Alkenyl Copper Reagent to [60]Fullerene. Synthesis of Penta-alkenyl FCp Ligand
Sawamura, M.; Nagahama, N.; Toganoh, M.; Nakamura, E.
J. Organomet. Chem. 2002, 652, 31-35.
- Epitaxial Growth and Electronic Structure of a C60 Derivative Prepared by Solution Spray Technique
Shimada, T.; H., N.; Ueno, K.; Koma, A.; Kuninobu, Y.; Sawamura, M.; Nakamura, E.J. Appl. Phys. 2001, 90, 209-212.
- Spherical Bilayer Vesicles of Fullerene-Based Surfactants in Water: A Laser Light Scattering Study
Zhou, S.-Q.; Burger, C.; Chu, B.; Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U. E.; Isobe, H.; Nakamura, E.
Science 2001, 291, 1944.
- Palladium-Catalysed Asymmetric [4+2] Cycloaddition of Vinylallene with 1,3-Diene
Murakami, M.; Minamida, R.; Itami, K.; Sawamura, M.; Ito, Y.
Chem. Commun. 2000, 2293-2294.
- Functionalized Fullerene as a New Artificial Vector for Transfection
Nakamura, E.; Isobe, H.; Tomita, N.; Sawamura, M.; Jinno, S.; Okayama, H.
Angew. Chem. Int. Ed. Engl. 2000, 39, 4254-4257.
- Half-Sandwich Metallocene Embedded in a Spherically Extended -Conjugate System. Synthesis, Structure, and Electrochemistry of Rh(5-C60Me5)(CO)2
Sawamura, M.; Kuninobu, Y.; Nakamura, E.
J. Am. Chem. Soc. 2000, 122, 12407-12408.
- Pentaorgano[60]fullerene R5C60–. A Water Soluble Hydrocarbon Anion
Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U., E.; Isobe, H.; Nakamura, E.; Zhou, S.-Q.; Chu, B.
Chem. Lett. 2000, 1098-1099.
- Catalytic Asymmetric Hydrogenation of -Acetamidoacrylates Using TRAP Trans-Chelating Chiral Diphosphine Ligands: Remarkable Effects of Ligand P-substituent and Hydrogen Pressure on Enantioselectivity
Kuwano, R.; Sawamura, M.; Ito, Y.
Bull. Chem. Soc. Jpn. 2000, 73, 2571-2578.
- Rhodium-Catalyzed Enantioselective Michael Addition of (1-Cyanoethyl)-phosphonate: Synthesis of Optically Active Phosphonic Acid Derivatives with Phosphorus-Substituted Quaternary Asymmetric Carbon Center
Sawamura, M.; Hamashima, H.; Ito, Y.
Bull. Chem. Soc. Jpn. 2000, 73, 2559-2562.
- Stepwise Synthesis of Fullerene Cyclopentadienide R5C60– and Indenide R3C60–. An Approach to Fully Unsymmetrically Substituted Derivatives
Sawamura, M.; Toganoh, M.; Suzuki, K.; Hirai, A.; Iikura, H.; Nakamura, E.
Org. Lett. 2000, 2, 1919-1921.
- A Cage with Fullerene End Caps
Isobe, H.; Ohbayashi, A.; Sawamura, M.; Nakamura, E.
J. Am. Chem. Soc. 2000, 122, 2669-2670.
- Synthesis of Pentamethyl-monohydro[60]fullerene C60Me5H and Its Use as Cyclopentadienyl-type Ligand Precursor
Sawamura, M.; Toganoh, M.; Kuninobu, Y.; Kato, S.; Nakamura, E.
Chem. Lett. 2000, 270-271.
- Asymmetric Hydrosilylation of Ketones Using Trans-Chelating Chiral Peralkyldiphosphine Ligands Bearing Primary Alkyl Substituents on Phosphorus Atoms
Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y.
Bull. Chem. Soc. Jpn. 2000, 73, 485-496.
- Single-Step Synthesis of Pentaaryl-monohydro[60]fullerenes through Five-Fold Addition of Organocopper Reagent to C60
Sawamura, M.; Iikura, H.; Ohama, T.; Hackler, U., E.; Nakamura, E.
J. Organometal. Chem. 2000, 599, 32-36.
- Optical Resolution of Chirrally Functionalized [60]Fullerene through Formation of Diastereomeric Methoxyphenyacetic Acid Esters
Isobe, H.; Sawamura, M.; Nakamura, E.
Fullerene Sci. Technol. 1999, 7, 519-528.
- Synthesis of p-Indenyl-type Fullerene Ligand and Its Metal Complexes via Quantative Trisarylation of C70
Sawamura, M.; Iikura, H.; Hirai, A.; Nakamura, E.
J. Am. Chem. Soc. 1998, 120, 8285-8286.
- Endohedral Homoconjugation in Cyclopentadiene Embedded in C60
Iikura, H.; Mori, S.; Sawamura, M.; Nakamura, E.
J. Org. Chem. 1997, 62, 7912-7913.
- Trans-Chelating Chiral Peralkyldiphosphine Ligands (R,R)-(S,S)-2,2″-Bis[1-(dialkylphosphino)ethyl]-1,1″-biferrocenes (AlkylTRAPs) and Their Transition Metal Complexes
Kuwano, R.; Sawamura, M.; Okuda, S.; Asai, T.; Ito, Y.; Redon, M.; Krief, A.
Bull. Chem. Soc. Jpn. 1997, 70, 2807-2822.
- Synthetic and Computational Studies on Symmetry-Defined Double Cycloaddition of a New Tris-Annulating Reagent to C60
Isobe, H.; Tokuyama, H.; Sawamura, M.; Nakamura, E.
J. Org. Chem. 1997, 62, 5034-5041.
- Sonochemical, Aerobic Conversion of Alkyl Halides into Alcohols Promoted by Trialkyltin Halide/NaBH3CN Catalytic System
Sawamura, M.; Kawaguchi, Y.; Sato, K.; Nakamura, E.
Chem. Lett. 1997, 705-706.
- Conversion of Alkyl Halides into Alcohols Using a Near Stoichiometric Amount of Molecular Oxygen: An Efficient Route to 18O- and 17O-Labeled Alcohols
Sawamura, M.; Kawaguchi, Y.; Nakamura, E.
Synlett 1997, 801-802.
- Enantioselective Allylation of Nitro Group-Stabilized Carbanions Catalyzed by Chiral Crown Ether Phosphine-Palladium Complexes
Sawamura, M.; Nakayama, Y.; Tang, W.-M.; Ito, Y.
J. Org. Chem. 1996, 61, 9090-9096.
- The First Pentahaptofullerene Metal Complexes
Sawamura, M.; Iikura, H.; Nakamura, E.
J. Am. Chem. Soc. 1996, 118, 12850-12851.
- Regio- and Diastereo-controlled Double Cycloaddition to [60]fullerene. One-Step Synthesis of Cs and C2 Chiral Organofullerenes with New Tris-Annulating Reagents
Nakamura, E.; Isobe, H.; Tokuyama, H.; Sawamura, M.
Chem. Commun. 1996, 1747-1748.
- An Enantioselective Two-Component Catalyst System: Rh-Pd-Catalyzed Allylic Alkylation of Activated Nitriles
Sawamura, M.; Sudoh, M.; Ito, Y.
J. Am. Chem. Soc. 1996, 118, 3309-3310.
- Enantioselective Cycloisomerization of 1,6-Enynes Catalyzed by Chiral Diphosphine-Palladium Complexes
Goeke, A.; Sawamura, M.; Kuwano, R.; Ito, Y.
Angew. Chem. Int. Ed. Engl. 1996, 35, 662-663.
- Catalytic Asymmetric Hydrogenation of Dimethy Itaconate with Trans-Chelating Chiral Diphosphine Ligands TRAP-Rhodium Complexes
Kuwano, R.; Sawamura, M.; Ito, Y.
Tetrahedron: Asymmetry 1995, 6, 2521-2526.
- Enantioselective Hydrogenation of -Disubstituted -Acetamidoacrylates Catalyzed by Rhodium Complexes with TRAP Trans-Chelating Chiral Phosphine Ligands
Sawamura, M.; Kuwano, R.; Ito, Y.
J. Am. Chem. Soc. 1995, 117, 9602-9603.
- Synthesis and Structures of Trans-Chelating Chiral Diphosphine Ligands Bearing Aromatic P-Substituents, (S,S)-(R,R)- and (R,R)-(S,S)-2,2″-Bis[1-(diarylphosphino)ethyl]-1,1″-biferrocenes (ArylTRAPs) and Their Transition Metal Complexes
Sawamura, M.; Hamashima, H.; Sugawara, M.; Kuwano, R.; Ito, Y.
Organometallics 1995, 14, 4549-4558.
- Asymmetric Michael Reaction of an -Cyano Weinreb Amide Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP
Sawamura, M.; Hamashima, H.; Shinoto, H.; Ito, Y.
Tetrahedron Lett. 1995, 36, 6479-6482.
- Synthesis and Cellular Characterization of the Detransformation Agent, (-)-Depudecin
Shimada, J.; Kwon, H. J.; Sawamura, M.; Schreiber, S. L.
Chem. Biol. 1995, 2, 517-525.
- Asymmetric Hydrosilylation of Symmetrical Diketones Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP
Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y.
Tetrahedron Lett. 1995, 36, 5239-5242.
- Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP
Sawamura, M.; Kuwano, R.; Shirai, J.; Ito, Y.
Synlett 1995, 347-348.
- Gold(I)-Catalyzed Asymmetric Aldol Reaction of an -Isocyano Weinreb Amide. An Efficient Synthesis of Optically Active -Hydroxy -Amino Aldehydes and Ketone
Sawamura, M.; Nakayama, Y.; Kato, T.; Ito, Y.
J. Org. Chem. 1995, 60, 1727-1732.
- Asymmetric Michael Reaction of -Cyano Carboxylates Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP
Sawamura, M.; Hamashima, H.; Ito, Y.
Tetrahedron 1994, 50, 4439-4454.
- Trans-Chelating Chiral Diphosphine Ligands Bearing Flexible P-Alkyl Substituents (AlkylTRAPs). An Application to Rhodium-Catalyzed Asymmetric Hydrosilylation of Simple Ketones
Sawamura, M.; Kuwano, R.; Ito, Y.
Angew. Chem. Int. Ed. Engl. 1994, 33, 111-113.
- Synthesis of Optically Active Ferrocene Analogues of Salicylic Acid Derivatives and Rhodium(II)-Catalyzed Asymmetric Intramolecular C-H Insertion of -Diazo -Keto Esters Using New Chiral Carboxylato Ligands
Sawamura, M.; Sasaki, H.; Nakata, T.; Ito, Y.
Bull. Chem. Soc. Jpn. 1993, 66, 2725-2729.
- Synthesis and Properties of a New Chiral Diphosphine Ligand Bearing a Cyclodextrin-Based Molecular Recognition Site and Its Palladium(II) Complex
Sawamura, M.; Kitayama, K.; Ito, Y.
Tetrahedron: Asymmetry 1993, 4, 1829-1832.
- Structure of (R)-1-[(S)-1′,2-Bis(diphenylphosphino)ferrocenyl]ethyl Acetate.
Shawkataly, O. B.; Fun, H.-K.; Chinnakali, K.; Yip, B.-C.; Tooh, S.-G.; Ito, Y.; Sawamura, M.
Acta Cryst. C. 1993, C49, 1898-1900.
- Structure of 1-[(R)-1′,2-Bis(diphenylphosphino)ferrocenyl]-(S)-N,N-dimethylethylamine
Shawkataly, O. B.; Khalil, H.; Fun, H.-K.; Chinnakali, K.; Tooh, S.-G.; Ito, Y.; Sawamura, M.
Acta Cryst. C. 1993, C49, 139-141.
- Catalytic Asymmetric Synthesis with Trans-Chelating Chiral Diphosphine Ligand TRAP: Rhodium-Catalyzed Asymmetric Michael Addition of α-Cyanocarboxylates
Sawamura, M.; Hamashima, H.; Ito, Y.
J. Am. Chem. Soc. 1992, 114, 8295-8296.
- Chiral Phosphine Ligands Functionalized by Crown Ethers: An Application to Palladium-Catalyzed Asymmetric Allylation of -Diketones
Sawamura, M.; Nagata, H.; Sakamoto, H.; Ito, Y.
J. Am. Chem. Soc. 1992, 114, 2586-2592.
- Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. 10: Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
Hayashi, T.; Sawamura, M.; Ito, Y.
Tetrahedron 1992, 48, 1999-2012.
- A Trans-Chelating Chiral Diphosphine Ligand: 2,2″-Bis[1-(diphenylphosphino)-ethyl]-1,1″-biferrocene and its Complexes with Platinum(II) and Palladium(II)
Sawamura, M.; Hamashima, H.; Ito, Y.
Tetrahedron: Asymmetry 1991, 2, 593-596.
- Synthesis of 2,2″-Bis(diphenylphosphino)-1,1″-biferrocene, a Planar Chiral Bisphosphine, and its Palladium(II) Complex
Sawamura, M.; Yamauchi, A.; Takegawa, T.; Ito, Y.
Chem. Commun. 1991, 874-875.
- The Asymmetric Aldol Reaction of Tosylmethyl Isocyanide and Aldehydes Catalyzed by Chiral Silver(I) Complexes
Sawamura, M.; Hamashima, H.; Ito, Y.
J. Org. Chem. 1990, 55, 5935-5936.
- Silver(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
Hayashi, T.; Uozumi, Y.; Yamazaki, A.; Sawamura, M.; Hamashima, H.; Ito, Y.
Tetrahedron Lett. 1991, 32, 2799-2802.
- NMR Studies of the Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
Sawamura, M.; Ito, Y.; Hayashi, T.
Tetrahedron Lett. 1990, 31, 2723-2726.
- Asymmetric Aldol Reaction of -Ketoesters with Isocyanoacetate and Isocyanoacetamide Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Ito, Y.; Sawamura, M.; Hamashima, H.; Emura, T.; Hayashi, T.
Tetrahedron Lett. 1989, 30, 4681-4684.
- Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Sawamura, M.; Ito, Y.; Hayashi, T.
Tetrahedron Lett. 1989, 30, 2247-2250.
- Asymmetric Aldol Reaction of -Isocyanoacetamides with Aldehydes Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Kobayashi, M.; Hayashi, T.
Tetrahedron Lett. 1988, 29, 6321-6324.
- Asymmetric Synthesis of -Hydroxy–alkylamino Acids by Asymmetric Aldol Reaction of -Isocyanocarboxylates Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes
Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.
Tetrahedron 1988, 44, 5253-5262.
- Asymmetric Synthesis of Threo– and Erythro-Sphingosines by Asymmetric Aldol Reaction of -Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Ito, Y.; Sawamura, M.; Hayashi, T.
Tetrahedron Lett. 1988, 29, 239-240.
- Asymmetric Aldol Reaction of -Isocyanocarboxylates with Paraformaldehyde Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Catalytic Asymmetric Synthesis of -Alkylserines
Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.
Tetrahedron Lett. 1988, 29, 235-238.
- Selective C-Alkylation of -Diketones
Shono, T.; Kashimura, S.; Sawamura, M.; Soejima, T.
J. Org. Chem. 1988, 53, 907-910.
- Asymmetric Aldol Reaction of an Isocyanoacetate with Aldehydes Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes
Ito, Y.; Sawamura, M.; Hayashi, T.
Tetrahedron Lett. 1987, 28, 6215-6218.
- Palladium-Catalyzed Allylation of -Isocyanocarboxylates
Ito, Y.; Sawamura, M.; Matsuoka, M.; Matsumoto, Y.; Hayashi, T.
Tetrahedron Lett. 1987, 28, 4849-4852.
- Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
Ito, Y.; Sawamura, M.; Hayashi, T.
J. Am. Chem. Soc. 1986, 108, 6405-6406.
- Trimethylchlorosilane Induced Ring Opening of 2-Alkyloxazolidines to Enamine Derivatives
Ito, Y.; Sawamura, M.; Kominami, K.; Saegusa, T.
Tetrahedron Lett. 1985, 26, 5303-5306.
- New Systems for the Storage of Electricity Using Nitrile and Iodine as the Anodic Active Substances
Shono, T.; Sawamura, M.; Kashimura, S.
Chem. Commun. 1984, 1204-1205.
Reviews
- Continuous-Flow Catalysis Using Phosphine-Metal Complex on Porous Polymers: Designing Ligands, Pores, and Reactors
Matsumoto, H.;Iwai, T.; Sawamura, M.; Miura, Y. ChemPlusChem, 2024, 89, accepted article, e202400039.
DOI: 10.1002/cplu.202400039
- アリル化合物
澤村正也
有機合成化学協会誌,2023, 81, 828.
- フェノール-カルベン不斉配位子とエナンチオ選択的銅触媒反応の開発
澤村正也
有機合成化学協会誌,2023, 81, 774–786.
- 金との出会い
澤村正也
ドラマチック有機合成化学-感動の瞬間100、有機合成化学協会編,化学同人,2023, pp 124–125
- Boron Catalysis in the Transformation of Carboxylic Acids and Carboxylic Acid Derivatives
Sawamura, M.; Shimizu, Y.
Eur. J. Org. Chem., 2023, 26, e202201249.
DOI: 10.1002/ejoc.202201249
- ポリスチレン架橋ホスフィンに基づく不均一系遷移金属触媒の開発とフロー反応システムへの応用
岩井智弘,三浦佳子,澤村正也
THE CHEMICAL TIMES, 2022, 263, 12–16.
- Copper-Catalyzed Reactions of Alkylboranes
Ohmiya, H.; Sawamura, M.
Bull. Chem. Soc. Jpn., 2021, 94, 197–203.
DOI: 10.1246/bcsj.20200283
- The Scope of 3-Acetyl-4-hydroxy-6-methyl-2H-pyran-2-one (DHA)
Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S.
Curr. Org. Chem., 2020, 24, 1459–1490.
DOI: 10.2174/1385272824999200622114328
- Construction of Medium-Sized Rings by Gold Catalysis
Reyes, R. L.; Iwai, T.; Sawamura, M.Chem. Rev., 2021, 121, 8926–8947.
DOI: 10.1021/acs.chemrev.0c00793
- Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin, 4-[[(1R)-2′-[(triisopropylsilyl)oxy][1,1′-binaphthalen]-2-yl]oxy]-, (11bR)-(9CI)Reyes, R. L.; Sawamura, M.
Electronic Encyclopedia of Reagents for Organic Synthesis, Rovis T., Ed.; Wiley.
http://onlinelibrary.wiley.com/doi/10.1002/047084289X.rn02326
- 5 anti Boron Addition to Alkynes
Sawamura, M.; Ohmiya, H.In Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, Fernández, E., Ed.; Thieme: Stuttgart,; Chapter 5, pp 105-130 (2019).
DOI: 10.1055/sos-SD-230-00048
- 固体表面を利用した配位子設計:活性サイトの孤立化に基づく高活性金属錯体触媒の開発
岩井智弘,澤村正也
触媒技術の動向と展望2019, 触媒学会(編), 2019, 113–123.
- 配位子つくって30年
澤村正也
OM News, 2018, 12–17.
- ナノと有機合成(巻頭言)
澤村正也
有機合成化学協会誌, 2016, 74, 581.
- 銅触媒の機能化に基づく高選択的合成反応の開発T
大宮寛久・ 澤村正也
月刊「化学工業」(特集「戦略的触媒開発と応用」),2016, 67, pp 361– 366.
- Transition-metal-catalyzed Site-selective C–H Functionalization of Quinolines beyond C2 Selectivity.
Iwai, T.; Sawamura, M.
ACS Catal. 2015, 5, 5031–5040.
DOI 10.1021/acscatal.5b01143
- Transition Metal Catalysis with Hollow-shaped Triethynylphosphine Ligands.
Iwai, T.; Sawamura, M.
Bull. Chem. Soc. Jpn. 2014, 87, 1147–1160. (Award Account)
DOI: 10.1246/bcsj.20140186
- Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes.
Ohmiya, H.; Sawamura, M.
J. Synth. Org. Chem. Jpn. 2014, 72 (Special Issue in English), 1207–1217.
- Carbon–Boron and Carbon–Silicon Bond Formation.
M. Sawamura, H. Ito, In Copper-Catalyzed Asymmetric Synthesis;
A. Alexakis, N. Krause, S. Woodword, Ed.; Wiley-VCH: Weinheim, Chapter 6, pp 157–177, 2014.
- シリカ固定化かご型ホスフィンSilica-SMAPおよびSilica-TRIPに基づく有機合成触媒反応の開発.
澤村正也
和光純薬時報,82, pp 2-6, 2014.
- 不活性sp3-C–H結合の化学変換—触媒設計によるチャレンジ
川守田創一郎・澤村正也
化学,68, pp 72–73, 2013.
- Development of Heterogeneous Catalysts through Immobilization of Caged Phosphine Ligand SMAP
Sawamura, M.
Catalysts and Catalysis. 2010, 52, 249-254.
- γ位選択的ボリル化反応澤村正也・伊藤肇
使える!有機合成反応241実践ガイド,丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著,化学同人,pp 314-315, 2010.
- γ位選択的アリル-アリール結成生成反応
澤村正也
使える!有機合成反応241実践ガイド,丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著,化学同人,pp 164-165, 2010.
- Air-Stable, Compact, Caged Trialkylphosphines (SMAPs): Synthesis, Properties and Applications to Homogeneous and Heterogeneous Catalysis
Sawamura, M.
J. Synth. Org. Chem., Jpn. 2009, 67, 1125-1135.
- Copper-Catalyzed Substitution of Allylic Carbonates with Diboron: A New Approach to Allylboronate Synthesis
Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M.
Pure Appl. Chem. 2008, 80, 1039-1045.
- Rhodium-Catalyzed Asymmetric Hydrogenation of Indoles.
Kuwano, R.; Sawamura, M. In Catalysts for Fine Chemical Synthesis; Regio- and Stereo- Controlled Oxidations and Reductions
Roberts, S. M., Whittall, J., Eds.; John Wiley & Sons: West Sussex, 2007; Vol. 5, p 73-86.
- Synthesis and Properties of SMAPs 1-Phospha-4-silabicyclo[2.2.2]octane Derivatives
Ochida, A.; Sawamura, M.
ARKIVOC 2006, 359-369.
- L-プロリン触媒を用いる不斉アルドール反応
澤村正也
有機合成のための触媒反応103,檜山為次郎・野崎京子編,東京化学同人,pp 90-91, 2004.
- 遷移金属錯体を用いるアルドール反応
澤村正也
有機合成のための触媒反応103,檜山為次郎・野崎京子編,東京化学同人,pp 88-89, 2004.
- 金(Au)
澤村正也・伊藤肇有機金属反応剤ハンドブック-3Liから83Biまで,玉尾皓平編著,化学同人,pp 243-245, 2003.
- 有機フラーレンの形作る超分子構造-膜と液晶-
中村栄一・松尾豊・磯部寛之・澤村正也
未来材料, 2003, 3, 6-12.
- 銅(I)ヒドリド錯体の触媒作用における不斉配位子加速効果
澤村正也
Organometallic News, 2002, 15.
- Chemistry of 5-Fullerene Metal Complexes.
E. Nakamura, M. Sawamura
Pure Appl. Chem., 2001, 73, 355-359.
- フラーレン類の反応-化学修飾と機能分子設計
中村栄一・澤村正也・磯部寛之
季刊化学総説「炭素第三の同素体フラーレンの化学」,日本化学会編,学会出版センターVol.43, chapter III-13, pp 165-171, 1999.
- Silver and Gold Reagents.
M. Sawamura, In Lewis Acid reagents: A Practical Approach
H. Yamamoto, Ed.; Oxford University Press.: Oxford, chapter 9, pp 169-176, 1999.
- Fullerene That Binds a Metal on the Pentagon.
E. Nakamura, M. Sawamura, H. Iikura, S. Mori
Proc. Electrochem. Soc. 97-14 (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials) 1997, 97-14, 298-308
- 金-α-イソシアノカルボン酸類の不斉アルドール反応
澤村正也
季刊化学総説「金属反応剤を用いる不斉化学合成」,日本化学会編,学会出版センターVol. 19, chapter 11, pp 129-141, 1993.
- Asymmetric Aldol Reaction.
M. Sawamura, Y. Ito, In Catalytic Asymmetric SynthesisI. Ojima, Ed.; VCH, Publishers, Inc.: New York, Chapter 7, pp 367-388, 1993.
- Catalytic Asymmetric Synthesis by Means of Secondary Interaction between Chiral Ligands and Substrates.
M. Sawamura, Y. Ito
Chem. Rev., 1992, 92, 857-871.
Environment and Safety
- 化学物質管理システム運用に関する課題整理と管理システム診断マップの開発
川上貴教・中村修・藤井邦彦・中山政勝・榊原洋子・澤村正也環境と安全, 3, pp 175–185, 2016
- Manegement of Chemicals for Safety and Education in Laboratory
T. Kinoshita, K. Tonokura, I. Shibata, E. Yamada, S. Murata, M. Matsumoto, M. Sawamura, H. Nakagawa, K. Morimoto, A. Koyama
Journal of Environment and Safety, 2015, 6, 81-84.
- 北海道大学における動物実験実施者等の実験動物への感作状況
吉村彩・武蔵学・金子壮郎・大西俊介・折戸智恵子・川原由佳子・橋野聡・森松正美・今野哲・有川二郎・石井哲也・澤村正也・上田一郎アレルギー, 63, pp 1132-11398, 2014
- かけがえのないもののために(巻頭言)
澤村 正也北海道大学環境保全センター報, 16, 1, 2007
- 北海道大学化学物質管理システムの運用について
江見清次郎・宮北貴志・澤村正也北海道大学環境保全センター報, 15, pp 12-15, 2006