2000-2010
39.
Mugineic Acid Derivatives as Molecular Probes for the Mechanistic Elucidation of Iron Acquisition in Barley.

Namba, K.; Kobayashi, K.; Murata, Y.; Hirakawa, H.; Yamagaki, T.; Iwashita, T.; Nishizawa, M.; Kusumoto, S.; Tanino, K.
Angew. Chem. Int. Ed. 2010, 49, 9956. DOI: 10.1002/anie.201004853

2010-7
38.
Toward Mechanistic Elucidation of Iron Acquisition in Barley: Efficient Synthesis of Mugineic Acids and Their Transport Activities.

Namba, K.; Murata, Y.
Chem. Record. 2010, 10, 140. DOI: 10.1002/tcr.200900028

37.
Asymmetric Total Synthesis of Glycinoeclepin A: Generation of a Novel Bridgehead Anion Species.

Shiina, Y.; Tomata, Y.; Miyashita, M.; Tanino, K.
Chem. Lett. 2010, 39, 3983. DOI: 10.1246/cl.2010.835

2010-5
36.
Practical synthesis of (E)- and (Z)-2-silyl-3-penten-1-ols with high enantiopurity.

Fukuda, K.; Miyashita, M.; Tanino, K.
Tetrahedron. Lett. 2010, 51, 4523. DOI: 10.1016/j.tetlet.2010.06.104

2010-4
35.
Cyclooctanone synthesis via a formal [6+2] cycloaddition reaction of a dicobalt acetylene complex.

Mitachi, K.; Shimizu, T.; Miyashita, M.; Tanino, K.
Tetrahedron Lett. 2010, 51, 3983. DOI: 10.1016/j.tetlet.2010.05.120

2010-3
34.
Total Synthesis of Furanether B. Construction of a Hydroazulene Skeleton via a Novel [5 + 2] Cycloaddition Reaction of Silyloxyallene.

Mitachi, K.; Yamamoto, T.; Kondo, F.; Shimizu, T.; Miyashita, M.; Tanino, K.
Chem. Lett. 2010, 39, 630. DOI: 10.1246/cl.2010.630

2010-2
33.
Synthetic studies on azadirachtin: stereoselective construction of the ABCE ring system.

Nakagawa, D.; Miyashita, M.; Tanino, K.
Tetrahedron. Lett. 2010, 51, 2771. DOI: 10.1016/j.tetlet.2010.03.077

2010-1
32.
Total Synthesis of Zoanthenol.

Takahashi, Y.; Yoshimura, F.; Tanino, K.; Miyashita, M.
Angew. Chem. Int. Ed. 2009, 48, 8905. DOI: 10.1002/anie.200904537

2009-5
31.
4-Aminopyridine Catalyzed Direct and Regioselective Acylation of N-Tosylhydrazide.

Namba, K.; Shoji, I.; Nishizawa, M.; Tanino, K.
Org. Lett. 2009, 11, 4970. DOI: 10.1021/ol9021194

2009-4
30.
AN EFFICIENT SYNTHETIC METHOD FOR 3-BROMOFURAN DERIVATIVES VIA STEREOSELECTIVE CYCLIZATION OF γ,δ-EPOXY-(E)-α-BROMOACRYLATES.

Yoshimura, F.; Takahashi, M.; Tanino, K.; Miyashita, M.
HETEROCYCLES 2009, 77, 201. DOI: 10.3987/COM-08-S(F)25

29.
Synthetic Studies of the Zoanthamine Alkaloids: The Total Syntheses of Norzoanthamine and Zoanthamine.

Yoshimura, F.; Sasaki, M.; Hattori, I.; Komatsu, K.; Sakai, M.; Tanino, K.; Miyashita, M.
Chem. Eur. J. 2009, 15, 6626. DOI: 10.1002/chem.200900310

2009-2
28.
Toward Palau’amine: Hg(OTf)2-Catalyzed Synthesis of the Cyclopentane Core.

Namba, K.; Kaihara, Y.; Yamamoto, H. Imagawa, H.; Tanino, K.; Williams, R. M.; Nishizawa, M.
Chem. Eur. J. 2009, 15, 6560. DOI: 10.1002/chem.200900622

2009-1
27.
Palladium-catalyzed stereospecific substitution of α,β-unsaturated γ,δ-epoxy esters by alcohols.

Yu, X. Q.; Yoshimura, F.; Tanino, K.; Miyashita, M.
Angew. Chem. Int. Ed. 2008, 47, 750. DOI: 10.1002/anie.200703889

2008-3
26.
Stereospecific interconversion of cis- and trans-g,d-epoxy, α,β-unsaturated ester systems.

Yu, X. Q.; Yoshimura, F.; Tanino, K.; Miyashita, M.
Tetrahedron Lett. 2008, 49, 7442. DOI: 10.1016/j.tetlet.2008.09.115

2008-2
25.
Stereospecific epoxide-opening reactions of 1,1-dibromo-3,4-epoxy-1-alkenes with carbon nucleophiles.

Yoshimura, F.; Takahashi, M.; Tanino, K.; Miyashita, M.
Tetrahedron Lett. 2008, 49, 6991. DOI: 10.1016/j.tetlet.2008.09.115

2008-1
24.
Synthesis of alicyclic esters via an intramolecular conjugate addition reaction. New method for generating (Z)-vinylcopper species from 1,1-dibromoalkenes.

Tanino, K.; Arakawa, K.; Satoh, M.; Iwata, Y.; Miyashita, M.
Tetrahedron Lett. 2006, 47, 861. DOI: 10.1016/j.tetlet.2005.12.002

2006-2
23.
A Novel Cyclopentene Annulation Method Based on Conjugate Addition Reactions of α-Cyano Carbanion Species.

Tanino, K,; Tomata, Y.; Shiina, Y.; Miyashita, M.
Eur. J. Org. Chem. 2006, 2, 328. DOI: 10.1002/ejoc.200500759

2006-1
22.
Total Synthesis of Ingenol.

Kuwajima, I.; Tanino, K.
Chem. Rev. 2005, 105, 4661. DOI: 10.1021/cr040636z

2005-7
21.
PROCESS FOR PRODUCTION OF CYCLOPENTENENITRILE DERIVATIVES.

MIYASHITA MASAAKI ,TANINO KEIJI ,TOMATA YOSHIHIDE, SHIINA YASUHIRO
PCT Int. Appl., 2005, Publication number:WO2005085184 (A1).
20.
Pd-Catalyzed Stereospecific Azide Substitution of α,β-Unsaturated γ,δ-Epoxy Esters with Double Inversion of Configuration.

Miyashita, M.; Mizutani, T.; Tadano, G.; Iwata, Y.; Miyazawa, M.; Tanino, K.
Angew. Chem. Int. Ed. 2005, 44, 5094. DOI: 10.1002/anie.200500838

2005-5
19.
Stereoselective Synthesis of Premisakinolide A, the Monomeric Counterpart of the Marine 40-Membered Dimeric Macrolide Misakinolide A.

Nakamura, R.; Tanino, K.; Miyashita, M.
Org. Lett. 2005, 7, 2929. DOI: 10.1021/ol050864v

2005-4
18.
Synthetic Studies of Tedanolide, a Marine Macrolide Displaying Potent Antitumor Activity. Stereoselective Synthesis of the C(13)-C(23) Segment.

Iwata, Y.; Tanino, K.; Miyashita, M.
Org. Lett. 2005, 7, 2341. DOI: 10.1021/ol050569a

2005-3
17.
Tetramic Acid Antibiotics: Stereoselective Synthesis of Streptolic Acid and Tirandalydigin.

Iwata, Y.; Maekawara, N.; Tanino, K.; Miyashita, M.
Angew. Chem. Int. Ed. 2005, 44, 1532. DOI: 10.1002/anie.200462300

2005-2
16.
Synthesis of cyclobutanones and four-membered enol ethers by using a rearrangement reaction of enol triflates.

Tanino, K.; Aoyagia, K.; Kiriharaa, Y.; Ito, Y.; Miyashita, M.
Tetrahedron. Lett. 2005, 46, 1169. DOI: 10.1016/j.tetlet.2004.12.060

2005-1
15.
Total Synthesis of Norzoanthamine.

Miyashita, M.; Sasaki, M.; Hattori, I.; Sakai, M.; Tanino, K.
SCIENCE 2004, 305, 495. Stable URL: http://www.jstor.org/stable/3837463

2004-3
14.
Stereoselective Total Synthesis of the Ionophore Antibiotic Zincophorin.

Komatsu, K.; Tanino, K.; Miyashita, M.
Angew. Chem. Int. Ed. 2004, 43, 4341. DOI: 10.1002/anie.200460434

2004-2
13.
Regio- and stereospecific alkyl and alkynyl substitution reactions of epoxy selenides with organoaluminums via episelenonium ions.

Sasaki, M.; Hatta, M.; Tanino, K.; Miyashita, M.
Tetrahedron. Lett. 2004, 45, 1911. DOI: 10.1016/j.tetlet.2003.12.137

2004-1
12.
The first C2 selective halide substitution reaction of 2,3-epoxy alcohols by the use of (CH3O)3B–MX (X=I, Br, Cl) system.

Tomata, Y.; Sasaki, M.; Tanino, K.; Miyashita, M.
Tetrahedron Lett. 2003, 44, 8975. DOI: 10.1016/j.tetlet.2003.10.001

2003-6
11.
Total Synthesis of Scytophycin C. 2. Coupling Reaction of the C(1)−C(18) Segment and the C(19)−C(31) Segment, a Key Macrolactonization, and the Crucial Terminal Amidation Reaction.

Nakamura, R.; Tanino, K.; Miyashita, M.
Org. Lett. 2003, 5, 3583. DOI: 10.1021/ol0352299

2003-5
10.
Total Synthesis of Scytophycin C. 1. Stereoselective Syntheses of the C(1)−C(18) Segment and the C(19)−C(31) Segment.

Nakamura, R.; Tanino, K.; Miyashita, M.
Org. Lett. 2003, 5, 3579. DOI: 10.1021/ol035227o

2003-4
9.
The C2 Selective Nucleophilic Substitution Reactions of 2,3-Epoxy Alcohols Mediated by Trialkyl Borates:  The First endo-Mode Epoxide-Opening Reaction through an Intramolecular Metal Chelate.

Sasaki, M.; Tanino, K.; Hirai, A.; Miyashita, M.
Org. Lett. 2003, 5, 1789. DOI: 10.1021/ol034455f

2003-3
8.
Stereospecific Synthesis of Aldoses Based on the Epoxide-Opening Reaction with Double Inversion of the Configuration.

Hirai, A.; Tonooka, T.; Tanino, K.; Miyashita, M.
Chirality 2003, 15, 108. DOI: 10.1002/chir.10170

2003-2
7.
Total Synthesis of Ingenol.

Tanino, K.; Onuki, K.; Asano, K.; Miyashita, M.; Nakamura, T.; Takahashi, Y.; Kuwajima, I.
J. Am. Chem. Soc. 2003, 125, 1498. DOI: 10.1021/ja029226n

2003-1
6.
Regio- and stereoselective α-methylation of γ,δ-epoxy-α,β-unsaturated esters with a Me2Zn-CuCN reagent.

Hirai, A.; Matsui, A.; Komatsu, K.; Tanino, K.; Miyashita, M.
Chem. Commun. 2002, 1970. DOI: 10.1039/b205957f

2002-3
5.
Stereoselective Synthesis of Cycloheptanone Derivatives via an Intermolecular [5+2] Cycloaddition Reaction.

Tanino, K.; Kondo, F.; Shimizu, T.; Miyashita, M.
Org. Lett. 2002, 4, 2217. DOI: 10.1021/ol020086w

2002-1
4.
Synthetic Studies of Zoanthamine Alkaloids. Stereoselective Synthesis of the ABC Ring System of Norzoanthamine by an Intramolecular Diels-Alder Reaction.

Sakai, M.; Sasaki, M.; Tanino, K.; Miyashita, M.
Tetrahedron Lett. 2002, 43, 1705. DOI: 10.1016/S0040-4039(02)00079-5

2002-1
3.
Stereospecific Alkyl and Alkynyl Substitution Reactions of Epoxy Sulfides with Organoaluminums with Double Inversion of the Configuration.

Sasaki, M.; Tanino, K.; Miyashita, M.
J. Org. Chem. 2001, 66, 5388. DOI: 10.1021/jo010240c

2001-2
2.
Regioselective Alkyl and Alkynyl Substitution Reactions of Epoxy Alcohols by the use of Organoaluminum Ate-Complexes: Regiochemical Reversal of Nucleophilic Substitution Reactions.

Sasaki, M.; Tanino, K.; Miyashita, M.
Org. Lett. 2001, 3, 1765. DOI: 10.1021/ol010062+

2001-1
1.
Regioselective Alkyl and Alkynyl Substitution Reactions of Epoxy Alcohols by the use of Organoaluminium Ate-Complexes: Regiochemical Reversal of Nucleophilic Substitution Reactions.

Sasaki, M.; Tanino, K.; Miyashita, M.
Org. Lett. 2001, 3, 1765. DOI: 10.1021/ol010062+

2001-1

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