Prof. Sawamura / Papers
Prof. Masaya Sawamura (Original papers/Reviews)
Original papers
217. Nickel-Catalyzed Defluorophosphonylation of Aryl Fluorides. You, Z.; Masuda, Y.; Iwai, T.; Higashida, K.; Sawamura, M. J. Org. Chem., 2022, 87, in press DOI: 10.1021/acs.joc.2c02048
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216. Photoinduced Alcoholic α-C–H Bond Anti-Markovnikov Addition to Vinylphosphonium Bromides Followed by Wittig Olefination: Two-step Protocol for α-C–H Allylic Alkylation of Alcohols. Yoshida, M.; Sawamura, M.; Masuda, Y. ChemCatChem., 2022, 14, Early View.(VIP) DOI: 10.1002/cctc.202200744
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215. Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold-Zinc Two-Metal Catalysis for Intermolecular Addition of O-Nucleophiles to Non-activated Alkynes. Rawat, V. K.; Higashida, K.; Sawamura, M. ACS Catal., 2022, 12, 8325-8330. DOI: 10.1021/acscatal.2c01701 |
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214. Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetic Acid Derivatives Enabled by Cooperative Participation of Classical and Nonclassical Hydrogen Bonds. Sakai, S.; Fujioka, A.; Imai, K.; Uchiyama, K.; Shimizu, Y.; Higashida, K.; Sawamura, M. Adv. Synth. Catal., 2022, 364, 2333-2339. DOI: 10.1002/adsc.202200327 |
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213. Insights into the Mechanism of Enantioselective Copper-Catalyzed Ring-Opening Allylic Alkylation of Cyclopropanols. Kitabayashi, A.; Mizushima, S.; Higashida, K.; Yasuda, Y.; Shimizu, Y.; Sawamura, M. Adv. Synth. Catal., 2022, 364,1855-1862. DOI: 10.1002/adsc.202200157 |
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212. Visible Light-Induced Reductive Allylation of Aldehydes by Umpolung Approach. Tanaka, I.; Sawamura, M.; Shimizu, Y. Org. Lett., 2022, 24, 520–524. DOI: 10.1021/acs.orglett.1c03927 |
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211. Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes. Ueda, Y.; Masuda, Y.; Iwai, T.; Imaeda, K.; Takeuchi, H.; Ueno, K.; Gao, M.; Hasegawa, J.; Sawamura, M. J. Am. Chem. Soc., 2022, 144, 2218–2224. DOI: 10.1021/jacs.1c11526 |
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210. Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands Niizeki, R.; Higashida, K.; Mejri, E.; Sawamura, M.; Shimizu, Y. Synlett, 2022,33, 288-292. DOI: 10.1055/a-1673-9236 |
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209. Visible-Light-Driven α-Allylation of Carboxylic Acids Sun, K.; Ueno, M.; Imaeda, K.; Ueno, K.; Sawamura, M.; Shimizu, Y. ACS Catal., 2021,11, 9722-9728. DOI: 10.1021/acscatal.1c02558 |
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208. Access to Indole-Fused Benzannulated Medium-Sized Rings through Gold(I)-Catalyzed Cascade Cyclization of Azido-Alkynes Greiner, L. C.; Inuki, S.; Arichi, N.; Oishi, S.; Rikito, S.; Iwai, T.; Sawamura, M.; Hashmi, A. S. K.; Ohno, H. Chem. Eur. J., 2021, 27, 12992-12997. DOI: 10.1002/chem.202101824 |
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207. Nickel-catalyzed Homo-coupling of Aryl Ethers with Magnesium Anthracene Reductant Rawat, V. K.; Higashida, K.; Sawamura, M. Synthesis, 2021, 53, 3397-3403. DOI: 10.1055/a-1509-5954 |
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206. A Hollow-Shaped Caged Triarylphosphine: Synthesis, Characterization and Applications to Gold(I)-Catalyzed 1,8-Enyne Cycloisomerization Iwai,T.; Goto,Y.; You, Z.; Sawamura, M. Chem. Lett., 2021, 50, 1236-1239. DOI: doi.org/10.1246/cl.210176 |
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205. Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids Rawat, V. K.; Higashida, K.; Sawamura, M. Adv. Synth. Cat., 2021, 363, 1631–1637. DOI: 10.1002/adsc.202001515 |
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204. Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms You, Z.; Higashida, K.; Iwai,T.; Sawamura, M. Angew. Chem. Int. Ed., 2021, 90, 5778–5782. DOI: 10.1002/anie.202013544 |
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203. Synthesis of 2-Hydroxy-2-pyridinone Derivatives and Evaluation of Their Antioxidant/Anticancer Activities Hamama, W. S.; Ghaith, E. A.; Ibrahim, M. E.; Sawamura, M.; Zoorob, H. H. ChemistrySelect, 2021, 6, 1430–1439. DOI: doi.org.10.1002/slct.202004682 |
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202. Dumbbell-Shaped 2,2’-Bipyridines: Controlled Metal Monochelation and Application to Ni-Catalyzed Cross-Couplings Kim, Y.; Iwai T.; Fujii,S.; Ueno, K.; Sawamura, M. Chem. Eur. J., 2021, 27, 2289–2293. DOI: 10.1002/chem.202004053 |
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201. Convenient Synthesis of Binary and Fused Pyrazole Ring Systems: Accredited by Molecular Modeling and Biological Evaluation Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S. ChemistrySelect. 2020, 5, 14917–14923. DOI: doi.org.10.1002/slct.202004014 |
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200. Polystyrene-Cross-Linking Triphenylphosphine on Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic Flow Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. Ind. Eng. Chem. Res. 2020, 59, 15179–15187. DOI: 10.1021/acs.iecr.0c02404 |
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199. Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.; Mori, S.; Sawamura, M. Adv. Synth. Catal. 2020, 362, 4655–4661. DOI: 10.1002/adsc.202000615 |
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198. Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2020, 22, 5240–5245. DOI: 10.1021/acs.orglett.0c01905 |
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197. Polystyrene‐Supported PPh3 in Macroporous Monolith: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C‐C Cross‐Coupling of Aryl Chlorides Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. ChemCatChem 2020, 12, 4034–4037. DOI: 10.1002/cctc.202000651 |
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196. Copper-Catalyzed Enantioselective Conjugate Reduction of α,β-Unsaturated Esters with Phenol-Carbene Chiral Ligand Mimura, S.; Mizushima, S.; Shimizu, Y.; Sawamura, M. Beilstein J. Org. Chem. 2020, 16, 537–543. DOI: 10.3762/bjoc.16.50 |
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195. Boron-Catalyzed α-Amination of Carboxylic Acids Morisawa, T.; Sawamura, M.; Shimizu, Y. Org. Lett. 2019, 21, 7466–7469. DOI: 10.1021/acs.orglett.9b02769 |
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194. Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2019, 21, 5867–5872 DOI: 10.1021/acs.orglett.9b01989 |
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193. Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines. Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M. J. Am. Chem. Soc. 2019, 141, 7261–7265. DOI: 10.1021/jacs.9b02751 |
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192. Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes Ueda, Y.; Iwai, T.; Sawamura, M Chem. Eur. J. 2019, 25, 9410–9414. DOI: 10.1002/chem.201900822. |
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191. Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2019, 361, 2250–2254. DOI: 10.1002/adsc.201801713 |
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190. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M. Org. Lett. 2019, 21, 1717–1721. DOI:10.1021/acs.orglett.9b00276 |
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189. A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides Arashima, J.; Iwai, T.; Sawamura, M. Chem. Asian J. 2019, 14, 411–415. DOI: 10.1002/asia.201801651 |
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188. P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization Iwai, T.; Shibaike, M.; Sawamura, M. Chem. Lett. 2018, 47, 1162–1164. DOI: 10.1246/cl.180501 |
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187. Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 9465–9469. DOI: 10.1002/anie.201802821 |
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186. Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand Konishi, S.; Iwai, T.; Sawamura, M. Organometallics 2018, 37, 1876–1883. DOI: 10.1021/acs.organomet.8b00113 |
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185. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M. Org. Lett. 2018, 20, 1861–1865. DOI: 10.1021/acs.orglett.8b00390 |
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184. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M. Chem. Sci. 2018, 9, 3484–3493. DOI: 10.1039/C8SC00527C |
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183. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M. Chem. Lett. 2018, 47, 632–635. DOI: 10.1246/cl.180147 |
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182. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes Yasuda, Y.; Ohmiya, H.; Sawamura, M. Synthesis 2018, 50, 2235–2246. DOI: 10.1055/s-0036-1591548 |
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181. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted g-Borylallylboranes Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 3196–3199. DOI: 10.1002/anie.201712351 |
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180. Nickel-Catalyzed Amination of Aryl Fluorides with Primary Amines Harada, T.; Ueda, Y.; Iwai, T.; Sawamura, M. Chem. Commun. 2018, 54, 1718–1721. DOI: 10.1039/C7CC08181B |
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179. Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition Iwai, T.; Ueno, M.; Okochi, H.; Sawamura, M. Adv. Synth. Catal. 2018, 360, 670–675. DOI: 10.1002/adsc.201701193 |
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178. Polystyrene-Cross-Linking Ortho-Substituted Triphenylphosphines: Synthesis, Coordination Properties, and Application to Pd-Catalyzed Cross-Coupling of Aryl Chlorides Iwai, T.; Asano, K.; Harada, T.; Sawamura, M. Bull. Chem. Soc. Jpn. 2017, 90, 943–949. DOI: 10.1246/bcsj.20170141 |
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177. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand. Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M. Chem. Eur. J. 2017, 23, 8400–8404. DOI: 10.1002/chem.201702070 |
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176. Exploring the Full Catalytic Cycle of Rhodium(I)–BINAP-Catalysed Isomerization of Allylic Amines: A Graph Theory Approach for Path Optimisation. Yoshimura, T.; Maeda, S.; Taketsugu, T.; Sawamura, M.; Morokuma, K.; Mori, S. Chem. Sci. 2017, 8, 4475–4488. DOI: 10.1039/C7SC00401J |
175. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides. Hojoh, K.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2017, 139, 2184–2187. DOI: 10.1021/jacs.6b12881 |
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174. A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis. Iwai, T.; Harada, T.; Shimada, H.; Asano, K.; Sawamura, M. ACS Catal. 2017, 7, 1681–1692. DOI: 10.1021/acscatal.6b02988 |
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173. Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines. Iwai, T.; Tanaka, R.; Sawamura, M. Organometallics, 2016, 35, 3959-3969. DOI: 10.1021/acs.organomet.6b00752 |
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172. Copper-Catalyzed Enantioselective Allyl–Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand. Yasuda, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed., 2016, 55, 10816-10820. DOI: 10.1002/anie.201605125 |
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171. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates. Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. Org. Lett., 2016, 18, 1706-1709. DOI: 10.1021/acs.orglett.6b00677 |
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170. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. Organometallics, 2016, 35, 1354-1357. DOI: 10.1021/acs.organomet.6b00126 |
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169. Site-selective and Stereoselective C(sp3)–H Borylation of Alkyl Side Chains of 1,3-Azoles with a Silica-Supported Monophosphine-Ir Catalyst. Murakami, R.; Iwai, T.; Sawamura, M. Synlett., 2016, 27, 1187-1192. DOI: 10.1055/s-0035-1561599 |
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168. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles. Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M. Angew. Chem. Int. Ed., 2016, 55, 4777-4780. DOI:10.1002/anie.201600619 |
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167. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. Beilstein J. Org. Chem., 2015, 11, 2444–2450. DOI:10.3762/bjoc.11.265 |
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166. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-coupling of Chloroarenes. Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M. ACS Catal., 2015, 5, 7254–7264. DOI: 10.1021/acscatal.5b00904 |
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165. Synthesis of 1,1-Diborylalkenes through a Brønsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron. Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed., 2015, 54, 15859-15862. DOI: 10.1002/anie.201509218 |
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164. Synthesis and Structures of a Chiral Phosphine-Phosphoric Acid Ligand and Its Rhodium(I) Complexes. Iwai, T.; Akiyama, Y.; Tsunoda, K.; Sawamura, M. Tetrahedron:Asymmetry, 2015, 26, 1245–1250. DOI: 10.1016/j.tetasy.2015.09.016 |
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163. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M. Tetrahedron, 2015, 71, 6519–6533. DOI:10.1016/j.tet.2015.05.048 |
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162. Copper-Catalyzed g-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes. Yasuda, Y.; Nagao, K.; Shido, Y.; Mori, S.; Ohmiya, H.; Sawamura, M. Chem. Eur. J. 2015, 21, 9666-9670. DOI: 10.1002/chem.201501055 |
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161. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M. Org. Lett. 2015, 17, 2039–2041. DOI: 10.1021/acs.orglet.5b00758 |
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160. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis. Nagao, K.; Ohmiya, H.; Sawamura, M. Org. Lett. 2015, 17, 1304–1307. DOI: 10.1021/acs.orglett.5b00305 |
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159. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles. Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2014, 136, 13932–13939. DOI: 10.1021/ja508433 |
158. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes. Nagao, K.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2014, 136, 10605–10608. DOI: 10.1021/ja506310v |
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157. Stereoselective C–H Borylations of Cyclopropanes and Cyclobutanes with Silica-supported Monophosphane-Ir Catalysts. Murakami, R.; Tsunoda,K.; Iwai, T.; Sawamura, M. Chem. Eur. J. 2014, 20, 13127–13131. DOI: 10.1002/chem.201404362 |
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156. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper). DOI: 10.1002/anie.201402386. |
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155. Silica-Supported Tripod Triarylphosphane: Application to Transition Metal Catalyzed C(sp3)–H Borylations. Iwai, T.; Murakami, R.; Harada,T.; Kawamorita, S.; Sawamura, M. Adv. Synth. Catal. 2014, 356, 1563–1570. DOI: 10.1002/adsc.201301147 |
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154. Silica-supported Tripod Triarylphosphines: Application to Palladium Catalyzed Borylation of Chloroarenes. Iwai, T.; Harada, T.; Tanaka, R.; Sawamura, M. Chem. Lett. 2014, 43, 584–586. DOI: 10.1246/cl.131161 |
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153. Tripod Immobilization of Triphenylphosphane on a Silica Gel Surface to Enable Selective Mono-P-ligation to Palladium: Application to Suzuki–Miyaura Cross-Coupling with Chloroarenes. Iwai, T.; Tanaka, R.; Harada, T.; Sawamura, M. Chem. Eur. J. 2014, 20, 1057–1065. DOI: 10.1002/chem.201304081 |
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152. Site-selective C–H Borylation of Quinolines at the C-8 Position Catalyzed by a Silica-supported Phosphane-Iridium System. Konishi, S.; Kawamorita, S.; Iwai, T.; Steel, P. G.; Marder, T. B.; Sawamura, M. Chem. Asian J. 2014, 9, 434-438. DOI: 10.1002/asia.201301423 |
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151. Friedel-Crafts Functionalization of Cyclopentadienyl Ligand in Bucky Metallocenes. Matsuo, Y.; Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura ,E. Dalton Trans. 2014, 43, 7407–7412. DOI: 10.1039/C3DT52002A |
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150. Threefold Cross-Linked Polystyrene-Triphenylphosphane Hybrids: Mono-P-Ligating Behaviors and Catalytic Applications for Aryl Chloride Cross-Coupling and C(sp3)–H Borylation. Iwai, T.; Harada, T.; Hara, K.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 12322–12326. DOI: 10.1002/anie.201306769 |
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149. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide. Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 11620–11623. DOI: 10.1002/anie.201305973 |
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148. Cooperative Catalysis of Metal and O–H···O/sp3-C–H···O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes. Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H.; Mori, S.; Sawamura,M. Chem. Eur. J. 2013, 19, 13547–13553. DOI: 10.1002/chem.201301280 |
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147. Synthesis of a Chiral N-Heterocyclic Carbene Bearing a m-Terphenyl-Based Phosphate Moiety as an Anionic N-Substituent and Its Application to Copper-Catalyzed Enantioselective Boron Conjugate Addition. Iwai, T.; Akiyama, Y.; Sawamura, M. Tetrahedron: Asymmetry 2013, 24, 729–735. DOI: 10.1016/j.tetasy.2013.05.013 |
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146. Copper-Catalyzed g-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes. Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 5350–5354. DOI: 10.1002/anie.201300785 |
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145. Synthesis of Primary and Secondary Alkylboronates through Site-Selective C(sp3)–H Activation with Silica-Supported Monophosphine–Ir Catalysts Kawamorita, S.; Murakami, R; Iwai, T.; Sawamura, M. J. Am. Chem. Soc. 2013, 135, 2947–2950. DOI: 10.1021/ja3126239 |
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144. Construction of Eight-Membered Carbocycles via Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers. Iwai, T.; Okochi, H.; Ito, H.; Sawamura, M. Angew. Chem. Int. Ed. 2013, 52, 4239-4242. DOI: 10.1002/anie.201300265 |
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143. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters. Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M. Adv. Synth. Cat. 2013, 355, 647–652. DOI: 10.1002/adsc.201200949 |
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142. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes. Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 18573–18576. DOI: 10.1021/ja3093955 |
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141. Conjugate Reduction of a,b-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane–Copper Complex. Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2012, 354, 3440–3444. DOI: 10.1002/adsc.201200555 |
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140. Rh-Catalyzed Borylation of N–Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand. Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 12924–12927. DOI: 10.1021/ja305694r |
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139. Synthesis of Allenylsilanes through Copper-Catalyzed g-Selective Coupling between g-Silylated Propargylic Phosphates and Alkylboranes. Yokobori, U.; Ohmiya, H.; Sawamura, M. Organometallics 2012, 31, 7909-7913. DOI: 10.1021/om300552f |
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138. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper–N-Heterocyclic Carbene Complex. Yoshida, M.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 11896–11899. DOI: 10.1021/ja304481a |
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137. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes. Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2012, 134, 8982–8987. DOI: 10.1021/ja302520h |
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136. Practical Procedure for Copper(I)-Catalyzed Allylic Boryl Substitution with Stoichiometric Alkoxide Base. Ito, H.; Miya, T.; Sawamura, M. Tetrahedron 2012, 68, 3423-3427. DOI: 10.1016/j.tet.2011.08.081 |
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135. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Allylic Phosphates and Alkylboranes. Nagao, K.; Ohmiya, H.; Sawamura, M. Synthesis 2012, 44, 1535-1541. DOI: 10.1055/s-0031-1290818 |
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134. Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation. Makida, Y.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2012, 51, 4122-4127. DOI: 10.1002/anie.201200809 |
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133. Synthesis of Conjugated Allenes through Copper-Catalyzed g-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates. Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M. Org. Lett. 2012, 14, 816-819. DOI: 10.1021/ol2033465 |
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132. Copper(I)-Catalyzed Allylic Substitution of Silyl Nucleophiles through Si–Si Bond Activation. Ito, H.; Horita, M.; Sawamura, M. Adv. Synth. Catal. 2012, 354, 813-817. DOI: 10.1002/adsc.201100819 |
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131. Efficient Preparation of b-Branched g,d-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal. Li, D.; Ohmiya, H.; Sawamura, M. Synthesis 2012, 44, 1304-1307. DOI: 10.1055/s-0031-1289712 |
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130. Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands. Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M. J. Am. Chem. Soc. 2011,133, 19310-19313. DOI: 10.1021/ja208364a |
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129. General Approach to Allenes through Copper-Catalyzed g-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M. Org. Lett. 2011, 13, 6312-6315. DOI: 10.1021/ol202866h |
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128. Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand. Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M. Angew. Chem. Int. Ed. (VIP) 2011,50, 8363-8366. DOI: 10.1002/anie.201103224 |
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127. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization. Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M. Beilstein. J. Org. Chem. 2011, 7, 951-959. DOI: 10.3762/bjoc.7.106 |
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126. Mechanistic Insight into the Anomalous syn-Selectivity Observed During the Addition of Allenylboronates to Aromatic Aldehydes. Sasaki, Y.; Sawamura, M.; Ito, H. Chem. Lett. 2011, 40, 1044-1046. DOI: 10.1246/cl.2011.1044 |
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125. Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl a,b-Unsaturated Ketones. Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M. Chem. Lett. 2011, 40, 928-930. DOI: 10.1246/cl.2011.928 |
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124. Copper-Catalyzed g-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals. Li, D.; Ohmiya, H.; Sawamura, M. J. Am. Chem. Soc. 2011, 133, 5672-5675. DOI: 10.1021/ja111645q |
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123. Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes. Ohmiya, H.; Tanabe, M.; Sawamura, M. Org. Lett. 2011, 13, 1086-1088. DOI: 10.1021/ol103128x |
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122. Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronate. Sasaki, Y.; Horita, Y.; Zhong, C.; Sawamura, M.; Ito, H. Angew. Chem. Int. Ed. 2011, 50, 2778-2782. DOI: 10.1002/anie.201007182 |
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121. Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl a,b-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes. Ohmiya, H.; Yoshida, M.; Sawamura, M. Org. Lett. 2011, 13, 482-485. DOI: 10.1021/ol102819k |
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120. Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids. Makida, Y.; Ohmiya, H.; Sawamura, M. Chem. Asian J.2011, 6, 410-414. DOI: 10.1002/asia.201000721 |
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119. Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex. Ito, H.; Ohmiya, H.; Sawamura, M. Org. Lett. 2010, 12, 4380-4383. DOI: 10.1021/ol101860j |
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118. Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex. Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M. Org. Lett. 2010, 12, 3978-3981. DOI: 10.1021/ol101493m |
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117. Direct Enantio-convergent Transformation of Racemic Substrates without Racemization or Symmetrization. Ito, H.; Kunii, S.; Sawamura, M. Nature Chem. 2010, 2, 972-976. DOI: 10.1038/nchem.801 |
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116. Enantioselective Synthesis of trans-Aryl- and Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative. Zhong, C.; Kuni, S.; Kosaka, Y.; Sawamura, M.; Ito, H. J. Am. Chem. Soc. 2010, 132, 11140-11142. DOI: 10.1021/ja103783p |
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115. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes. Ohmiya, H.; Yoshida, M.; Sawamura, M. Synlett, 2010, 2136-2140. DOI: 10.1055/s-0030-1258527 |
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114. Synthesis of a-Arylated Allylsilanes through Palladium-Catalyzed g-Selective Allyl-Aryl Coupling. Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M. Org. Lett. 2010, 12, 3344-3347. DOI: 10.1021/ol101114r |
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113. Copper-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates Ohmiya, H.; Yokokawa, N.; Sawamura, M. Org. Lett. 2010, 12, 2438-2440. DOI: 10.1021/ol100841y |
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112. Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex. Kawamorita, S.; Ohmiya, H.; Sawamura, M. J. Org. Chem. 2010, 75, 3855-3858. DOI: 10.1021/jo100352b |
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111. Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative. Ito, H.; Toyoda, T.; Sawamura, M. J. Am. Chem. Soc. 2010, 132, 5990-5992. DOI: 10.1021/ja101793a |
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110. Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates. Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M. Org. Lett. 2010, 12, 1796-1799. DOI: 10.1021/ol100405k |
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109. Copper-Catalyzed g-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes. Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M. J. Am. Chem. Soc. 2010, 132, 2895-2897. DOI: 10.1021/ja9109105 |
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108. Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantio-Enriched Cyclic Homoally- and Allylboronates. Sasaki, Y.; Zhong, C.; Sawamura, M.; Ito, H. J. Am. Chem. Soc. 2010, 132, 1226-1227. DOI: 10.1021/ja909640b |
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107. Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids. Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M. J. Am. Chem. Soc. 2010, 132, 879-889. DOI: 10.1021/ja9092264 |
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106. Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes. Ito, H.; Okura, T.; Matsuura, K.; Sawamura, M. Angew. Chem. Int. Ed. 2010, 49, 560-563. DOI: 10.1002/anie.200905993 |
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105. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate. Ohmiya, H.; Ito, H.; Sawamura, M. Org. Lett. 2009, 11, 5618-5620. DOI: 10.1021/ol902339a |
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104. The Synthesis of Allenes by Cu(I)-Catalyzed Regio- and Stereoselective Reduction of Propargylic Carbonates with Hydrosilanes. Zhong, C.; Sasaki, Y.; Ito, H.; Sawamura, M. Chem. Commun.2009, 5850-5852. DOI: 10.1039/b910192f |
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103. Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex. Ito, H.; Saito, T.; Miyahara, T.; Zhong, C.; Sawamura, M. Organometallics 2009, 28, 4829-4840. DOI: 10.1021/om900445w |
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102. Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents. Ohmiya, H.; Moriya, T.; Sawamura, M. Org. Lett. 2009, 11, 2145-2147. DOI: 10.1021/ol9007712 |
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101. Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System. Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M. J. Am. Chem. Soc. 2009, 131, 5058-5059. DOI: 10.1021/ja9008419 |
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100. Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids. Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M. J. Am. Chem. Soc. 2008, 130, 17276-17277. DOI: 10.1021/ja808673n |
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99. Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multi-Substituted Allenylboronates. Ito, H.; Sasaki, Y.; Sawamura, M. J. Am. Chem. Soc. 2008, 130, 15774-15775. DOI: 10.1021/ja806602h |
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98. Cyclization of Non-Terminal Alkynic b-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand. Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M. Org. Lett. 2008, 10, 5051-5054. DOI: 10.1021/ol802079r |
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97. Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes. Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M. Organometallics 2008, 27, 6495-6506. DOI: 10.1021/om800683g |
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96. Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System. Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M. Org. Lett. 2008,10, 4697-4700. DOI: 10.1021/ol801996r |
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95. Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Catalyzed by Cu(I) Complexes with Wide Bite-Angle Chiral Bisphosphine Ligands: Optimization, Scope and Mechanistic Studies Asano, Y.; Ito, H.; Hara, K.; Sawamura, M. Organometallics 2008, 27, 5984-5996. DOI: 10.1021/om800667c |
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94. Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M. Organometallics 2008, 27, 5494-5503. DOI: 10.1021/om8005728 |
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93. Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative Ito, H.; Kosaka, Y.; Nonoyama, K.; Sasaki, Y.; Sawamura, M. Angew. Chem., Int. Ed. 2008, 47, 7424-7427. DOI: 10.1002/anie.200802342 |
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92. Conductance of Single 1,4-Benzenediamine Molecule Bridging between Au and Pt Electrodes Kiguchi, M.; Miura, S.; Takahashi, T.; Hara, K.; Sawamura, M.; Murakoshi, K. J. Phys. Chem. C 2008, 112, 13349-13352. DOI: 10.1021/jp806129u |
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91. Reversible Mechanochromic Luminescence of Ito, H.; Saito, T.; Oshima, N.; Kitamura, N.; Ishizaki, S.; Hinatsu, Y.; Wakeshima, M.; Kato, M.; Tsuge, K.; Sawamura, M. J. Am. Chem. Soc. 2008, 129, 10044-10045. DOI: 10.1021/ja8019356 |
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90. Synthesis of Metal Fullerene Complexes by the Use of Fullerene Halides Matsuo, Y.; Kuninobu, Y.; Muramatsu, A.; Sawamura, M.; Nakamura, E. Organometallics 2008, 27, 3403-3409. DOI: 10.1021/om8001262 |
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89. Self-Assembled Monolayer of Compact Phosphane with Alkanethiole Pendant: Remarkable Reusability and Substrate Selectivity in Rh Catalysis Hara, K.; Akiyama, R.; Takakusagi, S.; Uosaki, K.; Yoshino, T.; Kagi, H.; Sawamura, M. Angew. Chem. Int. Ed. 2008, 47, 5627-5630. DOI: 10.1002/anie.200800884 |
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88. Copper-Catalyzed Enantioselective Substitution of Allylic Carbonates with Diboron: An Efficient Route to Optically Active a-Chiral Allylboronates Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M. J. Am. Chem. Soc. 2007, 129, 14856-14857. DOI: 10.1021/ja076634o |
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87. Construction of Self-assembled Monolayer Terminated with N-Heterocyclic Carbene-Rhodium(I) Complex Moiety Hara, K.; Iwahashi, K.; Takakusagi, S.; Uosaki, K.; Sawamura, M. Surf. Sci. 2007, 601, 5127-5132. DOI :10.1016/j.susc.2007.04.158 |
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86. Design and Synthesis of Isocyanide Ligands for Catalysis: Application to Rh-catalyzed Hydrosilylation of Ketones Ito, H.; Kato, T.; Sawamura, M. Chem. Asian J. 2007, 2, 1436-1446. DOI: 10.1002/asia.200700215 |
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85. Functionalization of Silicon Surface with Catalytically Active Pd Complex and Application to the Aerobic Oxidation of Benzylic Alcohols Hara, K.; Tayama, S.; Kano, H.; Masuda, T.; Takakusagi, S.; Kondo, T.; Uosaki, K.; Sawamura, M. Chem. Commun. 2007, 4280-4282. DOI: 10.1039/b710820f |
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84. Synthesis and Structural Characterization of Tetranuclear Platinum(II) Metallamacrocycle Containing 1,3-Diisocyanoarene Ligands Ito, H.; Maeda, T.; Sawamura, M. Bull. Chem. Soc. Jpn. 2007, 80, 1981-1986. DOI: 10.1246/bcsj.80.1981 |
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83. Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)-TRAP Complex Asano, Y.; Hara, K.; Ito, H.; Sawamura, M. Org. Lett. 2007, 9, 3901-3904. DOI: 10.1021/ol701534n |
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82. Conductance of Single 1,4-Disubstituted Benzene Molecules Anchored to Pt Electrodes Kiguchi, M.; Miura, S.; Hara, K.; Sawamura, M.; Murakoshi, K. App. Phys. Lett. 2007, 91, 053110. DOI: 10.1063/1.2757592 |
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81. Monocoordinating, Compact Phosphane Immobilized on Silica Surface: Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones Hamasaka, G.; Ochida, A.; Hara, K.; Sawamura, M. Angew. Chem. Int. Ed. 2007, 46, 5381-5383. DOI: 10.1002/anie.200700947 |
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80. Phosphorus Ligands with a Large Cavity: Synthesis of Triethynylphosphines with Bulky End Caps and Application to the Rhodium-Catalyzed Hydrosilylation of Ketones Ochida, A.; Sawamura, M. Chem. Asian J. 2007, 2, 609-618. DOI: 10.1002/asia.200700006 |
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79. Using Triethynylphosphine Ligands Bearing Bulky End Caps to Create a Holey Catalytic Environment: Application to Gold(I)-Catalyzed Alkyne Cyclizations Ochida, A.; Ito, H.; Sawamura, M. J. Am. Chem. Soc., 2006, 128, 16486-16487. DOI: 10.1021/ja066800c |
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78. Conductance of a Single Molecule Anchored by an Isocyanide Substituent to Gold Electrodes Kiguchi, M.; Miura, S.; Hara, K.; Sawamura, M.; Murakoshi, K. Appl. Phys. Lett. 2006, 89, 213104. DOI: 10.1063/1.2392816 |
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77. Synthesis of New Bulky Isocyanide Ligands and Their Use for Rh-catalyzed Hydrosilylation Ito, H.; Kato, T.; Sawamura, M. Chem. Lett. 2006, 35, 1038-1039. DOI: 10.1246/cl.2006.1038 |
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76. Ring Carbon Functionalization of N-Heterocyclic Carbene Ligand with Ester Groups: Electronic Effect of the Ester Groups on Coordination Properties Hara, K.; Kanamori, Y.; Sawamura, M. Bull. Chem. Soc. Jpn. 2006, 79, 1781-1786. DOI: 10.1246/bcsj.79.1781 |
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75. Cyclic Diaminocarbene-Rhodium(I) Complex Tethered to Disulfide: Synthesis and Application to Gold Surface Modification Hara, K.; Iwahashi, K.; Kanamori, Y.; Naito, S.; Takakusagi, S.; Uosaki, K.; Sawamura, M. Chem. Lett. 2006, 35, 870-871. DOI: 10.1246/cl.2006.870 |
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74. Electronically Tunable Compact Trialkylphosphines: SMAPs Bridged Bicylic Phosphines Ochida, A.; Ito, S.; Miyahara, T.; Ito, H.; Sawamura, M. Chem. Lett. 2006, 35, 294-295. DOI: 10.1246/cl.2006.294 |
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73. Strong Counter Anion Effects on the Catalytic Activity of Cationic Silicon Lewis Acids in Mukaiyama Aldol and Diels-Alder Reactions Hara, K.; Akiyama, R.; Sawamura, M. Org. Lett. 2005, 7, 5621- 5623. DOI: 10.1021/ol052206g |
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72. Copper-Catalyzed g-Selective and Sterespecific Substitution Reaction of Allylic Carbonates with Diboron: Efficient Route to Chiral Allylboron Compounds Ito, H.; Kawakami, C.; Sawamura, M. J. Am. Chem. Soc. 2005, 127, 16034-16035. DOI: 10.1021/ja056099x |
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71. Gold(I)-Phosphine Catalyst for the Highly Chemoselective Dehydrogenative Silylation of Alcohols Ito, H.; Takagi, K.; Miyahara, T.; Sawamura, M. Org. Lett. 2005, 7, 3001-3004. DOI: 10.1021/ol050979z |
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70. Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)-Phosphine Complex Ito, H.; Watanabe, A.; Sawamura, M. Org. Lett. 2005, 7, 1869-1871. DOI: 10.1021/ol050559+ |
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69. Creation of Hoop- and Bowl-Shaped Benzenoid Systems by Selective Detraction of [60]Fullerene Conjugation. [10]Cyclophenacene and Fused Corannulene Derivatives Matsuo, Y.; Tahara, K.; Sawamura, M.; Nakamura, E. J. Am. Chem. Soc. 2004, 126, 8725-8734. |
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68. Nickel, Palladium and Platinum Complexes of 5- Cyclopentadienide C60R5 Ligands. Kinetic and Thermodynamic Stabilization Effects of C60Ph5 Ligand Kuninobu, Y.; Matsuo, Y.; Toganoh, M.; Sawamura, M.; Nakamura, E. Organometallics 2004, 23, 3259-3266. |
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67. Multilayer Vesicless and Vesicle Clusters Formed by the Fullerene-based Surfactant C60(CH3)5K Burger, C.; Hao, J.; Ying, Q.; Isobe, H.; Sawamura, M.; Nakamura, E.; Chu, B. J. Colloid Interface Sci. 2004, 275, 632-641. |
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66. Non-volatile Me3P-like P-Donor Ligand: Synthesis and Properties of 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane Ochida, A.; Hara, K.; Ito, H.; Sawamura, M. Org. Lett. 2003, 5, 2671-2674. DOI: 10.1021/ol0349099 |
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65. Regioselective Synthesis of [60]Fullerene 5-Indenide R3C60- and 5-Cyclopentadienide R5C60-Bearing Different R Groups Toganoh, M.; Suzuki, K.; Udagawa, R.; Hirai, A.; Sawamura, M.; Nakamura, E. Org. Biomol. Chem. 2003, 1, 2604-2611. |
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64. Synthesis, Structure, and Aromaticity of a Hoop-Shaped Cyclic Benzenoid [10]Cyclophenacene Nakamura, E.; Tahara, K.; Matsuo, Y.; Sawamura, M. J. Am. Chem. Soc. 2003, 125, 2834-2835. |
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63. Stacking of Conical Molecules with Fullerene Apex into Polar Columns in Crystals and Liquid Crystals Sawamura, M.; Kawai, K.; Matsuo, Y.; Kanie, K.; Kato, T.; Nakamura, E. Nature 2002, 419, 702-705. |
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62. Hybrid of Ferrocene and Fullerene Sawamura, M.; Kuninobu, Y.; Toganoh, M.; Matsuo, Y.; Yamanaka, M.; Nakamura, E. J. Am. Chem. Soc. 2002, 124, 9354-9355. |
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61. Cu(I)-Mediated Regioselective Tri-addition of Grignard Reagent to [70]Fullerene. Synthesis of Indenyl-type Metal Ligand Embedded into Graphitic Structure Sawamura, M.; Toganoh, M.; Iikura, H.; Matsuo, Y.; Hirai, A.; Nakamura, E. J. Mat. Chem. 2002, 12, 2109-2115. |
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60. Regioselective Penta-addition of 1-Alkenyl Copper Reagent to [60]Fullerene. Synthesis of Penta-alkenyl FCp Ligand Sawamura, M.; Nagahama, N.; Toganoh, M.; Nakamura, E. J. Organomet. Chem. 2002, 652, 31-35. |
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59. Epitaxial Growth and Electronic Structure of a C60 Derivative Prepared by Solution Spray Technique Shimada, T.; H., N.; Ueno, K.; Koma, A.; Kuninobu, Y.; Sawamura, M.; Nakamura, E. J. Appl. Phys. 2001, 90, 209-212. |
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58. Spherical Bilayer Vesicles of Fullerene-Based Surfactants in Water: A Laser Light Scattering Study Zhou, S.-Q.; Burger, C.; Chu, B.; Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U. E.; Isobe, H.; Nakamura, E. Science 2001, 291, 1944. |
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57. Palladium-Catalysed Asymmetric [4+2] Cycloaddition of Vinylallene with 1,3-Diene Murakami, M.; Minamida, R.; Itami, K.; Sawamura, M.; Ito, Y. Chem. Commun. 2000, 2293-2294. |
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56. Functionalized Fullerene as a New Artificial Vector for Transfection Nakamura, E.; Isobe, H.; Tomita, N.; Sawamura, M.; Jinno, S.; Okayama, H. Angew. Chem. Int. Ed. Engl. 2000, 39, 4254-4257. |
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55. Half-Sandwich Metallocene Embedded in a Spherically Extended -Conjugate System. Synthesis, Structure, and Electrochemistry of Rh(5-C60Me5)(CO)2 Sawamura, M.; Kuninobu, Y.; Nakamura, E. J. Am. Chem. Soc. 2000, 122, 12407-12408. |
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54. Pentaorgano[60]fullerene R5C60-. A Water Soluble Hydrocarbon Anion Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U., E.; Isobe, H.; Nakamura, E.; Zhou, S.-Q.; Chu, B. Chem. Lett. 2000, 1098-1099. |
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53. Catalytic Asymmetric Hydrogenation of -Acetamidoacrylates Using TRAP Trans-Chelating Chiral Diphosphine Ligands: Remarkable Effects of Ligand P-substituent and Hydrogen Pressure on Enantioselectivity Kuwano, R.; Sawamura, M.; Ito, Y. Bull. Chem. Soc. Jpn. 2000, 73, 2571-2578. |
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52. Rhodium-Catalyzed Enantioselective Michael Addition of (1-Cyanoethyl)-phosphonate: Synthesis of Optically Active Phosphonic Acid Derivatives with Phosphorus-Substituted Quaternary Asymmetric Carbon Center Sawamura, M.; Hamashima, H.; Ito, Y. Bull. Chem. Soc. Jpn. 2000, 73, 2559-2562. |
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51. Stepwise Synthesis of Fullerene Cyclopentadienide R5C60- and Indenide R3C60-. An Approach to Fully Unsymmetrically Substituted Derivatives Sawamura, M.; Toganoh, M.; Suzuki, K.; Hirai, A.; Iikura, H.; Nakamura, E. Org. Lett. 2000, 2, 1919-1921. |
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50. A Cage with Fullerene End Caps Isobe, H.; Ohbayashi, A.; Sawamura, M.; Nakamura, E. J. Am. Chem. Soc. 2000, 122, 2669-2670. |
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49. Synthesis of Pentamethyl-monohydro[60]fullerene C60Me5H and Its Use as Cyclopentadienyl-type Ligand Precursor Sawamura, M.; Toganoh, M.; Kuninobu, Y.; Kato, S.; Nakamura, E. Chem. Lett. 2000, 270-271. |
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48. Asymmetric Hydrosilylation of Ketones Using Trans-Chelating Chiral Peralkyldiphosphine Ligands Bearing Primary Alkyl Substituents on Phosphorus Atoms Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y. Bull. Chem. Soc. Jpn. 2000, 73, 485-496. |
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47. Single-Step Synthesis of Pentaaryl-monohydro[60]fullerenes through Five-Fold Addition of Organocopper Reagent to C60 Sawamura, M.; Iikura, H.; Ohama, T.; Hackler, U., E.; Nakamura, E. J. Organometal. Chem. 2000, 599, 32-36. |
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46. Optical Resolution of Chirrally Functionalized [60]Fullerene through Formation of Diastereomeric Methoxyphenyacetic Acid Esters Isobe, H.; Sawamura, M.; Nakamura, E. Fullerene Sci. Technol. 1999, 7, 519-528. |
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45. Synthesis of p-Indenyl-type Fullerene Ligand and Its Metal Complexes via Quantative Trisarylation of C70 Sawamura, M.; Iikura, H.; Hirai, A.; Nakamura, E. J. Am. Chem. Soc. 1998, 120, 8285-8286. |
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44. Endohedral Homoconjugation in Cyclopentadiene Embedded in C60 Iikura, H.; Mori, S.; Sawamura, M.; Nakamura, E. J. Org. Chem. 1997, 62, 7912-7913. |
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43. Trans-Chelating Chiral Peralkyldiphosphine Ligands (R,R)-(S,S)-2,2"-Bis[1-(dialkylphosphino)ethyl]-1,1"-biferrocenes (AlkylTRAPs) and Their Transition Metal Complexes Kuwano, R.; Sawamura, M.; Okuda, S.; Asai, T.; Ito, Y.; Redon, M.; Krief, A. Bull. Chem. Soc. Jpn. 1997, 70, 2807-2822. |
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42. Synthetic and Computational Studies on Symmetry-Defined Double Cycloaddition of a New Tris-Annulating Reagent to C60 Isobe, H.; Tokuyama, H.; Sawamura, M.; Nakamura, E. J. Org. Chem. 1997, 62, 5034-5041. |
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41. Sonochemical, Aerobic Conversion of Alkyl Halides into Alcohols Promoted by Trialkyltin Halide/NaBH3CN Catalytic System Sawamura, M.; Kawaguchi, Y.; Sato, K.; Nakamura, E. Chem. Lett. 1997, 705-706. |
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40. Conversion of Alkyl Halides into Alcohols Using a Near Stoichiometric Amount of Molecular Oxygen: An Efficient Route to 18O- and 17O-Labeled Alcohols Sawamura, M.; Kawaguchi, Y.; Nakamura, E. Synlett 1997, 801-802. |
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39. Enantioselective Allylation of Nitro Group-Stabilized Carbanions Catalyzed by Chiral Crown Ether Phosphine-Palladium Complexes Sawamura, M.; Nakayama, Y.; Tang, W.-M.; Ito, Y. J. Org. Chem. 1996, 61, 9090-9096. |
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38. The First Pentahaptofullerene Metal Complexes Sawamura, M.; Iikura, H.; Nakamura, E. J. Am. Chem. Soc. 1996, 118, 12850-12851. |
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37. Regio- and Diastereo-controlled Double Cycloaddition to [60]fullerene. One-Step Synthesis of Cs and C2 Chiral Organofullerenes with New Tris-Annulating Reagents Nakamura, E.; Isobe, H.; Tokuyama, H.; Sawamura, M. Chem. Commun. 1996, 1747-1748. |
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36. An Enantioselective Two-Component Catalyst System: Rh-Pd-Catalyzed Allylic Alkylation of Activated Nitriles Sawamura, M.; Sudoh, M.; Ito, Y. J. Am. Chem. Soc. 1996, 118, 3309-3310. |
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35. Enantioselective Cycloisomerization of 1,6-Enynes Catalyzed by Chiral Diphosphine-Palladium Complexes Goeke, A.; Sawamura, M.; Kuwano, R.; Ito, Y. Angew. Chem. Int. Ed. Engl. 1996, 35, 662-663. |
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34. Catalytic Asymmetric Hydrogenation of Dimethy Itaconate with Trans-Chelating Chiral Diphosphine Ligands TRAP-Rhodium Complexes Kuwano, R.; Sawamura, M.; Ito, Y. Tetrahedron: Asymmetry 1995, 6, 2521-2526. |
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33. Enantioselective Hydrogenation of -Disubstituted -Acetamidoacrylates Catalyzed by Rhodium Complexes with TRAP Trans-Chelating Chiral Phosphine Ligands Sawamura, M.; Kuwano, R.; Ito, Y. J. Am. Chem. Soc. 1995, 117, 9602-9603. |
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32. Synthesis and Structures of Trans-Chelating Chiral Diphosphine Ligands Bearing Aromatic P-Substituents, (S,S)-(R,R)- and (R,R)-(S,S)-2,2"-Bis[1-(diarylphosphino)ethyl]-1,1"-biferrocenes (ArylTRAPs) and Their Transition Metal Complexes Sawamura, M.; Hamashima, H.; Sugawara, M.; Kuwano, R.; Ito, Y. Organometallics 1995, 14, 4549-4558. |
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31. Asymmetric Michael Reaction of an -Cyano Weinreb Amide Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP Sawamura, M.; Hamashima, H.; Shinoto, H.; Ito, Y. Tetrahedron Lett. 1995, 36, 6479-6482. |
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30. Synthesis and Cellular Characterization of the Detransformation Agent, (-)-Depudecin Shimada, J.; Kwon, H. J.; Sawamura, M.; Schreiber, S. L. Chem. Biol. 1995, 2, 517-525. |
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29. Asymmetric Hydrosilylation of Symmetrical Diketones Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y. Tetrahedron Lett. 1995, 36, 5239-5242. |
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28. Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP Sawamura, M.; Kuwano, R.; Shirai, J.; Ito, Y. Synlett 1995, 347-348. |
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27. Gold(I)-Catalyzed Asymmetric Aldol Reaction of an -Isocyano Weinreb Amide. An Efficient Synthesis of Optically Active -Hydroxy -Amino Aldehydes and Ketone Sawamura, M.; Nakayama, Y.; Kato, T.; Ito, Y. J. Org. Chem. 1995, 60, 1727-1732. |
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26. Asymmetric Michael Reaction of -Cyano Carboxylates Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP Sawamura, M.; Hamashima, H.; Ito, Y. Tetrahedron 1994, 50, 4439-4454. |
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25. Trans-Chelating Chiral Diphosphine Ligands Bearing Flexible P-Alkyl Substituents (AlkylTRAPs). An Application to Rhodium-Catalyzed Asymmetric Hydrosilylation of Simple Ketones Sawamura, M.; Kuwano, R.; Ito, Y. Angew. Chem. Int. Ed. Engl. 1994, 33, 111-113. |
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24. Synthesis of Optically Active Ferrocene Analogues of Salicylic Acid Derivatives and Rhodium(II)-Catalyzed Asymmetric Intramolecular C-H Insertion of -Diazo -Keto Esters Using New Chiral Carboxylato Ligands Sawamura, M.; Sasaki, H.; Nakata, T.; Ito, Y. Bull. Chem. Soc. Jpn. 1993, 66, 2725-2729. |
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23. Synthesis and Properties of a New Chiral Diphosphine Ligand Bearing a Cyclodextrin-Based Molecular Recognition Site and Its Palladium(II) Complex Sawamura, M.; Kitayama, K.; Ito, Y. Tetrahedron: Asymmetry 1993, 4, 1829-1832. |
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22. Structure of (R)-1-[(S)-1',2-Bis(diphenylphosphino)ferrocenyl]ethyl Acetate. Shawkataly, O. B.; Fun, H.-K.; Chinnakali, K.; Yip, B.-C.; Tooh, S.-G.; Ito, Y.; Sawamura, M. Acta Cryst. C. 1993, C49, 1898-1900. |
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21. Structure of 1-[(R)-1',2-Bis(diphenylphosphino)ferrocenyl]-(S)-N,N-dimethylethylamine Shawkataly, O. B.; Khalil, H.; Fun, H.-K.; Chinnakali, K.; Tooh, S.-G.; Ito, Y.; Sawamura, M. Acta Cryst. C. 1993, C49, 139-141. |
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20. Catalytic Asymmetric Synthesis with Trans-Chelating Chiral Diphosphine Ligand TRAP: Rhodium-Catalyzed Asymmetric Michael Addition of α-Cyanocarboxylates Sawamura, M.; Hamashima, H.; Ito, Y. J. Am. Chem. Soc. 1992, 114, 8295-8296. |
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19. Chiral Phosphine Ligands Functionalized by Crown Ethers: An Application to Palladium-Catalyzed Asymmetric Allylation of -Diketones Sawamura, M.; Nagata, H.; Sakamoto, H.; Ito, Y. J. Am. Chem. Soc. 1992, 114, 2586-2592. |
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18. Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. 10: Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate Hayashi, T.; Sawamura, M.; Ito, Y. Tetrahedron 1992, 48, 1999-2012. |
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17. A Trans-Chelating Chiral Diphosphine Ligand: 2,2"-Bis[1-(diphenylphosphino)-ethyl]-1,1"-biferrocene and its Complexes with Platinum(II) and Palladium(II) Sawamura, M.; Hamashima, H.; Ito, Y. Tetrahedron: Asymmetry 1991, 2, 593-596. |
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16. Synthesis of 2,2"-Bis(diphenylphosphino)-1,1"-biferrocene, a Planar Chiral Bisphosphine, and its Palladium(II) Complex Sawamura, M.; Yamauchi, A.; Takegawa, T.; Ito, Y. Chem. Commun. 1991, 874-875. |
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15. The Asymmetric Aldol Reaction of Tosylmethyl Isocyanide and Aldehydes Catalyzed by Chiral Silver(I) Complexes Sawamura, M.; Hamashima, H.; Ito, Y. J. Org. Chem. 1990, 55, 5935-5936. |
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14. Silver(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate Hayashi, T.; Uozumi, Y.; Yamazaki, A.; Sawamura, M.; Hamashima, H.; Ito, Y. Tetrahedron Lett. 1991, 32, 2799-2802. |
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13. NMR Studies of the Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate Sawamura, M.; Ito, Y.; Hayashi, T. Tetrahedron Lett. 1990, 31, 2723-2726. |
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12. Asymmetric Aldol Reaction of -Ketoesters with Isocyanoacetate and Isocyanoacetamide Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Hamashima, H.; Emura, T.; Hayashi, T. Tetrahedron Lett. 1989, 30, 4681-4684. |
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11. Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Sawamura, M.; Ito, Y.; Hayashi, T. Tetrahedron Lett. 1989, 30, 2247-2250. |
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10. Asymmetric Aldol Reaction of -Isocyanoacetamides with Aldehydes Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Kobayashi, M.; Hayashi, T. Tetrahedron Lett. 1988, 29, 6321-6324. |
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9. Asymmetric Synthesis of -Hydroxy--alkylamino Acids by Asymmetric Aldol Reaction of -Isocyanocarboxylates Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T. Tetrahedron 1988, 44, 5253-5262. |
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8. Asymmetric Synthesis of Threo- and Erythro-Sphingosines by Asymmetric Aldol Reaction of -Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Hayashi, T. Tetrahedron Lett. 1988, 29, 239-240. |
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7. Asymmetric Aldol Reaction of -Isocyanocarboxylates with Paraformaldehyde Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Catalytic Asymmetric Synthesis of -Alkylserines Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T. Tetrahedron Lett. 1988, 29, 235-238. |
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6. Selective C-Alkylation of -Diketones Shono, T.; Kashimura, S.; Sawamura, M.; Soejima, T. J. Org. Chem. 1988, 53, 907-910. |
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5. Asymmetric Aldol Reaction of an Isocyanoacetate with Aldehydes Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes Ito, Y.; Sawamura, M.; Hayashi, T. Tetrahedron Lett. 1987, 28, 6215-6218. |
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4. Palladium-Catalyzed Allylation of -Isocyanocarboxylates Ito, Y.; Sawamura, M.; Matsuoka, M.; Matsumoto, Y.; Hayashi, T. Tetrahedron Lett. 1987, 28, 4849-4852. |
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3. Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Hayashi, T. J. Am. Chem. Soc. 1986, 108, 6405-6406. |
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2. Trimethylchlorosilane Induced Ring Opening of 2-Alkyloxazolidines to Enamine Derivatives Ito, Y.; Sawamura, M.; Kominami, K.; Saegusa, T. Tetrahedron Lett. 1985, 26, 5303-5306. |
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1. New Systems for the Storage of Electricity Using Nitrile and Iodine as the Anodic Active Substances Shono, T.; Sawamura, M.; Kashimura, S. Chem. Commun. 1984, 1204-1205. |
Reviews
37. Boron Catalysis in the Transformation of Carboxylic Acids and Carboxylic Acid Derivatives Sawamura, M.; Shimizu, Y. Eur. J. Org. Chem., in press. DOI: 10.1002/ejoc.202201249 |
36. ポリスチレン架橋ホスフィンに基づく不均一系遷移金属触媒の開発とフロー反応システムへの応用 岩井智弘,三浦佳子,澤村正也 THE CHEMICAL TIMES, 263, 12-16 (2022) |
35. Copper-Catalyzed Reactions of Alkylboranes Ohmiya, H.; Sawamura, M. Bull. Chem. Soc. Jpn.,2021, 94, 197–203. DOI: 10.1246/bcsj.20200283 |
34. The Scope of 3-Acetyl-4-hydroxy-6-methyl-2H-pyran-2-one (DHA) Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S. Curr. Org. Chem., 2020, 24, 1459–1490. DOI: 10.2174/1385272824999200622114328 |
33. Construction of Medium-Sized Rings by Gold Catalysis Reyes, R. L.; Iwai, T.; Sawamura, M. Chem. Rev. 2021, 121, 8926–8947. (DOI: 10.1021/acs.chemrev.0c00793) |
32. Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-[[(1R)-2'-[(triisopropylsilyl)oxy][1,1'-binaphthalen]-2-yl]oxy]-, (11bR)-(9CI) Reyes, R. L.; Sawamura, M. Electronic Encyclopedia of Reagents for Organic Synthesis, Rovis T., Ed.; Wiley. http://onlinelibrary.wiley.com/doi/10.1002/047084289X.rn02326 |
31. anti Boron Addition to Alkynes Sawamura, M.; Ohmiya, H. In Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, Fernández, E., Ed.; Thieme: Stuttgart,; Chapter 5, pp 105-130 (2019). DOI: 10.1055/sos-SD-230-00048 |
30. 固体表面を利用した配位子設計:活性サイトの孤立化に基づく高活性金属錯体触媒の開発 岩井智弘,澤村正也 触媒技術の動向と展望2019, 触媒学会(編), 113–123 (2019). |
29. 配位子つくって30年 澤村正也 OM News, 12–17 (2018). |
28. ナノと有機合成(巻頭言) 澤村正也 有機合成化学協会誌 (巻頭言), 74, 581 (2016). |
27. 銅触媒の機能化に基づく高選択的合成反応の開発 大宮寛久・澤村正也 月刊「化学工業」(特集「戦略的触媒開発と応用」), 67, 361– 366 (2016). |
26. Transition-metal-catalyzed Site-selective C–H Functionalization of Quinolines beyond C2 Selectivity. Iwai, T.; Sawamura, M. ACS Catal. 2015, 5, 5031-5040. DOI 10.1021/acscatal.5b01143 |
25. Transition Metal Catalysis with Hollow-shaped Triethynylphosphine Ligands. Iwai, T.; Sawamura, M. Bull. Chem. Soc. Jpn. 2014, 87, 1147–1160. (Award Account) DOI: 10.1246/bcsj.20140186 |
24. Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes. Ohmiya, H.; Sawamura, M. J. Synth. Org. Chem. Jpn. 2014, 72 (Special Issue in English), 1207–1217. |
23. High-Density Monolayer of Metal Complex: Preparation and Catalysis. Hara, K.; Sawamura, M.; Fukuoka, A.. Chem. Rec. 2014, 14, 869–878. DOI: 10.1002/tcr.201402031 |
22. Carbon–Boron and Carbon–Silicon Bond Formation. M. Sawamura, H. Ito, In Copper-Catalyzed Asymmetric Synthesis; A. Alexakis, N. Krause, S. Woodword, Ed.; Wiley-VCH: Weinheim, Chapter 6, pp 157–177, 2014. |
21. シリカ固定化かご型ホスフィンSilica-SMAPおよびSilica-TRIPに基づく有機合成触媒反応の開発. 澤村正也 和光純薬時報,82, pp 2-6, 2014. |
20. 不活性sp3-C–H結合の化学変換—触媒設計によるチャレンジ 川守田創一郎・澤村正也 化学,68, pp 72–73, 2013. |
19. Development of Heterogeneous Catalysts through Immobilization of Caged Phosphine Ligand SMAP Sawamura, M. Catalysts and Catalysis. 2010, 52, 249-254. |
18. γ位選択的ボリル化反応 澤村正也・伊藤肇 使える!有機合成反応241実践ガイド,丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著,化学同人,pp 314-315, 2010. |
17. γ位選択的アリル-アリール結成生成反応 澤村正也 使える!有機合成反応241実践ガイド,丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著,化学同人,pp 164-165, 2010. |
16. Air-Stable, Compact, Caged Trialkylphosphines (SMAPs): Synthesis, Properties and Applications to Homogeneous and Heterogeneous Catalysis Sawamura, M. J. Synth. Org. Chem., Jpn. 2009, 67, 1125-1135. |
15. Copper-Catalyzed Substitution of Allylic Carbonates with Diboron: A New Approach to Allylboronate Synthesis Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M. Pure Appl. Chem. 2008, 80, 1039-1045. |
14. Rhodium-Catalyzed Asymmetric Hydrogenation of Indoles. Kuwano, R.; Sawamura, M. In Catalysts for Fine Chemical Synthesis; Regio- and Stereo- Controlled Oxidations and Reductions Roberts, S. M., Whittall, J., Eds.; John Wiley & Sons: West Sussex, 2007; Vol. 5, p 73-86. |
13. Synthesis and Properties of SMAPs 1-Phospha-4-silabicyclo[2.2.2]octane Derivatives Ochida, A.; Sawamura, M. ARKIVOC 2006, 359-369. |
12. L-プロリン触媒を用いる不斉アルドール反応 澤村正也 有機合成のための触媒反応103,檜山為次郎・野崎京子編,東京化学同人,pp 90-91, 2004. |
11. 遷移金属錯体を用いるアルドール反応 澤村正也 有機合成のための触媒反応103,檜山為次郎・野崎京子編,東京化学同人,pp 88-89, 2004. |
10. 金(Au)澤村正也・伊藤肇有機金属反応剤ハンドブック-3Liから83Biまで,玉尾皓平編著,化学同人,pp 243-245, 2003. |
9. 有機フラーレンの形作る超分子構造-膜と液晶- 中村栄一・松尾豊・磯部寛之・澤村正也 未来材料, 2003, 3, 6-12. |
8. 銅(I)ヒドリド錯体の触媒作用における不斉配位子加速効果 澤村正也 Organometallic News, 2002, 15. |
7. Chemistry of 5-Fullerene Metal Complexes. E. Nakamura, M. Sawamura Pure Appl. Chem., 2001, 73, 355-359. |
6. フラーレン類の反応-化学修飾と機能分子設計 中村栄一・澤村正也・磯部寛之 季刊化学総説「炭素第三の同素体フラーレンの化学」,日本化学会編,学会出版センターVol.43, chapter III-13, pp 165-171, 1999. |
5. Silver and Gold Reagents. M. Sawamura, In Lewis Acid reagents: A Practical Approach H. Yamamoto, Ed.; Oxford University Press.: Oxford, chapter 9, pp 169-176, 1999. |
4. Fullerene That Binds a Metal on the Pentagon. E. Nakamura, M. Sawamura, H. Iikura, S. Mori Proc. Electrochem. Soc. 97-14 (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials) 1997, 97-14, 298-308 |
3. 金-α-イソシアノカルボン酸類の不斉アルドール反応 沢村正也 季刊化学総説「金属反応剤を用いる不斉化学合成」,日本化学会編,学会出版センターVol. 19, chapter 11, pp 129-141, 1993. |
2. Asymmetric Aldol Reaction. M. Sawamura, Y. Ito, In Catalytic Asymmetric SynthesisI. Ojima, Ed.; VCH, Publishers, Inc.: New York, Chapter 7, pp 367-388, 1993. |
1. Catalytic Asymmetric Synthesis by Means of Secondary Interaction between Chiral Ligands and Substrates. M. Sawamura, Y. Ito Chem. Rev., 1992, 92, 857-871. |