ICReDD Specially Appointed Assis. Prof. Higashida

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Dr. Kosuke Higashida (Original papers/Review)

Original papers

17.
Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold-Zinc Two-Metal Catalysis for
Intermolecular Addition of O-Nucleophiles to Non-activated Alkynes.

Rawat, V. K.; Higashida, K.; Sawamura, M.
ACS Catal., 2022, 12, 8325-8330. (DOI: 10.1021/acscatal.2c01701 

16.
Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetic Acid Derivatives Enabled by Cooperative Participation of
Classical and Nonclassical Hydrogen Bonds.

Sakai, S.; Fujioka, A.; Imai, K.; Uchiyama, K.; Shimizu, Y.; Higashida, K.; Sawamura, M.
Adv. Synth. Catal.
, 2022364, 2333-2339. (DOI: 10.1002/adsc.202200327)

15.
Insights into the Mechanism of Enantioselective Copper-Catalyzed Ring-Opening Allylic Alkylation of Cyclopropanols.
Kitabayashi, A.; Mizushima, S.; Higashida, K.; Yasuda, Y.;  Shimizu, Y.;  Sawamura, M. 
Adv. Synth. Catal.2022, 364, 1855-1862 (DOI: 10.1002/adsc.202200157)

14.
Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands
Niizeki, R.; Higashida, K.; Mejri, E.; Sawamura, M.; Shimizu, Y.
Synlett, 2022,32, 288-292. (DOI: 10.1055/a-1673-9236)
13.
Nickel-catalyzed Homo-coupling of Aryl Ethers with Magnesium Anthracene Reductant
Rawat, V. K.; Higashida, K.;  Sawamura, M.
Synthesis2021, 53, 3397-3403. (DOI: 10.1055/a-1509-5954)
12.
Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids
Rawat, V. K.; Higashida, K.;  Sawamura, M.
Adv. Synth. Cat., 2021, 363, 1631–1637.(DOI: 10.1002/adsc.202001515)
11.
Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms

You, Z.; Higashida, K.; Iwai,T.; Sawamura, M.
Angew. Chem. Int. Ed., 2021, 90, 5778–5782. (DOI: 10.1002/anie.202013544)
10.
Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions
Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.;  Mori, S.; Sawamura, M.
Adv. Synth. Catal. 2020, 362, 4655–4661. (DOI: 10.1002/adsc.202000615)
9.
Site-selective trans-Hydrostannation of 1,3- and 1,n-Diynes. Application to the Total Synthesis of Typhonosides E and F and a Fluorinated Cerebroside Analogue
Mo, X.; Letort, A.; Roşca, D.-A.; Higashida, K.; Fürstner, A.
Chem. Eur. J. 2018, 24, 9667-9674. (DOI: 10.1002/chem.201801344)
8.
Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and –Zinc Base
Castelló-Micó, A.; Nafe, J.; Higashida, K.; Karaghiosoff, K.; Gingras, M.; Knochel, P.
Org. Lett. 2017, 19, 360-363. (DOI: 10.1021/acs.orglett.6b03539)
7.
Iridium-catalyzed Asymmetric Hydrogenation of Tosylamido-Substituted Pyrazines for Constructing Chiral Tetrahydropyrazines with an Amidine Skelton
Higashida, K.; Nagae, H.; Mashima, K.
Adv. Synth. Catal. 2016, 358, 3949-3954. (DOI: 10.1002/adsc.201600852)
6.
Synthesis and Characterization of Heterobimetallic Tantalum–Rhodium and Tantalum–Iridium Complexes Connected by a Tantallacyclopentadiene Fragment
Yamamoto, K.; Higashida, K.; Nagae, H.; Tsurugi, H.; Mashima, K.
Helv. Chim. Acta. 2016, 99, 848-858. (DOI: 10.1002/hlca.201600180)
5.
E-Selective Semi-hydrogenation of Alkynes with Dinuclear Iridium Complexes under Atmospheric Pressure of Hydrogen
Higashida, K.; Mashima, K.
Chem. Lett.
2016, 45, 866-868. (DOI: 10.1246/cl.160410)
4.
Asymmetric Hydrogenation of 3-Amido-2-arylpyridinium Salts by Triply-chloride-bridged Dinuclear Iridium Complexes Bearing Enantiopure Diphosphine Ligands: Synthesis of Neurokinin-1 Receptor Antagonist Derivatives

Iimuro, A.; Higashida, K.; Kita, Y.; Mashima, K.
Adv. Synth. Catal. 2016, 358, 1929-1933. (DOI: 10.1002/adsc.201600203)
3.
Chloride-bridged Dinuclear Rhodium(III) Complexes Bearing Chiral Diphosphine Ligands as New Rhodium(III) Catalyst Precursors for Asymmetric Hydrogenation of Simple Olefins
Kita, Y.; Hida, S.; Higashihara, K.; Jena, H. S.; Higashida, K.; Mashima, K.
Angew. Chem., Int. Ed. 2016, 55, 8299-8303. (DOI: 10.1002/anie.201601748) (Inside Cover)
2.
Asymmetric Hydrogenation of Quinazolinium Salts Catalyzed by Halide-bridged Dinuclear Iridium Complexes Bearing Chiral Diphosphine Ligands
Kita, Y.; Higashida, K.; Yamaji, K.; Iimuro, A.; Mashima, K.
Chem. Commun. 2015, 51, 4380-4382. (DOI: 10.1039/C5CC00258C)
1.
Enhancing Effects of Salt Formation on Catalytic Activity and Enantioselectivity for Asymmetric Hydrogenation of Isoquinolinium Salts by Dinuclear Halide-Bridged Iridium Complexes Bearing Chiral Diphosphine Ligands
Kita, K.; Yamaji, K.; Higashida, K.; Kandula, S.; Iimuro, A.; Mashima, K.
Chem. Eur. J. 2015, 21, 1915-1927. (DOI: 10.1002/chem.201405408) (Cover Picture)

Reviews
2.
Triply-halide-bridged Dinuclear Iridium(III) Complexes with Chiral Diphosphine Ligands as New Easy-handling Iridium Catalysts for Asymmetric Hydrogenation of Imines and N-Heteroaromatics

Mashima, K.; Higashida, K.; Iimuro, A.; Nagae, H.; Kita, Y.
The Chemical Record, 2016, 16, 2585-2594. (DOI: 10.1002/tcr.201600079)
1.
Asymmetric Hydrogenation of Six-membered Monocyclic N-Heteroaromatic Compounds
Iimuro, A.; Higashida, K.; Nagae, H.; Mashima, K.
HETEROCYCLES, 2017, 95, 63-80. (DOI: 10.3987/REV-16-SR(S)1)