ICReDD Specially Appointed Assis. Prof. Higashida

Dr. Kosuke Higashida (Original papers/Review)

Original papers
12.
Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids
Rawat, V. K.; Higashida, K.;  Sawamura, M.
Adv. Synth. Cat., 2021, 363, 1631–1637. (DOI: 10.1002/adsc.202001515)
11.
Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms
You, Z.; Higashida, K.; Iwai,T.; Sawamura, M.
Angew. Chem. Int. Ed., 2021, 90, 5778–5782. (DOI: 10.1002/anie.202013544)
10.
Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions
Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.;  Mori, S.; Sawamura, M.
Adv. Synth. Catal. 2020, 362, 4655–4661. (DOI: 10.1002/adsc.202000615)
9.
Site-selective trans-Hydrostannation of 1,3- and 1,n-Diynes. Application to the Total Synthesis of Typhonosides E and F and a Fluorinated Cerebroside Analogue
Mo, X.; Letort, A.; Roşca, D.-A.; Higashida, K.; Fürstner, A.
Chem. Eur. J. 2018, 24, 9667-9674. (DOI: 10.1002/chem.201801344)
8.
Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and –Zinc Base
Castelló-Micó, A.; Nafe, J.; Higashida, K.; Karaghiosoff, K.; Gingras, M.; Knochel, P.
Org. Lett. 2017, 19, 360-363. (DOI: 10.1021/acs.orglett.6b03539)
7.
Iridium-catalyzed Asymmetric Hydrogenation of Tosylamido-Substituted Pyrazines for Constructing Chiral Tetrahydropyrazines with an Amidine Skelton
Higashida, K.; Nagae, H.; Mashima, K.
Adv. Synth. Catal. 2016, 358, 3949-3954. (DOI: 10.1002/adsc.201600852)
6.
Synthesis and Characterization of Heterobimetallic Tantalum–Rhodium and Tantalum–Iridium Complexes Connected by a Tantallacyclopentadiene Fragment
Yamamoto, K.; Higashida, K.; Nagae, H.; Tsurugi, H.; Mashima, K.
Helv. Chim. Acta. 2016, 99, 848-858. (DOI: 10.1002/hlca.201600180)
5.
E-Selective Semi-hydrogenation of Alkynes with Dinuclear Iridium Complexes under Atmospheric Pressure of Hydrogen
Higashida, K.; Mashima, K.
Chem. Lett.
2016, 45, 866-868. (DOI: 10.1246/cl.160410)
4.
Asymmetric Hydrogenation of 3-Amido-2-arylpyridinium Salts by Triply-chloride-bridged Dinuclear Iridium Complexes Bearing Enantiopure Diphosphine Ligands: Synthesis of Neurokinin-1 Receptor Antagonist Derivatives

Iimuro, A.; Higashida, K.; Kita, Y.; Mashima, K.
Adv. Synth. Catal. 2016, 358, 1929-1933. (DOI: 10.1002/adsc.201600203)
3.
Chloride-bridged Dinuclear Rhodium(III) Complexes Bearing Chiral Diphosphine Ligands as New Rhodium(III) Catalyst Precursors for Asymmetric Hydrogenation of Simple Olefins
Kita, Y.; Hida, S.; Higashihara, K.; Jena, H. S.; Higashida, K.; Mashima, K.
Angew. Chem., Int. Ed. 2016, 55, 8299-8303. (DOI: 10.1002/anie.201601748) (Inside Cover)
2.
Asymmetric Hydrogenation of Quinazolinium Salts Catalyzed by Halide-bridged Dinuclear Iridium Complexes Bearing Chiral Diphosphine Ligands
Kita, Y.; Higashida, K.; Yamaji, K.; Iimuro, A.; Mashima, K.
Chem. Commun. 2015, 51, 4380-4382. (DOI: 10.1039/C5CC00258C)
1.
Enhancing Effects of Salt Formation on Catalytic Activity and Enantioselectivity for Asymmetric Hydrogenation of Isoquinolinium Salts by Dinuclear Halide-Bridged Iridium Complexes Bearing Chiral Diphosphine Ligands
Kita, K.; Yamaji, K.; Higashida, K.; Kandula, S.; Iimuro, A.; Mashima, K.
Chem. Eur. J. 2015, 21, 1915-1927. (DOI: 10.1002/chem.201405408) (Cover Picture)
Reviews
2.
Triply-halide-bridged Dinuclear Iridium(III) Complexes with Chiral Diphosphine Ligands as New Easy-handling Iridium Catalysts for Asymmetric Hydrogenation of Imines and N-Heteroaromatics

Mashima, K.; Higashida, K.; Iimuro, A.; Nagae, H.; Kita, Y.
The Chemical Record, 2016, 16, 2585-2594. (DOI: 10.1002/tcr.201600079)
1.
Asymmetric Hydrogenation of Six-membered Monocyclic N-Heteroaromatic Compounds
Iimuro, A.; Higashida, K.; Nagae, H.; Mashima, K.
HETEROCYCLES, 2017, 95, 63-80. (DOI: 10.3987/REV-16-SR(S)1)