論文リスト

Original papers

  1. Oxyamination of Alkenes Enabled by Direct Photoexcitation of Fluorenone Oxime Derivatives.
    Tagata, A.; Sawamura, M.; Shimizu, Y.
    Chem. Lett., 2024, 53, upae216.
    DOI:10.1093/chemle/upae216

  2. Roles of Divinylbenzene Co-Cross-Linker in a Threefold Cross-Linked Polystyrene-Phosphine Hybrid Monolith: Impact of Cross-Linking Degree on Catalytic Performance.
    Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
    Eur. J. Org. Chem., Early View, 2024, e202400974.
    DOI:10.1002/ejoc.202400974

  3. Photoinduced Enantioselective Triplet Radical Reaction on Metal: Copper-Catalyzed Conjugate Addition of Acylsilanes to α,β-Unsaturated Ketones and Aldehydes.
    Masuda, Y.; Ueda, Y.; Sueki, A.; Shimosato, J.; Nishimura, K.; Gao, M.; Hasegawa, J.; Sawamura, M.
    Chem. Eur. J., 2024, 30, e202402564.
    DOI: 10.1002/chem.202402564
    Front Cover: DOI: 10.1002/chem.202486501

  4. Boron-Catalyzed Michael Reaction of Donor-Acceptor Carboxylic Acid Pairs Enabling Direct Synthesis of 1,5-Dicarboxylic Acids.
    Yoshida, Y.; Sawamura, M.; Shimizu, Y. 
    Org. Lett., 2024, 26, 5425–5429.
    DOI: 10.1021/acs.orglett.4c01542

  5. Gold-Zinc Co-Catalyzed Alkynoate Hydrocarboxylation with N-Protected Amino Acids for Preparation of Storable Acylating Reagents and Racemization-Free Peptide Synthesis
    Sakurada, A.; Sato, M.; Higashida, K.; Sawamura, M.  
    Adv. Synth. Catal., 2024, 366, 2507-2513.
    DOI: 10.1002/adsc.202400286
  6. Photoinduced Platinum-catalyzed Reductive Allylation of α-Diketones with Allylic Carbonates.
    Shimosato, J.; Sawamura, M.; Masuda, Y.  
    Org. Lett., 2024,26, 2023-2028.
    DOI: 10.1021/acs.orglett.4c00091
  7. Photocatalytic Aldehyde C–H Bond Phosphonioethylation with Vinylphosphonium Bromide.
    Mori, H.; Yoshida, M.; Sawamura, M.; Masuda, Y. 
    Asian J. Org. Chem., 2024, 13, e202300532.
    DOI:10.1002/ajoc.202300532
  8. Photocatalytic 1,2-Phosphorus-Migrative [3+2] Cycloaddition of Tri(t-butyl)phosphine with Terminal Alkynes.
    Masuda, Y.; Ikeshita, D.; Higashida, K.; Yoshida, M.; Ishida, N.; Murakami, M.; Sawamura, M.
    J. Am. Chem. Soc., 2023,145, 19060–19066.
    DOI:10.1021/jacs.3c06760
  9. Gold-Zinc Cooperative Catalysis for Seven-exo–dig Hydrocarboxylation of Internal Alkynes.
    Sato, M.; Rawat, V. K.; Higashida, K.; Sawamura, M.  
    Chem. Eur. J., 2023, 29, e202301917.
    DOI: 10.1002/chem.202301917
  10. Sheltering Mono-P-Ligated Metal Complexes in Porous Polystyrene Monolith: Effect of Aryl Pendant Stabilizers on Catalytic Durability.
    Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
    Chem. Eur. J., 2023,29, e202301847.
    DOI:10.1002/chem.202301847
  11. Dimetal-Binding Scaffold 2-(Pyridin-2-yl)imidazo[1,5-b]pyridazine-7-ylidene: Synthesis of Trinuclear Heterobimetallic Complexes Involving Gold–Metal Interactions.
    Kitabayashi, A.; Ono, Y.; Taketsugu, T.; Sawamura, M.; Higashida, K. 
    Chem. Eur. J., 2023, 29, Early View, e202301673(Hot Paper).
    DOI:10.1002/chem.202301673
  12. Sequence-selective Three-component Reactions of Alkyltrifluoroborates with α,β-Unsaturated Carbonyl Compounds and Vinylphosphonium Salts.
    Yoshida, M.; Sawamura, M.; Masuda, Y. 
    Org. Chem. Front., 2023,10, 3654-3661.
    DOI: 10.1039/D3QO00631J
  13. Visible-Light-Induced Aminochlorination of Alkenes.
    Mejri, E.; Higashida, K.; Kondo,Y.; Nawachi, A.; Morimoto, H.; Ohshima, T.; 
    Sawamura, M.; Shimizu, Y. 
    Org. Lett., 2023, 25,in press.
    DOI: 10.1021/acs.orglett.3c01645
  14. Direct α-Trifluoromethylthiolation of Carboxylic Acids Enabled by Boron Catalysis.
    Sun, K.; Huang, C.-Y.(Dennis) ; Sawamura, M.; Shimizu, Y. 
    Synlett, 2023, 34,2210–2214.
    DOI:10.1055/a-2071-4465
  15. Nickel-Catalyzed Defluorophosphonylation of Aryl Fluorides.
    You, Z.; Masuda, Y.; Iwai, T.; Higashida, K.;  Sawamura, M. 
    J. Org. Chem., 2022, 87,14731-14737.
    DOI: 10.1021/acs.joc.2c02048
  16. Photoinduced Alcoholic α-C–H Bond Anti-Markovnikov Addition to Vinylphosphonium Bromides Followed by Wittig Olefination: Two-step Protocol for α-C–H Allylic Alkylation of Alcohols.
    Yoshida, M.; Sawamura, M.; Masuda, Y. 
    ChemCatChem., 2022, 14, e202200744(VIP).
    DOI: 10.1002/cctc.202200744
  17. Construction of Heterobimetallic Catalytic Scaffold with a Carbene-Bipyridine Ligand: Gold-Zinc Two-Metal Catalysis for Intermolecular Addition of O-Nucleophiles to Non-activated Alkynes.
    Rawat, V. K.; Higashida, K.; Sawamura, M.
    ACS Catal., 2022, 12, 8325-8330.
    DOI: 10.1021/acscatal.2c01701
  18. Silver-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetic Acid Derivatives Enabled by Cooperative Participation of Classical and Nonclassical Hydrogen Bonds.
    Sakai, S.; Fujioka, A.; Imai, K.; Uchiyama, K.; Shimizu, Y.; 
    Higashida, K.; Sawamura, M.
    Adv. Synth. Catal., 2022, 364, 2333-2339.
    DOI: 10.1002/adsc.202200327
  19. Insights into the Mechanism of Enantioselective Copper-Catalyzed Ring-Opening Allylic Alkylation of Cyclopropanols.
    Kitabayashi, A.; Mizushima, S.; Higashida, K.; 
    Yasuda, Y.;  Shimizu, Y.;  Sawamura, M.
    Adv. Synth. Catal., 2022, 364,1855-1862.
    DOI: 10.1002/adsc.202200157
  20. Visible Light-Induced Reductive Allylation of Aldehydes by Umpolung Approach.
    Tanaka, I.; Sawamura, M.; Shimizu, Y.
    Org. Lett., 2022, 24, 520–524.
    DOI: 10.1021/acs.orglett.1c03927
  21. Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes.
    Ueda, Y.; Masuda, Y.; Iwai, T.; Imaeda, K.; Takeuchi, H.; Ueno, K.; Gao, M.; Hasegawa, J.; Sawamura, M.
    J. Am. Chem. Soc., 2022, 144, 2218–2224.
    DOI: 10.1021/jacs.1c11526
  22. Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands
    Niizeki, R.; Higashida, K.; Mejri, E.; Sawamura, M.; Shimizu, Y.
    Synlett, 2022,33, 288-292.
    DOI: 10.1055/a-1673-9236
  23. Visible-Light-Driven α-Allylation of Carboxylic Acids
    Sun, K.; Ueno, M.; Imaeda, K.; Ueno, K.; Sawamura, M.; Shimizu, Y.
    ACS Catal., 2021,11, 9722-9728.
    DOI: 10.1021/acscatal.1c02558
  24. Access to Indole-Fused Benzannulated Medium-Sized Rings through Gold(I)-Catalyzed Cascade Cyclization of Azido-Alkynes
    Greiner, L. C.; Inuki, S.;  Arichi, N.; Oishi, S.; Rikito, S.; Iwai, T.; Sawamura, M.; Hashmi, A. S. K.; Ohno, H.
    Chem. Eur. J., 2021, 27, 12992-12997.
    DOI:  10.1002/chem.202101824
  25. Nickel-catalyzed Homo-coupling of Aryl Ethers with Magnesium Anthracene Reductant
    Rawat, V. K.; Higashida, K.;  Sawamura, M.
    Synthesis, 2021, 53, 3397-3403. 
    DOI: 10.1055/a-1509-5954
  26. A Hollow-Shaped Caged Triarylphosphine: Synthesis, Characterization and Applications to Gold(I)-Catalyzed 1,8-Enyne Cycloisomerization
    Iwai,T.; Goto,Y.; You, Z.; Sawamura, M.
    Chem. Lett., 2021, 50, 1236-1239.
    DOI: 10.1246/cl.210176
  27. Use of Imidazo[1,5-a]pyridin-3-ylidene as a Platform for Metal-Imidazole Cooperative Catalysis: Silver-Catalyzed Cyclization of Alkyne-Tethered Carboxylic Acids
    Rawat, V. K.; Higashida, K.;  Sawamura, M.
    Adv. Synth. Cat., 2021, 363, 1631–1637.
    DOI: 10.1002/adsc.202001515
  28. Phosphinylation of Non-activated Aryl Fluorides through Nucleophilic Aromatic Substitution at the Boundary of Concerted and Stepwise Mechanisms
    You, Z.; Higashida, K.; Iwai,T.; Sawamura, M.
    Angew. Chem. Int. Ed., 2021, 90, 5778–5782.
    DOI: 10.1002/anie.202013544
  29. Synthesis of 2-Hydroxy-2-pyridinone Derivatives and Evaluation of Their Antioxidant/Anticancer ActivitiesHamama, W. S.;  Ghaith, E. A.; Ibrahim, M. E.; Sawamura, M.; Zoorob, H. H.
    ChemistrySelect, 2021, 6, 1430–1439.
    DOI: 10.1002/slct.202004682
  30. Dumbbell-Shaped 2,2’-Bipyridines: Controlled Metal Monochelation and Application to Ni-Catalyzed Cross-CouplingsKim, Y.; Iwai T.; Fujii,S.; Ueno, K.; Sawamura, M.
    Chem. Eur. J., 2021, 27, 2289–2293.
    DOI: 10.1002/chem.202004053
  31. Convenient Synthesis of Binary and Fused Pyrazole Ring Systems: Accredited by Molecular Modeling and Biological Evaluation
    Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S.ChemistrySelect. 2020, 5, 14917–14923.
    DOI: 10.1002/slct.202004014
  32. Polystyrene-Cross-Linking Triphenylphosphine on Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic FlowMatsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
    Ind. Eng. Chem. Res. 2020, 59, 15179–15187.
    DOI: 10.1021/acs.iecr.0c02404
  33. Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions
    Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.;  Mori, S.; Sawamura, M.
    Adv. Synth. Catal. 2020, 362, 4655–4661.
    DOI: 10.1002/adsc.202000615 
  34. Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine
    Zhang, D.; Iwai, T.; Sawamura, M.
    Org. Lett. 2020, 22, 5240–5245.
    DOI: 10.1021/acs.orglett.0c01905
  35. Polystyrene‐Supported PPh3 in Macroporous Monolith: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C‐C Cross‐Coupling of Aryl Chlorides
    Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y.
    ChemCatChem 2020, 12, 4034–4037.
    DOI: 10.1002/cctc.202000651
  36. Copper-Catalyzed Enantioselective Conjugate Reduction of α,β-Unsaturated Esters with Phenol-Carbene Chiral Ligand
    Mimura, S.; Mizushima, S.; Shimizu, Y.; Sawamura, M.
    Beilstein J. Org. Chem. 2020, 16, 537–543.
    DOI: 10.3762/bjoc.16.50
  37. Boron-Catalyzed α-Amination of Carboxylic Acids
    Morisawa, T.; Sawamura, M.; Shimizu, Y.
    Org. Lett. 2019, 21, 7466–7469.
    DOI: 10.1021/acs.orglett.9b02769
  38. Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor
    Zhang, D.; Iwai, T.; Sawamura, M.
    Org. Lett. 2019, 21, 5867–5872
    DOI: 10.1021/acs.orglett.9b01989
  39. Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines.
    Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M.
    J. Am. Chem. Soc. 2019, 141, 7261–7265.
    DOI: 10.1021/jacs.9b02751
  40. Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes
    Ueda, Y.; Iwai, T.; Sawamura, M
    Chem. Eur. J. 2019, 25, 9410–9414.
    DOI: 10.1002/chem.201900822
  41. Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand
    Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M.
    Adv. Synth. Catal. 2019, 361, 2250–2254.
    DOI: 10.1002/adsc.201801713
  42. Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand
    Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M.
    Org. Lett. 2019, 21, 1717–1721.
    DOI:10.1021/acs.orglett.9b00276
  43. A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides
    Arashima, J.; Iwai, T.; Sawamura, M.
    Chem. Asian J. 2019, 14, 411–415.
    DOI: 10.1002/asia.201801651
  44. P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization
    Iwai, T.; Shibaike, M.; Sawamura, M.
    Chem. Lett. 2018, 47, 1162–1164.
    DOI: 10.1246/cl.180501
  45. Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines
    Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M.
    Angew. Chem. Int. Ed. 2018, 57, 9465–9469.
    DOI: 10.1002/anie.201802821
  46. Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand
    Konishi, S.; Iwai, T.; Sawamura, M.
    Organometallics 2018, 37, 1876–1883.
    DOI: 10.1021/acs.organomet.8b00113
  47. Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes
    Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2018, 20, 1861–1865.
    DOI: 10.1021/acs.orglett.8b00390
  48. Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of  a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions
    Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M.
    Chem. Sci. 2018, 9, 3484–3493.
    DOI: 10.1039/C8SC00527C
  49. Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation
    Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M.
    Chem. Lett. 2018, 47, 632–635.
    DOI: 10.1246/cl.180147
  50. Copper-Catalyzed Enantioselective Coupling between Allylboronates and Phosphates with a Phenol-Carbene Chiral Ligand: Asymmetric Synthesis of Chiral Branched 1,5-Dienes
    Yasuda, Y.; Ohmiya, H.; Sawamura, M.
    Synthesis 2018, 50, 2235–2246.
    DOI: 10.1055/s-0036-1591548
  51. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted g-Borylallylboranes
    Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2018, 57, 3196–3199.
    DOI: 10.1002/anie.201712351
  52. Nickel-Catalyzed Amination of Aryl Fluorides with Primary Amines
    Harada, T.; Ueda, Y.; Iwai, T.; Sawamura, M.
    Chem. Commun. 2018, 54, 1718–1721.
    DOI: 10.1039/C7CC08181B
  53. Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition
    Iwai, T.; Ueno, M.; Okochi, H.; Sawamura, M.
    Adv. Synth. Catal. 2018, 360, 670–675.
    DOI: 10.1002/adsc.201701193
  54. Polystyrene-Cross-Linking Ortho-Substituted Triphenylphosphines: Synthesis, Coordination Properties, and Application to Pd-Catalyzed Cross-Coupling of Aryl Chlorides
    Iwai, T.; Asano, K.; Harada, T.; Sawamura, M.Bull. Chem. Soc. Jpn. 2017, 90, 943–949.
    DOI: 10.1246/bcsj.20170141
  55. Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.
    Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M.
    Chem. Eur. J. 2017, 23, 8400–8404.
    DOI: 10.1002/chem.201702070
  56. Exploring the Full Catalytic Cycle of Rhodium(I)–BINAP-Catalysed Isomerization of Allylic Amines: A Graph Theory Approach for Path Optimisation.
    Yoshimura, T.; Maeda, S.; Taketsugu, T.; Sawamura, M.; Morokuma, K.; Mori, S.
    Chem. Sci. 2017, 8, 4475–4488.
    DOI: 10.1039/C7SC00401J
  57. Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides.
    Hojoh, K.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2017, 139, 2184–2187.
    DOI: 10.1021/jacs.6b12881
  58. A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis.
    Iwai, T.; Harada, T.; Shimada, H.; Asano, K.; Sawamura, M.
    ACS Catal. 2017, 7, 1681–1692.
    DOI: 10.1021/acscatal.6b02988
  59. Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines.
    Iwai, T.; Tanaka, R.; Sawamura, M.
    Organometallics, 2016, 35, 3959-3969.
    DOI: 10.1021/acs.organomet.6b00752
  60. Copper-Catalyzed Enantioselective Allyl–Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand.
    Yasuda, Y.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed., 2016, 55,10816-10820.
    DOI: 10.1002/anie.201605125
  61. Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates.                                    
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Org. Lett., 2016, 18, 1706-1709.
    DOI: 10.1021/acs.orglett.6b00677
  62. Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen.
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Organometallics, 2016, 35, 1354-1357.
    DOI: 10.1021/acs.organomet.6b00126
  63. Site-selective and Stereoselective C(sp3)–H Borylation of Alkyl Side Chains of 1,3-Azoles with a Silica-Supported Monophosphine-Ir Catalyst.
    Murakami, R.; Iwai, T.; Sawamura, M.
    Synlett., 2016, 27, 1187-1192.
    DOI: 10.1055/s-0035-1561599
  64. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles.
    Ohmiya, H.; Zhang, H.; Shibata, S.; Harada, A.; Sawamura, M.
    Angew. Chem. Int. Ed., 2016, 55, 4777-4780.
    DOI:10.1002/anie.201600619
  65. Copper-Catalyzed Stereoselective Conjugate Addition of Alkylboranes to Alkynoates.
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Beilstein J. Org. Chem., 2015, 11, 2444–2450.
    DOI:10.3762/bjoc.11.265
  66. Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-coupling of Chloroarenes.
    Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M.
    ACS Catal., 2015, 5, 7254–7264.
    DOI: 10.1021/acscatal.5b00904
  67. Synthesis of 1,1-Diborylalkenes through a Brønsted-base-catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron.
    Morinaga, A.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed., 2015, 54, 15859-15862.
    DOI: 10.1002/anie.201509218
  68. Synthesis and Structures of a Chiral Phosphine-Phosphoric Acid Ligand and Its Rhodium(I) Complexes.
    Iwai, T.; Akiyama, Y.; Tsunoda, K.; Sawamura, M.
    Tetrahedron:Asymmetry, 2015, 26, 1245–1250.
    DOI: 10.1016/j.tetasy.2015.09.016
  69. Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes.
    Hojoh, K.; Shido, Y.; Nagao, K.; Mori, S.; Ohmiya, H.; Sawamura, M.
    Tetrahedron, 2015, 71, 6519–6533.
    DOI:10.1016/j.tet.2015.05.048
  70. Copper-Catalyzed g-Selective and Stereospecific Allylic Cross-Coupling with Secondary Alkylboranes.
    Yasuda, Y.; Nagao, K.; Shido, Y.;  Mori, S.; Ohmiya, H.; Sawamura, M.
    Chem. Eur. J. 2015, 21, 9666-9670.
    DOI: 10.1002/chem.201501055
  71. Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes
    Murayama, H.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2015, 17,  2039–2041.
    DOI: 10.1021/acs.orglet.5b00758
  72. Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis.
    Nagao, K.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2015, 17, 1304–1307.
    DOI: 10.1021/acs.orglett.5b00305
  73. Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles.
    Harada, A.; Makida, Y.; Sato, T.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2014, 136, 13932–13939.
    DOI: 10.1021/ja508433
  74. Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes.
    Nagao, K.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2014, 136, 10605–10608.
    DOI: 10.1021/ja506310v
  75. Stereoselective C–H Borylations of Cyclopropanes and Cyclobutanes with Silica-supported Monophosphane-Ir Catalysts.
    Murakami, R.; Tsunoda,K.; Iwai, T.; Sawamura, M.
    Chem. Eur. J. 2014, 20, 13127–13131.
    DOI: 10.1002/chem.201404362
  76. Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes. 
    Hojoh, K.; Shido,Y.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2014, 53, 4954–4958 (Hot Paper).
    DOI: 10.1002/anie.201402386.
  77. Silica-Supported Tripod Triarylphosphane: Application to Transition Metal Catalyzed C(sp3)–H Borylations.
    Iwai, T.; Murakami, R.; Harada,T.; Kawamorita, S.; Sawamura, M.
    Adv. Synth. Catal. 2014, 356, 1563–1570.
    DOI: 10.1002/adsc.201301147
  78. Silica-supported Tripod Triarylphosphines: Application to Palladium Catalyzed Borylation of Chloroarenes.
    Iwai, T.; Harada, T.; Tanaka, R.; Sawamura, M.Chem. Lett. 2014, 43, 584–586.
    DOI: 10.1246/cl.131161
  79. Tripod Immobilization of Triphenylphosphane on a Silica Gel Surface to Enable Selective Mono-P-ligation to Palladium: Application to Suzuki–Miyaura Cross-Coupling with Chloroarenes.
    Iwai, T.; Tanaka, R.; Harada, T.; Sawamura, M.
    Chem. Eur. J. 2014, 20, 1057–1065.
    DOI: 10.1002/chem.201304081
  80. Site-selective C–H Borylation of Quinolines at the C-8 Position Catalyzed by a Silica-supported Phosphane-Iridium System.
    Konishi, S.; Kawamorita, S.; Iwai, T.; Steel, P. G.; Marder, T. B.; Sawamura, M.
    Chem. Asian J. 2014, 9, 434-438.
    DOI: 10.1002/asia.201301423
  81. Friedel-Crafts Functionalization of Cyclopentadienyl Ligand in Bucky Metallocenes.
    Matsuo, Y.; Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura ,E.
    Dalton Trans. 2014, 43, 7407–7412.
    DOI: 10.1039/C3DT52002A
  82. Threefold Cross-Linked Polystyrene-Triphenylphosphane Hybrids: Mono-P-Ligating Behaviors and Catalytic Applications for Aryl Chloride Cross-Coupling and C(sp3)–H Borylation.
    Iwai, T.; Harada, T.; Hara, K.; Sawamura, M.
    Angew. Chem. Int. Ed. 2013, 52, 12322–12326.
    DOI: 10.1002/anie.201306769
  83. Synthesis of Trisubstituted Alkenylstannanes through Copper-Catalyzed Three-Component Coupling with Alkylboranes, Alkynoates, and Tributyltin Methoxide.
    Wakamatsu, T.; Nagao, K.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2013, 52, 11620–11623.
    DOI: 10.1002/anie.201305973
  84. Cooperative Catalysis of Metal and O–H···O/sp3-C–H···O Two-point Hydrogen Bonds in Alcoholic Solvents: Copper-catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes.
    Ishii, T.; Watanabe, R.; Moriya, T.; Ohmiya, H.; Mori, S.; Sawamura,M.
    Chem. Eur. J. 2013, 19, 13547–13553.
    DOI: 10.1002/chem.201301280
  85. Synthesis of a Chiral N-Heterocyclic Carbene Bearing a m-Terphenyl-Based Phosphate Moiety as an Anionic N-Substituent and Its Application to Copper-Catalyzed Enantioselective Boron Conjugate Addition.
    Iwai, T.; Akiyama, Y.; Sawamura, M.
    Tetrahedron: Asymmetry 2013, 24, 729–735.
    DOI: 10.1016/j.tetasy.2013.05.013
  86. Copper-Catalyzed g-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes.
    Makida, Y.; Takayama, Y.; Ohmiya, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2013, 52, 5350–5354.
    DOI: 10.1002/anie.201300785
  87. Synthesis of Primary and Secondary Alkylboronates through Site-Selective C(sp3)–H Activation with Silica-Supported Monophosphine–Ir Catalysts
    Kawamorita, S.; Murakami, R; Iwai, T.; Sawamura, M.
    J. Am. Chem. Soc. 2013, 135, 2947–2950.
    DOI: 10.1021/ja3126239
  88. Construction of Eight-Membered Carbocycles via Gold Catalysis with Acetylene-Tethered Silyl Enol Ethers.
    Iwai, T.; Okochi, H.; Ito, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2013, 52, 4239-4242.
    DOI: 10.1002/anie.201300265
  89. Use of a Semihollow-Shaped Triethynylphosphane Ligand for Efficient Formation of Six- and Seven-Membered Ring Ethers through Gold(I)-Catalyzed Cyclization of Hydroxy-Tethered Propargylic Esters.
    Ito, H.; Harada, A.; Ohmiya, H.; Sawamura, M.
    Adv. Synth. Cat. 2013, 355, 647–652.
    DOI: 10.1002/adsc.201200949
  90. Copper-Catalyzed Enantioselective Allylic Substitution with Alkylboranes.
    Shido, Y.; Yoshida M.; Tanabe, M.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2012, 134, 18573–18576.
    DOI: 10.1021/ja3093955
  91. Conjugate Reduction of a,b-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane–Copper Complex.
    Kawamorita, S.; Yamazaki, K.; Ohmiya, H.; Iwai, T.;  Sawamura, M.
    Adv. Synth. Catal. 2012, 354, 3440–3444.
    DOI: 10.1002/adsc.201200555
  92. Rh-Catalyzed Borylation of N–Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand.
    Kawamorita, S.; Miyazaki, T.; Iwai, T.; Ohmiya, H.;  Sawamura, M.
    J. Am. Chem. Soc. 2012, 134, 12924–12927.
    DOI: 10.1021/ja305694r
  93. Synthesis of Allenylsilanes through Copper-Catalyzed g-Selective Coupling between g-Silylated Propargylic Phosphates and Alkylboranes.
    Yokobori, U.; Ohmiya, H.; Sawamura, M.
    Organometallics 2012, 31, 7909-7913.
    DOI: 10.1021/om300552f
  94. Enantioselective Conjugate Addition of Alkylboranes Catalyzed by a Copper–N-Heterocyclic Carbene Complex.
    Yoshida, M.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2012, 134, 11896–11899.
    DOI: 10.1021/ja304481a
  95. Reversible 1,3-Anti/Syn Stereochemical Courses in Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Chiral Allylic Phosphates and Alkylboranes. 
    Nagao, K.; Yokobori, U.; Makida, Y.; Ohmiya, H.; Sawamura, M. 
    J. Am. Chem. Soc. 2012, 134, 8982–8987.
    DOI: 10.1021/ja302520h
  96. Practical Procedure for Copper(I)-Catalyzed Allylic Boryl Substitution with Stoichiometric Alkoxide Base.  
    Ito, H.; Miya, T.; Sawamura, M. 
    Tetrahedron 2012, 68, 3423-3427.
    DOI: 10.1016/j.tet.2011.08.081
  97. Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed g-Selective Allyl–Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    Nagao, K.; Ohmiya, H.; Sawamura, M. 
    Synthesis 2012, 44, 1535-1541.
    DOI: 10.1055/s-0031-1290818
  98. Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation.
    Makida, Y.; Ohmiya, H.; Sawamura, M. 
    Angew. Chem. Int. Ed. 2012, 51, 4122-4127.
    DOI: 10.1002/anie.201200809
  99. Synthesis of Conjugated Allenes through Copper-Catalyzed g-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates.
    Yang, M.; Yokokawa, N.;Ohmiya, H.; Sawamura, M. 
    Org. Lett.2012, 14, 816-819.
    DOI: 10.1021/ol2033465
  100. Copper(I)-Catalyzed Allylic Substitution of Silyl Nucleophiles through Si–Si Bond Activation.
    Ito, H.; Horita, M.; Sawamura, M. 
     Adv. Synth. Catal.2012,354, 813-817.
    DOI: 10.1002/adsc.201100819
  101. Efficient Preparation of b-Branched g,d-Unsaturated Esters through Copper-Catalyzed Allylic Alkylation of Ketene Silyl Acetal.
    Li, D.; Ohmiya, H.; Sawamura, M. 
    Synthesis2012, 44, 1304-1307.
    DOI: 10.1055/s-0031-1289712
  102. Rh-Catalyzed Ortho-Selective C-H Borylation of N-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands.
    Kawamorita, S.; Miyazaki, T.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    J. Am. Chem. Soc. 2011,133, 19310-19313.
    DOI: 10.1021/ja208364a
  103. General Approach to Allenes through Copper-Catalyzed g-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes.
    Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    Org. Lett. 2011, 13, 6312-6315.
    DOI: 10.1021/ol202866h
  104. Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with Silica-Supported Compact Phosphane Ligand.
    Kawamorita, S.; Ohmiya, H.; Iwai, T.; Sawamura, M.
    Angew. Chem. Int. Ed. (VIP) 2011,50, 8363-8366.
    DOI: 10.1002/anie.201103224
  105. Intramolecular Hydroamination of Alkynic Sulfonamides Catalyzed by Gold-Triethynylphosphine Complex: Construction of Azepine Frameworks by 7-Exo-dig Cyclization.
    Ito, H.; Harada, T.; Ohmiya, H.; Sawamura, M.
    Beilstein. J. Org. Chem. 2011, 7, 951-959.
    DOI: 10.3762/bjoc.7.106
  106. Mechanistic Insight into the Anomalous syn-Selectivity Observed During the Addition of Allenylboronates to Aromatic Aldehydes.
    Sasaki, Y.; Sawamura, M.; Ito, H.
    Chem. Lett. 2011, 40, 1044-1046.
    DOI: 10.1246/cl.2011.1044
  107. Copper-Catalyzed Conjugate Additions of Alkylboranes to Aryl a,b-Unsaturated Ketones.
    Ohmiya, H.; Shido, Y.; Yoshida, M.; Sawamura, M.
    Chem. Lett. 2011, 40, 928-930.
    DOI: 10.1246/cl.2011.928
  108. Copper-Catalyzed g-Selective and Stereospecific Allylic Alkylation of Ketene Silyl Acetals.
    Li, D.; Ohmiya, H.; Sawamura, M.
    J. Am. Chem. Soc. 2011, 133, 5672-5675.
    DOI: 10.1021/ja111645q
  109. Copper-Catalyzed Carboxylation of Alkylboranes with Carbon Dioxide: Formal Reductive Carboxylation of Terminal Alkenes.
    Ohmiya, H.; Tanabe, M.; Sawamura, M.
    Org. Lett. 2011, 13, 1086-1088.
    DOI: 10.1021/ol103128x
  110. Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronate.
    Sasaki, Y.; Horita, Y.; Zhong, C.; Sawamura, M.; Ito, H.
    Angew. Chem. Int. Ed. 2011, 50, 2778-2782.
    DOI: 10.1002/anie.201007182
  111. Copper-Catalyzed Conjugate Additions of Alkylboranes to Imidazolyl a,b-Unsaturated Ketones: Formal Reductive Conjugate Addition of Terminal Alkenes.
    Ohmiya, H.; Yoshida, M.; Sawamura, M.
    Org. Lett. 2011, 13, 482-485.
    DOI: 10.1021/ol102819k
  112. Sulfonamidoquinoline-Palladium(II) Dimer Complex As a Catalyst Precursor for Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling Reaction between Allylic Acetates and Arylboronic Acids.
    Makida, Y.; Ohmiya, H.; Sawamura, M.
    Chem. Asian J.2011, 6, 410-414.
    DOI: 10.1002/asia.201000721
  113. Construction of Methylenecycloheptane Frameworks through 7-Exo-dig Cyclization of Acetylenic Silyl Enol Ethers Catalyzed by Triethynylphosphine-Gold Complex.
    Ito, H.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2010, 12, 4380-4383.
    DOI: 10.1021/ol101860j
  114. Directed Ortho Borylation of Phenol Derivatives Catalyzed by a Silica-Supported Iridium Complex.
    Yamazaki, K.; Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2010, 12, 3978-3981.
    DOI: 10.1021/ol101493m
  115. Direct Enantio-convergent Transformation of Racemic Substrates without Racemization or Symmetrization.
    Ito, H.; Kunii, S.; Sawamura, M.
    Nature Chem. 2010, 2, 972-976.
    DOI: 10.1038/nchem.801
  116. Enantioselective Synthesis of trans-Aryl- and Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative.
    Zhong, C.; Kuni, S.; Kosaka, Y.; Sawamura, M.; Ito, H.
    J. Am. Chem. Soc. 2010, 132, 11140-11142.
    DOI: 10.1021/ja103783p
  117. Protecting-Group-Free Route to Hydroxylated Pyrrolidine and Piperidine Derivatives through Cu(I)-Catalyzed Intramolecular Hydroamination of Alkenes.
    Ohmiya, H.; Yoshida, M.; Sawamura, M.
    Synlett, 2010, 2136-2140.
    DOI: 10.1055/s-0030-1258527
  118. Synthesis of a-Arylated Allylsilanes through Palladium-Catalyzed g-Selective Allyl-Aryl Coupling.
    Li, D.; Tanaka, T.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2010, 12, 3344-3347.
    DOI: 10.1021/ol101114r
  119. Copper-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates
    Ohmiya, H.; Yokokawa, N.; Sawamura, M.
    Org. Lett. 2010, 12, 2438-2440.
    DOI: 10.1021/ol100841y
  120. Ester-Directed Regioselective Borylation of Heteroarenes Catalyzed by a Silica-Supported Iridium Complex.
    Kawamorita, S.; Ohmiya, H.; Sawamura, M.
    J. Org. Chem. 2010, 75, 3855-3858.
    DOI: 10.1021/jo100352b
  121. Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative.
    Ito, H.; Toyoda, T.; Sawamura, M.
    J. Am. Chem. Soc. 2010, 132, 5990-5992.
    DOI: 10.1021/ja101793a
  122. Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.
    Ohmiya, H.; Yang, M.; Yamauchi, Y.; Ohtsuka, Y.; Sawamura, M.
    Org. Lett. 2010, 12, 1796-1799.
    DOI: 10.1021/ol100405k
  123. Copper-Catalyzed g-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes.
    Ohmiya, H.; Yokobori, U.; Makida, Y.; Sawamura, M.
    J. Am. Chem. Soc. 2010, 132, 2895-2897.
    DOI: 10.1021/ja9109105
  124. Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantio-Enriched Cyclic Homoally- and Allylboronates.
    Sasaki, Y.; Zhong, C.; Sawamura, M.; Ito, H.
    J. Am. Chem. Soc. 2010, 132, 1226-1227.
    DOI: 10.1021/ja909640b
  125. Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids.
    Ohmiya, H.; Makida, Y.; Li, D.; Tanabe, M.; Sawamura, M.
    J. Am. Chem. Soc. 2010, 132, 879-889.
    DOI: 10.1021/ja9092264
  126. Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes.
    Ito, H.; Okura, T.; Matsuura, K.; Sawamura, M.
    Angew. Chem. Int. Ed. 2010, 49, 560-563.
    DOI: 10.1002/anie.200905993
  127. General and Functional Group-Tolerable Approach to Allenylsilanes by Rhodium-Catalyzed Coupling between Propargylic Carbonates and a Silylboronate.
    Ohmiya, H.; Ito, H.; Sawamura, M.
    Org. Lett. 2009, 11, 5618-5620.
    DOI: 10.1021/ol902339a
  128. The Synthesis of Allenes by Cu(I)-Catalyzed Regio- and Stereoselective Reduction of Propargylic Carbonates with Hydrosilanes.
    Zhong, C.; Sasaki, Y.; Ito, H.; Sawamura, M.
    Chem. Commun.2009, 5850-5852.
    DOI: 10.1039/b910192f
  129. Gold(I) Hydride Intermediate in Catalysis: Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex.
    Ito, H.; Saito, T.; Miyahara, T.; Zhong, C.; Sawamura, M.
    Organometallics 2009, 28, 4829-4840.
    DOI: 10.1021/om900445w
  130. Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents.
    Ohmiya, H.; Moriya, T.; Sawamura, M.
    Org. Lett. 2009, 11, 2145-2147.
    DOI: 10.1021/ol9007712
  131. Directed ortho-Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System.
    Kawamorita, S.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    J. Am. Chem. Soc. 2009, 131, 5058-5059.
    DOI: 10.1021/ja9008419
  132. Palladium-Catalyzed g-Selective and Stereospecific Allyl-Aryl Coupling between Allylic Acetates and Arylboronic Acids.
    Ohmiya, H.; Makida, Y.; Tanaka, T.; Sawamura, M.
    J. Am. Chem. Soc. 2008, 130, 17276-17277.
    DOI: 10.1021/ja808673n
  133. Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multi-Substituted Allenylboronates.
    Ito, H.; Sasaki, Y.; Sawamura, M.
    J. Am. Chem. Soc. 2008, 130, 15774-15775.
    DOI: 10.1021/ja806602h　
  134. Cyclization of Non-Terminal Alkynic b-Keto Esters Catalyzed by Gold(I) Complex with a Semihollow, End-Capped Triethynylphosphine Ligand.
    Ito, H.; Makida, Y.; Ochida, A.; Ohmiya, H.; Sawamura, M.
    Org. Lett. 2008, 10, 5051-5054.
    DOI: 10.1021/ol802079r
  135. Synthesis of Silica-Supported Compact Phosphines and Their Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones with Triorganosilanes.
    Hamasaka, G.; Kawamorita, S.; Ochida, A.; Akiyama, R.; Hara, K.; Fukuoka, A.; Asakura, K.; Chun, W. J.; Ohmiya, H.; Sawamura, M.
    Organometallics 2008, 27, 6495-6506.
    DOI: 10.1021/om800683g
  136. Hydrogenation of Hindered Ketones Catalyzed by a Silica-Supported Compact Phosphine-Rh System.
    Kawamorita, S.; Hamasaka, G.; Ohmiya, H.; Hara, K.; Fukuoka, A.; Sawamura, M.
    Org. Lett. 2008,10, 4697-4700.
    DOI: 10.1021/ol801996r
  137. Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Catalyzed by Cu(I) Complexes with Wide Bite-Angle Chiral Bisphosphine Ligands: Optimization, Scope and Mechanistic Studies
    Asano, Y.; Ito, H.; Hara, K.; Sawamura, M.
    Organometallics 2008, 27, 5984-5996.
    DOI: 10.1021/om800667c
  138. Synthesis, Properties and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
    Ochida, A.; Hamasaka, G.; Yamauchi, Y.; Kawamorita, S.; Oshima, N.; Hara, K.; Ohmiya, H.; Sawamura, M.
    Organometallics 2008, 27, 5494-5503.
    DOI: 10.1021/om8005728
  139. Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative
    Ito, H.; Kosaka, Y.; Nonoyama, K.; Sasaki, Y.; Sawamura, M.
    Angew. Chem., Int. Ed. 2008, 47, 7424-7427.
    DOI: 10.1002/anie.200802342
  140. Conductance of Single 1,4-Benzenediamine Molecule Bridging between Au and Pt Electrodes
    Kiguchi, M.; Miura, S.; Takahashi, T.; Hara, K.; Sawamura, M.; Murakoshi, K.
    J. Phys. Chem. C 2008, 112, 13349-13352.
    DOI: 10.1021/jp806129u
  141. Reversible Mechanochromic Luminescence of
    Ito, H.; Saito, T.; Oshima, N.; Kitamura, N.; Ishizaki, S.; Hinatsu, Y.; Wakeshima, M.; Kato, M.; Tsuge, K.; Sawamura, M.
    J. Am. Chem. Soc. 2008, 129, 10044-10045.
    DOI: 10.1021/ja8019356　
  142. Synthesis of Metal Fullerene Complexes by the Use of Fullerene Halides
    Matsuo, Y.; Kuninobu, Y.; Muramatsu, A.; Sawamura, M.; Nakamura, E.
    Organometallics 2008, 27, 3403-3409.
    DOI: 10.1021/om8001262
  143. Self-Assembled Monolayer of Compact Phosphane with Alkanethiole Pendant: Remarkable Reusability and Substrate Selectivity in Rh Catalysis
    Hara, K.; Akiyama, R.; Takakusagi, S.; Uosaki, K.; Yoshino, T.; Kagi, H.; Sawamura, M.
    Angew. Chem. Int. Ed. 2008, 47, 5627-5630.
    DOI: 10.1002/anie.200800884
  144. Copper-Catalyzed Enantioselective Substitution of Allylic Carbonates with Diboron: An Efficient Route to Optically Active a-Chiral Allylboronates
    Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M.
    J. Am. Chem. Soc. 2007, 129, 14856-14857.
    DOI: 10.1021/ja076634o
  145. Construction of Self-assembled Monolayer Terminated with N-Heterocyclic Carbene-Rhodium(I) Complex Moiety
    Hara, K.; Iwahashi, K.; Takakusagi, S.; Uosaki, K.; Sawamura, M.
    Surf. Sci. 2007, 601, 5127-5132.
    DOI :10.1016/j.susc.2007.04.158
  146. Design and Synthesis of Isocyanide Ligands for Catalysis: Application to Rh-catalyzed Hydrosilylation of Ketones
    Ito, H.; Kato, T.; Sawamura, M.
    Chem. Asian J. 2007, 2, 1436-1446.
    DOI: 10.1002/asia.200700215
  147. Functionalization of Silicon Surface with Catalytically Active Pd Complex and Application to the Aerobic Oxidation of Benzylic Alcohols
    Hara, K.; Tayama, S.; Kano, H.; Masuda, T.; Takakusagi, S.; Kondo, T.; Uosaki, K.; Sawamura, M.
    Chem. Commun. 2007, 4280-4282.
    DOI: 10.1039/b710820f
  148. Synthesis and Structural Characterization of Tetranuclear Platinum(II) Metallamacrocycle Containing 1,3-Diisocyanoarene Ligands
    Ito, H.; Maeda, T.; Sawamura, M.
    Bull. Chem. Soc. Jpn. 2007, 80, 1981-1986.
    DOI: 10.1246/bcsj.80.1981
  149. Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)-TRAP Complex
    Asano, Y.; Hara, K.; Ito, H.; Sawamura, M.
    Org. Lett. 2007, 9, 3901-3904.
    DOI: 10.1021/ol701534n
  150. Conductance of Single 1,4-Disubstituted Benzene Molecules Anchored to Pt Electrodes
    Kiguchi, M.; Miura, S.; Hara, K.; Sawamura, M.; Murakoshi, K.
    App. Phys. Lett. 2007, 91, 053110.
    DOI: 10.1063/1.2757592
  151. Monocoordinating, Compact Phosphane Immobilized on Silica Surface: Application to Rhodium-Catalyzed Hydrosilylation of Hindered Ketones
    Hamasaka, G.; Ochida, A.; Hara, K.; Sawamura, M.
    Angew. Chem. Int. Ed. 2007, 46, 5381-5383.
    DOI: 10.1002/anie.200700947
  152. Phosphorus Ligands with a Large Cavity: Synthesis of Triethynylphosphines with Bulky End Caps and Application to the Rhodium-Catalyzed Hydrosilylation of Ketones
    Ochida, A.; Sawamura, M.
    Chem. Asian J. 2007, 2, 609-618.
    DOI: 10.1002/asia.200700006
  153. Using Triethynylphosphine Ligands Bearing Bulky End Caps to Create a Holey Catalytic Environment: Application to Gold(I)-Catalyzed Alkyne Cyclizations
    Ochida, A.; Ito, H.; Sawamura, M.
    J. Am. Chem. Soc., 2006, 128, 16486-16487.
    DOI: 10.1021/ja066800c
  154. Conductance of a Single Molecule Anchored by an Isocyanide Substituent to Gold Electrodes
    Kiguchi, M.; Miura, S.; Hara, K.; Sawamura, M.; Murakoshi, K.
    Appl. Phys. Lett. 2006, 89, 213104.
    DOI: 10.1063/1.2392816
  155. Synthesis of New Bulky Isocyanide Ligands and Their Use for Rh-catalyzed Hydrosilylation
    Ito, H.; Kato, T.; Sawamura, M.
    Chem. Lett. 2006, 35, 1038-1039.
    DOI: 10.1246/cl.2006.1038
  156. Ring Carbon Functionalization of N-Heterocyclic Carbene Ligand with Ester Groups: Electronic Effect of the Ester Groups on Coordination Properties
    Hara, K.; Kanamori, Y.; Sawamura, M.
    Bull. Chem. Soc. Jpn. 2006, 79, 1781-1786.
    DOI: 10.1246/bcsj.79.1781
  157. Cyclic Diaminocarbene-Rhodium(I) Complex Tethered to Disulfide: Synthesis and Application to Gold Surface Modification
    Hara, K.; Iwahashi, K.; Kanamori, Y.; Naito, S.; Takakusagi, S.; Uosaki, K.; Sawamura, M.
    Chem. Lett. 2006, 35, 870-871.
    DOI: 10.1246/cl.2006.870
  158. Electronically Tunable Compact Trialkylphosphines: SMAPs Bridged Bicylic Phosphines
    Ochida, A.; Ito, S.; Miyahara, T.; Ito, H.; Sawamura, M.
    Chem. Lett. 2006, 35, 294-295.
    DOI: 10.1246/cl.2006.294
  159. Strong Counter Anion Effects on the Catalytic Activity of Cationic Silicon Lewis Acids in Mukaiyama Aldol and Diels-Alder Reactions
    Hara, K.; Akiyama, R.; Sawamura, M.
    Org. Lett. 2005, 7, 5621- 5623.
    DOI: 10.1021/ol052206g
  160. Copper-Catalyzed g-Selective and Sterespecific Substitution Reaction of Allylic Carbonates with Diboron: Efficient Route to Chiral Allylboron Compounds
    Ito, H.; Kawakami, C.; Sawamura, M.
    J. Am. Chem. Soc. 2005, 127, 16034-16035.
    DOI: 10.1021/ja056099x
  161. Gold(I)-Phosphine Catalyst for the Highly Chemoselective Dehydrogenative Silylation of Alcohols
    Ito, H.; Takagi, K.; Miyahara, T.; Sawamura, M.
    Org. Lett. 2005, 7, 3001-3004.
    DOI: 10.1021/ol050979z
  162. Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)-Phosphine Complex
    Ito, H.; Watanabe, A.; Sawamura, M.
    Org. Lett. 2005, 7, 1869-1871.
    DOI: 10.1021/ol050559+
  163. Creation of Hoop- and Bowl-Shaped Benzenoid Systems by Selective Detraction of [60]Fullerene Conjugation. [10]Cyclophenacene and Fused Corannulene Derivatives
    Matsuo, Y.; Tahara, K.; Sawamura, M.; Nakamura, E.
    J. Am. Chem. Soc. 2004, 126, 8725-8734.
  164. Nickel, Palladium and Platinum Complexes of 5– Cyclopentadienide C60R5 Ligands. Kinetic and Thermodynamic Stabilization Effects of C60Ph5 Ligand
    Kuninobu, Y.; Matsuo, Y.; Toganoh, M.; Sawamura, M.; Nakamura, E.
    Organometallics 2004, 23, 3259-3266.
  165. Multilayer Vesicless and Vesicle Clusters Formed by the Fullerene-based Surfactant C60(CH3)5K
    Burger, C.; Hao, J.; Ying, Q.; Isobe, H.; Sawamura, M.; Nakamura, E.; Chu, B.
    J. Colloid Interface Sci. 2004, 275, 632-641.
  166. Non-volatile Me3P-like P-Donor Ligand: Synthesis and Properties of 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
    Ochida, A.; Hara, K.; Ito, H.; Sawamura, M.
    Org. Lett. 2003, 5, 2671-2674.
    DOI: 10.1021/ol0349099
  167. Regioselective Synthesis of [60]Fullerene 5-Indenide R3C60– and 5-Cyclopentadienide R5C60-Bearing Different R Groups
    Toganoh, M.; Suzuki, K.; Udagawa, R.; Hirai, A.; Sawamura, M.; Nakamura, E.
    Org. Biomol. Chem. 2003, 1, 2604-2611.
  168. Synthesis, Structure, and Aromaticity of a Hoop-Shaped Cyclic Benzenoid [10]Cyclophenacene
    Nakamura, E.; Tahara, K.; Matsuo, Y.; Sawamura, M.
    J. Am. Chem. Soc. 2003, 125, 2834-2835.
  169. Stacking of Conical Molecules with Fullerene Apex into Polar Columns in Crystals and Liquid Crystals
    Sawamura, M.; Kawai, K.; Matsuo, Y.; Kanie, K.; Kato, T.; Nakamura, E.
    Nature 2002, 419, 702-705.
  170. Hybrid of Ferrocene and Fullerene
    Sawamura, M.; Kuninobu, Y.; Toganoh, M.; Matsuo, Y.; Yamanaka, M.; Nakamura, E.
    J. Am. Chem. Soc. 2002, 124, 9354-9355.
  171. Cu(I)-Mediated Regioselective Tri-addition of Grignard Reagent to [70]Fullerene. Synthesis of Indenyl-type Metal Ligand Embedded into Graphitic Structure
    Sawamura, M.; Toganoh, M.; Iikura, H.; Matsuo, Y.; Hirai, A.; Nakamura, E.
    J. Mat. Chem. 2002, 12, 2109-2115.
  172. Regioselective Penta-addition of 1-Alkenyl Copper Reagent to [60]Fullerene. Synthesis of Penta-alkenyl FCp Ligand
    Sawamura, M.; Nagahama, N.; Toganoh, M.; Nakamura, E.
    J. Organomet. Chem. 2002, 652, 31-35.
  173. Epitaxial Growth and Electronic Structure of a C60 Derivative Prepared by Solution Spray Technique
    Shimada, T.; H., N.; Ueno, K.; Koma, A.; Kuninobu, Y.; Sawamura, M.; Nakamura, E.J. Appl. Phys. 2001, 90, 209-212.
  174. Spherical Bilayer Vesicles of Fullerene-Based Surfactants in Water: A Laser Light Scattering Study
    Zhou, S.-Q.; Burger, C.; Chu, B.; Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U. E.; Isobe, H.; Nakamura, E.
    Science     2001, 291, 1944.
  175. Palladium-Catalysed Asymmetric [4+2] Cycloaddition of Vinylallene with 1,3-Diene
    Murakami, M.; Minamida, R.; Itami, K.; Sawamura, M.; Ito, Y.
    Chem. Commun.     2000, 2293-2294.
  176. Functionalized Fullerene as a New Artificial Vector for Transfection
    Nakamura, E.; Isobe, H.; Tomita, N.; Sawamura, M.; Jinno, S.; Okayama, H.
    Angew. Chem. Int. Ed. Engl. 2000, 39, 4254-4257.
  177. Half-Sandwich Metallocene Embedded in a Spherically Extended -Conjugate System. Synthesis, Structure, and Electrochemistry of Rh(5-C60Me5)(CO)2
    Sawamura, M.; Kuninobu, Y.; Nakamura, E.
    J. Am. Chem. Soc. 2000, 122, 12407-12408.
  178. Pentaorgano[60]fullerene R5C60–. A Water Soluble Hydrocarbon Anion
    Sawamura, M.; Nagahama, N.; Toganoh, M.; Hackler, U., E.; Isobe, H.; Nakamura, E.; Zhou, S.-Q.; Chu, B.
    Chem. Lett.     2000, 1098-1099.
  179. Catalytic Asymmetric Hydrogenation of -Acetamidoacrylates Using TRAP Trans-Chelating Chiral Diphosphine Ligands: Remarkable Effects of Ligand P-substituent and Hydrogen Pressure on Enantioselectivity
    Kuwano, R.; Sawamura, M.; Ito, Y.
    Bull. Chem. Soc. Jpn. 2000, 73, 2571-2578.
  180. Rhodium-Catalyzed Enantioselective Michael Addition of (1-Cyanoethyl)-phosphonate: Synthesis of Optically Active Phosphonic Acid Derivatives with Phosphorus-Substituted Quaternary Asymmetric Carbon Center
    Sawamura, M.; Hamashima, H.; Ito, Y.
    Bull. Chem. Soc. Jpn. 2000, 73, 2559-2562.
  181. Stepwise Synthesis of Fullerene Cyclopentadienide R5C60– and Indenide R3C60–. An Approach to Fully Unsymmetrically Substituted Derivatives
    Sawamura, M.; Toganoh, M.; Suzuki, K.; Hirai, A.; Iikura, H.; Nakamura, E.
    Org. Lett.     2000, 2, 1919-1921.
  182. A Cage with Fullerene End Caps
    Isobe, H.; Ohbayashi, A.; Sawamura, M.; Nakamura, E.
    J. Am. Chem. Soc. 2000, 122, 2669-2670.
  183. Synthesis of Pentamethyl-monohydro[60]fullerene C60Me5H and Its Use as Cyclopentadienyl-type Ligand Precursor
    Sawamura, M.; Toganoh, M.; Kuninobu, Y.; Kato, S.; Nakamura, E.
    Chem. Lett. 2000, 270-271.
  184. Asymmetric Hydrosilylation of Ketones Using Trans-Chelating Chiral Peralkyldiphosphine Ligands Bearing Primary Alkyl Substituents on Phosphorus Atoms
    Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y.
    Bull. Chem. Soc. Jpn.     2000, 73, 485-496.
  185. Single-Step Synthesis of Pentaaryl-monohydro[60]fullerenes through Five-Fold Addition of Organocopper Reagent to C60
    Sawamura, M.; Iikura, H.; Ohama, T.; Hackler, U., E.; Nakamura, E.
    J. Organometal. Chem. 2000, 599, 32-36.
  186. Optical Resolution of Chirrally Functionalized [60]Fullerene through Formation of Diastereomeric Methoxyphenyacetic Acid Esters
    Isobe, H.; Sawamura, M.; Nakamura, E.
    Fullerene Sci. Technol.     1999, 7, 519-528.
  187. Synthesis of p-Indenyl-type Fullerene Ligand and Its Metal Complexes via Quantative Trisarylation of C70
    Sawamura, M.; Iikura, H.; Hirai, A.; Nakamura, E.
    J. Am. Chem. Soc. 1998, 120, 8285-8286.
  188. Endohedral Homoconjugation in Cyclopentadiene Embedded in C60
    Iikura, H.; Mori, S.; Sawamura, M.; Nakamura, E.
    J. Org. Chem. 1997, 62, 7912-7913.
  189. Trans-Chelating Chiral Peralkyldiphosphine Ligands (R,R)-(S,S)-2,2″-Bis[1-(dialkylphosphino)ethyl]-1,1″-biferrocenes (AlkylTRAPs) and Their Transition Metal Complexes
    Kuwano, R.; Sawamura, M.; Okuda, S.; Asai, T.; Ito, Y.; Redon, M.; Krief, A.
    Bull. Chem. Soc. Jpn.     1997, 70, 2807-2822.
  190. Synthetic and Computational Studies on Symmetry-Defined Double Cycloaddition of a New Tris-Annulating Reagent to C60
    Isobe, H.; Tokuyama, H.; Sawamura, M.; Nakamura, E.
    J. Org. Chem. 1997, 62, 5034-5041.
  191. Sonochemical, Aerobic Conversion of Alkyl Halides into Alcohols Promoted by Trialkyltin Halide/NaBH3CN Catalytic System
    Sawamura, M.; Kawaguchi, Y.; Sato, K.; Nakamura, E.
    Chem. Lett.     1997, 705-706.
  192. Conversion of Alkyl Halides into Alcohols Using a Near Stoichiometric Amount of Molecular Oxygen: An Efficient Route to 18O- and 17O-Labeled Alcohols
    Sawamura, M.; Kawaguchi, Y.; Nakamura, E.
    Synlett     1997, 801-802.
  193. Enantioselective Allylation of Nitro Group-Stabilized Carbanions Catalyzed by Chiral Crown Ether Phosphine-Palladium Complexes
    Sawamura, M.; Nakayama, Y.; Tang, W.-M.; Ito, Y.
    J. Org. Chem.     1996, 61, 9090-9096.
  194. The First Pentahaptofullerene Metal Complexes
    Sawamura, M.; Iikura, H.; Nakamura, E.
    J. Am. Chem. Soc. 1996, 118, 12850-12851.
  195. Regio- and Diastereo-controlled Double Cycloaddition to [60]fullerene. One-Step Synthesis of Cs and C2 Chiral Organofullerenes with New Tris-Annulating Reagents
    Nakamura, E.; Isobe, H.; Tokuyama, H.; Sawamura, M.
    Chem. Commun.     1996, 1747-1748.
  196. An Enantioselective Two-Component Catalyst System: Rh-Pd-Catalyzed Allylic Alkylation of Activated Nitriles
    Sawamura, M.; Sudoh, M.; Ito, Y.
    J. Am. Chem. Soc.     1996, 118, 3309-3310.
  197. Enantioselective Cycloisomerization of 1,6-Enynes Catalyzed by Chiral Diphosphine-Palladium Complexes
    Goeke, A.; Sawamura, M.; Kuwano, R.; Ito, Y.
    Angew. Chem. Int. Ed. Engl.     1996, 35, 662-663.
  198. Catalytic Asymmetric Hydrogenation of Dimethy Itaconate with Trans-Chelating Chiral Diphosphine Ligands TRAP-Rhodium Complexes
    Kuwano, R.; Sawamura, M.; Ito, Y.
    Tetrahedron: Asymmetry     1995, 6, 2521-2526.
  199. Enantioselective Hydrogenation of -Disubstituted -Acetamidoacrylates Catalyzed by Rhodium Complexes with TRAP Trans-Chelating Chiral Phosphine Ligands
    Sawamura, M.; Kuwano, R.; Ito, Y.
    J. Am. Chem. Soc. 1995, 117, 9602-9603.
  200. Synthesis and Structures of Trans-Chelating Chiral Diphosphine Ligands Bearing Aromatic P-Substituents, (S,S)-(R,R)- and (R,R)-(S,S)-2,2″-Bis[1-(diarylphosphino)ethyl]-1,1″-biferrocenes (ArylTRAPs) and Their Transition Metal Complexes
    Sawamura, M.; Hamashima, H.; Sugawara, M.; Kuwano, R.; Ito, Y.
    Organometallics     1995, 14, 4549-4558.
  201. Asymmetric Michael Reaction of an -Cyano Weinreb Amide Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP
    Sawamura, M.; Hamashima, H.; Shinoto, H.; Ito, Y.
    Tetrahedron Lett.     1995, 36, 6479-6482.
  202. Synthesis and Cellular Characterization of the Detransformation Agent, (-)-Depudecin
    Shimada, J.; Kwon, H. J.; Sawamura, M.; Schreiber, S. L.
    Chem. Biol.     1995, 2, 517-525.
  203. Asymmetric Hydrosilylation of Symmetrical Diketones Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP
    Kuwano, R.; Sawamura, M.; Shirai, J.; Takahashi, M.; Ito, Y.
    Tetrahedron Lett.     1995, 36, 5239-5242.
  204. Asymmetric Hydrosilylation of Keto Esters Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP
    Sawamura, M.; Kuwano, R.; Shirai, J.; Ito, Y.
    Synlett     1995, 347-348.
  205. Gold(I)-Catalyzed Asymmetric Aldol Reaction of an -Isocyano Weinreb Amide. An Efficient Synthesis of Optically Active -Hydroxy -Amino Aldehydes and Ketone
    Sawamura, M.; Nakayama, Y.; Kato, T.; Ito, Y.
    J. Org. Chem. 1995, 60, 1727-1732.
  206. Asymmetric Michael Reaction of -Cyano Carboxylates Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine PhTRAP
    Sawamura, M.; Hamashima, H.; Ito, Y.
    Tetrahedron     1994, 50, 4439-4454.
  207. Trans-Chelating Chiral Diphosphine Ligands Bearing Flexible P-Alkyl Substituents (AlkylTRAPs). An Application to Rhodium-Catalyzed Asymmetric Hydrosilylation of Simple Ketones
    Sawamura, M.; Kuwano, R.; Ito, Y.
    Angew. Chem. Int. Ed. Engl.     1994, 33, 111-113.
  208. Synthesis of Optically Active Ferrocene Analogues of Salicylic Acid Derivatives and Rhodium(II)-Catalyzed Asymmetric Intramolecular C-H Insertion of -Diazo -Keto Esters Using New Chiral Carboxylato Ligands
    Sawamura, M.; Sasaki, H.; Nakata, T.; Ito, Y.
    Bull. Chem. Soc. Jpn.     1993, 66, 2725-2729.
  209. Synthesis and Properties of a New Chiral Diphosphine Ligand Bearing a Cyclodextrin-Based Molecular Recognition Site and Its Palladium(II) Complex
    Sawamura, M.; Kitayama, K.; Ito, Y.
    Tetrahedron: Asymmetry     1993, 4, 1829-1832.
  210. Structure of (R)-1-[(S)-1′,2-Bis(diphenylphosphino)ferrocenyl]ethyl Acetate.
    Shawkataly, O. B.; Fun, H.-K.; Chinnakali, K.; Yip, B.-C.; Tooh, S.-G.; Ito, Y.; Sawamura, M.
    Acta Cryst. C.     1993, C49, 1898-1900.
  211. Structure of 1-[(R)-1′,2-Bis(diphenylphosphino)ferrocenyl]-(S)-N,N-dimethylethylamine
    Shawkataly, O. B.; Khalil, H.; Fun, H.-K.; Chinnakali, K.; Tooh, S.-G.; Ito, Y.; Sawamura, M.
    Acta Cryst. C.     1993, C49, 139-141.
  212. Catalytic Asymmetric Synthesis with Trans-Chelating Chiral Diphosphine Ligand TRAP: Rhodium-Catalyzed Asymmetric Michael Addition of α-Cyanocarboxylates
    Sawamura, M.; Hamashima, H.; Ito, Y.
    J. Am. Chem. Soc.     1992, 114, 8295-8296.
  213. Chiral Phosphine Ligands Functionalized by Crown Ethers: An Application to Palladium-Catalyzed Asymmetric Allylation of -Diketones
    Sawamura, M.; Nagata, H.; Sakamoto, H.; Ito, Y.
    J. Am. Chem. Soc.     1992, 114, 2586-2592.
  214. Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. 10: Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
    Hayashi, T.; Sawamura, M.; Ito, Y.
    Tetrahedron 1992, 48, 1999-2012.
  215. A Trans-Chelating Chiral Diphosphine Ligand: 2,2″-Bis[1-(diphenylphosphino)-ethyl]-1,1″-biferrocene and its Complexes with Platinum(II) and Palladium(II)
    Sawamura, M.; Hamashima, H.; Ito, Y.
    Tetrahedron: Asymmetry     1991, 2, 593-596.
  216. Synthesis of 2,2″-Bis(diphenylphosphino)-1,1″-biferrocene, a Planar Chiral Bisphosphine, and its Palladium(II) Complex
    Sawamura, M.; Yamauchi, A.; Takegawa, T.; Ito, Y.
    Chem. Commun.     1991, 874-875.
  217. The Asymmetric Aldol Reaction of Tosylmethyl Isocyanide and Aldehydes Catalyzed by Chiral Silver(I) Complexes
    Sawamura, M.; Hamashima, H.; Ito, Y.
    J. Org. Chem.     1990, 55, 5935-5936.
  218. Silver(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
    Hayashi, T.; Uozumi, Y.; Yamazaki, A.; Sawamura, M.; Hamashima, H.; Ito, Y.
    Tetrahedron Lett.     1991, 32, 2799-2802.
  219. NMR Studies of the Gold(I)-Catalyzed Asymmetric Aldol Reaction of Isocyanoacetate
    Sawamura, M.; Ito, Y.; Hayashi, T.
    Tetrahedron Lett.     1990, 31, 2723-2726.
  220. Asymmetric Aldol Reaction of -Ketoesters with Isocyanoacetate and Isocyanoacetamide Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
    Ito, Y.; Sawamura, M.; Hamashima, H.; Emura, T.; Hayashi, T.
    Tetrahedron Lett.     1989, 30, 4681-4684.
  221. Asymmetric Synthesis of (1-Aminoalkyl)phosphonic Acids via Asymmetric Aldol Reaction of (Isocyanomethyl)phosphonates Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
    Sawamura, M.; Ito, Y.; Hayashi, T.
    Tetrahedron Lett.     1989, 30, 2247-2250.
  222. Asymmetric Aldol Reaction of -Isocyanoacetamides with Aldehydes Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex Ito, Y.; Sawamura, M.; Kobayashi, M.; Hayashi, T.
    Tetrahedron Lett. 1988, 29, 6321-6324.
  223. Asymmetric Synthesis of -Hydroxy–alkylamino Acids by Asymmetric Aldol Reaction of -Isocyanocarboxylates Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes
    Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.
    Tetrahedron     1988, 44, 5253-5262.
  224. Asymmetric Synthesis of Threo– and Erythro-Sphingosines by Asymmetric Aldol Reaction of -Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
    Ito, Y.; Sawamura, M.; Hayashi, T.
    Tetrahedron Lett. 1988, 29, 239-240.
  225. Asymmetric Aldol Reaction of -Isocyanocarboxylates with Paraformaldehyde Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes: Catalytic Asymmetric Synthesis of -Alkylserines
    Ito, Y.; Sawamura, M.; Shirakawa, E.; Hayashizaki, K.; Hayashi, T.
    Tetrahedron Lett.     1988, 29, 235-238.
  226. Selective C-Alkylation of -Diketones
    Shono, T.; Kashimura, S.; Sawamura, M.; Soejima, T.
    J. Org. Chem. 1988, 53, 907-910.
  227. Asymmetric Aldol Reaction of an Isocyanoacetate with Aldehydes Catalyzed by Chiral Ferrocenylphosphine-Gold(I) Complexes
    Ito, Y.; Sawamura, M.; Hayashi, T.
    Tetrahedron Lett. 1987, 28, 6215-6218.
  228. Palladium-Catalyzed Allylation of -Isocyanocarboxylates
    Ito, Y.; Sawamura, M.; Matsuoka, M.; Matsumoto, Y.; Hayashi, T.
    Tetrahedron Lett.     1987, 28, 4849-4852.
  229. Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex
    Ito, Y.; Sawamura, M.; Hayashi, T.
    J. Am. Chem. Soc. 1986, 108, 6405-6406.
  230. Trimethylchlorosilane Induced Ring Opening of 2-Alkyloxazolidines to Enamine Derivatives
    Ito, Y.; Sawamura, M.; Kominami, K.; Saegusa, T.
    Tetrahedron Lett. 1985, 26, 5303-5306.
  231. New Systems for the Storage of Electricity Using Nitrile and Iodine as the Anodic Active Substances
    Shono, T.; Sawamura, M.; Kashimura, S.
    Chem. Commun.     1984, 1204-1205.

Reviews

  1. Continuous-Flow Catalysis Using Phosphine-Metal Complex on Porous Polymers: Designing Ligands, Pores, and Reactors
    Matsumoto, H.;Iwai, T.; Sawamura, M.; Miura, Y. ChemPlusChem, 2024, 89, accepted article, e202400039.
    DOI: 10.1002/cplu.202400039
  2. アリル化合物
    澤村正也
    有機合成化学協会誌，2023, 81, 828.
  3. フェノール-カルベン不斉配位子とエナンチオ選択的銅触媒反応の開発
    澤村正也
    有機合成化学協会誌，2023, 81, 774–786.
  4. 金との出会い
    澤村正也
    ドラマチック有機合成化学－感動の瞬間100、有機合成化学協会編，化学同人，2023, pp 124–125
  5. Boron Catalysis in the Transformation of Carboxylic Acids and Carboxylic Acid Derivatives 
    Sawamura, M.; Shimizu, Y.
    Eur. J. Org. Chem., 2023, 26, e202201249.
    DOI: 10.1002/ejoc.202201249
  6. ポリスチレン架橋ホスフィンに基づく不均一系遷移金属触媒の開発とフロー反応システムへの応用
    岩井智弘，三浦佳子，澤村正也
    THE CHEMICAL TIMES, 2022, 263, 12–16.
  7. Copper-Catalyzed Reactions of Alkylboranes
     Ohmiya, H.; Sawamura, M.
    Bull. Chem. Soc. Jpn., 2021, 94, 197–203.
    DOI: 10.1246/bcsj.20200283
  8. The Scope of 3-Acetyl-4-hydroxy-6-methyl-2H-pyran-2-one (DHA)
    Ghaith, E. A.; Zoorob, H. H.; Ibrahim, M. E.; Sawamura, M.; Hamama, W. S.
    Curr. Org. Chem., 2020, 24, 1459–1490.
    DOI: 10.2174/1385272824999200622114328
  9. Construction of Medium-Sized Rings by Gold Catalysis
    Reyes, R. L.; Iwai, T.; Sawamura, M.Chem. Rev., 2021, 121, 8926–8947. 
    DOI: 10.1021/acs.chemrev.0c00793
  10. Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin,     4-[[(1R)-2′-[(triisopropylsilyl)oxy][1,1′-binaphthalen]-2-yl]oxy]-, (11bR)-(9CI)Reyes, R. L.; Sawamura, M.
    Electronic Encyclopedia of Reagents for Organic Synthesis, Rovis T., Ed.; Wiley.
    http://onlinelibrary.wiley.com/doi/10.1002/047084289X.rn02326
  11. 5 anti Boron Addition to Alkynes
    Sawamura, M.; Ohmiya, H.In Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, Fernández, E., Ed.; Thieme: Stuttgart,; Chapter 5, pp 105-130 (2019).
    DOI: 10.1055/sos-SD-230-00048
  12. 固体表面を利用した配位子設計：活性サイトの孤立化に基づく高活性金属錯体触媒の開発
    岩井智弘，澤村正也
    触媒技術の動向と展望2019, 触媒学会（編）, 2019, 113–123.
  13. 配位子つくって３０年
    澤村正也
    OM News, 2018, 12–17.
  14. ナノと有機合成(巻頭言）
    澤村正也
    有機合成化学協会誌, 2016, 74, 581.
  15. 銅触媒の機能化に基づく高選択的合成反応の開発T
    大宮寛久・ 澤村正也
    月刊「化学工業」（特集「戦略的触媒開発と応用」)，2016, 67, pp 361– 366.
  16. Transition-metal-catalyzed Site-selective C–H Functionalization of Quinolines beyond C2 Selectivity.
    Iwai, T.; Sawamura, M.
    ACS Catal. 2015, 5, 5031–5040.
    DOI 10.1021/acscatal.5b01143
  17. Transition Metal Catalysis with Hollow-shaped Triethynylphosphine Ligands.
    Iwai, T.; Sawamura, M.
    Bull. Chem. Soc. Jpn. 2014, 87, 1147–1160. (Award Account)
    DOI: 10.1246/bcsj.20140186
  18. Copper-Catalyzed Allylic Substitution and Conjugate Addition with Alkylboranes.
    Ohmiya, H.; Sawamura, M.
     J. Synth. Org. Chem. Jpn.  2014, 72 (Special Issue in English), 1207–1217.
  19. Carbon–Boron and Carbon–Silicon Bond Formation.
    M. Sawamura, H. Ito, In Copper-Catalyzed Asymmetric Synthesis;
    A. Alexakis, N. Krause, S. Woodword, Ed.; Wiley-VCH: Weinheim, Chapter 6, pp 157–177, 2014.
  20. シリカ固定化かご型ホスフィンSilica-SMAPおよびSilica-TRIPに基づく有機合成触媒反応の開発．
    澤村正也
    和光純薬時報，82, pp 2-6, 2014.
  21. 不活性sp3-C–H結合の化学変換—触媒設計によるチャレンジ
     川守田創一郎・澤村正也
    化学，68, pp 72–73, 2013.
  22. Development of Heterogeneous Catalysts through Immobilization of Caged Phosphine Ligand SMAP
    Sawamura, M.
    Catalysts and Catalysis.     2010, 52, 249-254.
  23. γ位選択的ボリル化反応澤村正也・伊藤肇
    使える！有機合成反応２４１実践ガイド，丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著，化学同人，pp 314-315, 2010.
  24. γ位選択的アリル－アリール結成生成反応
    澤村正也
    使える！有機合成反応２４１実践ガイド，丸岡啓二・野崎京子・石井康敬・大寺純蔵・富岡清編著，化学同人，pp 164-165, 2010.
  25. Air-Stable, Compact, Caged Trialkylphosphines (SMAPs): Synthesis, Properties and Applications to Homogeneous and Heterogeneous Catalysis
    Sawamura, M.
    J. Synth. Org. Chem., Jpn. 2009, 67, 1125-1135.
  26. Copper-Catalyzed Substitution of Allylic Carbonates with Diboron: A New Approach to Allylboronate Synthesis
    Ito, H.; Ito, S.; Sasaki, Y.; Matsuura, K.; Sawamura, M.
    Pure Appl. Chem.     2008, 80, 1039-1045.
  27. Rhodium-Catalyzed Asymmetric Hydrogenation of Indoles.
    Kuwano, R.; Sawamura, M. In Catalysts for Fine Chemical Synthesis; Regio- and Stereo- Controlled Oxidations and Reductions
    Roberts, S. M., Whittall, J., Eds.; John Wiley & Sons: West Sussex, 2007; Vol. 5, p 73-86.
  28. Synthesis and Properties of SMAPs 1-Phospha-4-silabicyclo[2.2.2]octane Derivatives
    Ochida, A.; Sawamura, M.
    ARKIVOC 2006, 359-369.
  29. L-プロリン触媒を用いる不斉アルドール反応
    澤村正也
    有機合成のための触媒反応１０３，檜山為次郎・野崎京子編，東京化学同人，pp 90-91, 2004.
  30. 遷移金属錯体を用いるアルドール反応
    澤村正也
    有機合成のための触媒反応１０３，檜山為次郎・野崎京子編，東京化学同人，pp 88-89, 2004.
  31. 金(Au)
    澤村正也・伊藤肇有機金属反応剤ハンドブック－3Liから83Biまで，玉尾皓平編著，化学同人，pp 243-245, 2003.
  32. 有機フラーレンの形作る超分子構造－膜と液晶－
    中村栄一・松尾豊・磯部寛之・澤村正也
    未来材料, 2003, 3, 6-12.
  33. 銅(I)ヒドリド錯体の触媒作用における不斉配位子加速効果
    澤村正也
    Organometallic News, 2002, 15.
  34. Chemistry of 5-Fullerene Metal Complexes.
    E. Nakamura, M. Sawamura
    Pure Appl. Chem.    , 2001, 73, 355-359.
  35. フラーレン類の反応-化学修飾と機能分子設計
    中村栄一・澤村正也・磯部寛之
    季刊化学総説「炭素第三の同素体フラーレンの化学」，日本化学会編，学会出版センターVol.４３, chapter III-13, pp 165-171, 1999.
  36. Silver and Gold Reagents.
    M. Sawamura, In Lewis Acid reagents: A Practical Approach
    H. Yamamoto, Ed.; Oxford University Press.: Oxford, chapter 9, pp 169-176, 1999.
  37. Fullerene That Binds a Metal on the Pentagon.
    E. Nakamura, M. Sawamura, H. Iikura, S. Mori
    Proc. Electrochem. Soc. 97-14 (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials) 1997, 97-14, 298-308
  38. 金－α-イソシアノカルボン酸類の不斉アルドール反応
    澤村正也
    季刊化学総説「金属反応剤を用いる不斉化学合成」，日本化学会編，学会出版センターVol. 19, chapter 11, pp 129-141, 1993.
  39. Asymmetric Aldol Reaction.
    M. Sawamura, Y. Ito, In Catalytic Asymmetric SynthesisI. Ojima, Ed.; VCH, Publishers, Inc.: New York, Chapter 7, pp 367-388, 1993.
  40. Catalytic Asymmetric Synthesis by Means of Secondary Interaction between Chiral Ligands and Substrates.
    M. Sawamura, Y. Ito
    Chem. Rev.    , 1992, 92, 857-871.

Environment and Safety

  1. 化学物質管理システム運用に関する課題整理と管理システム診断マップの開発
    川上貴教・中村修・藤井邦彦・中山政勝・榊原洋子・澤村正也環境と安全, 3, pp 175–185, 2016
  2. Manegement of Chemicals for Safety and Education in Laboratory
    T. Kinoshita, K. Tonokura, I. Shibata, E. Yamada, S. Murata, M. Matsumoto, M. Sawamura, H. Nakagawa, K. Morimoto, A. Koyama
    Journal of Environment and Safety    , 2015, 6, 81-84.
  3. 北海道大学における動物実験実施者等の実験動物への感作状況
    吉村彩・武蔵学・金子壮郎・大西俊介・折戸智恵子・川原由佳子・橋野聡・森松正美・今野哲・有川二郎・石井哲也・澤村正也・上田一郎アレルギー, 63, pp 1132-11398, 2014
  4. かけがえのないもののために（巻頭言）
    澤村 正也北海道大学環境保全センター報, 16, 1, 2007
  5. 北海道大学化学物質管理システムの運用について
    江見清次郎・宮北貴志・澤村正也北海道大学環境保全センター報, 15, pp 12-15, 2006

北海道大学大学院 理学研究院 化学部門

有機金属化学研究室

〒060-0810札幌市北区北10条西8丁目
北海道大学理学部6号館

Organometallic Chemistry Lab.

Division of Chemistry, Graduate School of Science, Hokkaido University

Kita 10 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-0810, Japan

Copyright © Organometallic Chemistry Lab.
トップへ戻るボタン