研究成果
原著論文
2024年
[8] B. Wang, T. Fukushima, H. Minamimoto, A. Lyalin, K. Murakoshi, T. Taketsugu
“Directing the Electrode-Electrolyte Interface Towards Active Nickel-Based Electrocatalysts for Oxygen Evolution Reaction"
arXiv (2024)
DOI: 10.48550/arXiv.2410.16715
[7] T. Fukushima, K. Tsuchimoto, N. Oyamada, D. Sato, H. Minamimoto and K. Murakoshi
“Raman Spectroscopic Observation of Electrolyte-Dependent Oxygen Evolution Reaction Intermediates in Nickel-Based Electrodes"
J. Phys. Chem. C, accepted (2024)
DOI: 10.1021/acs.jpcc.4c06732
[6] T. Hayashi, T. Fukushima, and K. Murakoshi
“Role of Cavity Strong Coupling on Single Electron Transfer Reaction Rate at Electrode-Electrolyte Interface"
J. Chem. Phys. 161, 181101 (2024)
DOI : 10.1063/5.0231477
Special topic on "Polaritonics for Next Generation Materials"
[5] D. Sato, N. Oyamada T. Fukushima, and K. Murakoshi
“Evaluation of Hydrogen Evolution Activity by Bubbles Growth Rates as Descriptor"
J. Electroanal. Chem. , 973(15) (2024).
DOI : 10.1016/j.jelechem.2024.118667
Free access
[4] T. Watanabe, K. Tsuchimoto, T. Fukushima, K. Murakoshi, M. Mizuhata, H. Minamimoto
“Preparations of Fluorine-doped α-Ni Hydroxides as Alkaline Water Electrolysis Catalysts via Liquid Phase Deposition Method"
Sustainable Energy & Fuels (2024) in press.
DOI : 10.1039/D4SE00983E
[3] R. Zhou
“Calculation of the Characteristic X-ray Lines with Slater’s Rules for a Better Understanding of Quantum Transition and Moseley’s Law"
J. Chem. Educ. 101(8), 3326 - 3332 (2024).
DOI: 10.1021/acs.jchemed.4c00396
[2] Y. Tajiri, D. Sato, M. Tomisaki, K. Murakoshi, Y. Einaga, M. Mizuhata, and H. Minamimoto
“Clarifications of Electrochemical Potential of Excited Electrons on Visible-Light Response Plasmonic Cathode Electrodes"
J. Phys. Chem. C, 128(30), 12339 - 12345 (2024).
DOI: https://doi.org/10.1021/acs.jpcc.4c03271
[1] D. Ashizawa, M. Itatani, T. Fukushima, and K. Murakoshi
“Enhanced Electrochemical Oxygen Evolution Reaction Enabled by Ni Cavity-Arrayed Electrodes"
ChemRxiv (2024)
DOI: https://doi.org/10.26434/chemrxiv-2024-cb2sk
2023年
[3] T. Fukushima, S. Yoshimitsu, K. Murakoshi
“Unlimiting Ionic Conduction: Manipulating Hydration Dynamics through Vibrational Strong Coupling of Water"
Chem. Sci. 14, 11441-11446 (2023).
DOI: 10.1039/D3SC03364C
[2] T. Fukushima, M. Fukasawa, K. Murakoshi
“Unveiling the Hidden Energy Profiles of the Oxygen Evolution Reaction via Machine Learning Analyses"
J. Phys. Chem. Lett. 14, 30, 6808-6813 (2023).
DOI: 10.1021/acs.jpclett.3c01596
[1] T. Hayashi, H. Minamimoto, K. Murakoshi
“Understanding Spatial Distributions of Dye Molecules Coupled to Surface Lattice Resonance Mode through Electrochemical Reaction Control"
J. Phys. Chem. Lett. 14, 2268-2276 (2023).
DOI: 10.1021/acs.jpclett.2c03442
2022年
[5] T. Fukushima, S. Yoshimitsu, K. Murakoshi
“Inherent Promotion of Ionic Conductivity via Collective Vibrational Strong Coupling of Water with the Vacuum Electromagnetic Field"
J. Am. Chem. Soc. 144, 27, 12177-12183 (2022).
DOI: 10.1021/jacs.2c02991
[4] T. Fukushima, D. Ashizawa, K. Murakoshi
“Rapid Detection of Donor-dependent Photocatalytic Hydrogen Evolution by NMR Spectroscopy"
RSC Adv., 12, 12967-12970 (2022).
DOI: 10.1039/d2ra01676a
[3] C. Kojima, A. Noguchi, T. Nagai, K. Yuyama, S. Fujii, K. Ueno, N. Oyamada, K. Murakoshi, T. Shoji, Y. Tsuboi
“Generation of Ultralong Liposome Tubes by Membrane Fusion Beneath a Laser-Induced Micro Bubble on Gold Surfaces"
ACS Omega, 7(15) 13120-13127 (2022).
DOI: 0.1021/acsomega.2c00553
[2] N. Oyamada, H. Minamimoto, K. Murakoshi
“Room-Temperature Molecular Manipulation via Plasmonic Trapping at Electrified Interfaces"
J. Am. Chem. Soc. 144, 2755 (2022).
DOI: 10.1021/jacs.1c12213
[1] S. Oikawa, H. Minamimoto, K. Murakoshi
“Low-Temperature Annealing of Plasmonic Metal Arrays for Improved Light Confinement"
J. Phys. Chem. C 126, 1188 (2022).
DOI: 10.1021/acs.jpcc.1c08931
* Invited paper for virtual special issue “Marie-Paule Pileni Festschrift"
2021年
[6] T. Fukushima, S. Yoshimitsu, K. Murakoshi
“Vibrational Coupling of Water from Weak to Ultrastrong Coupling Regime via Cavity Mode Tuning"
J. Phys. Chem. C, 125, 25832-25840 (2021).
DOI: 10.1021/acs.jpcc.1c07686
* Invited paper for virtual special issue “125 Years of The Journal of Physical Chemistry"
[5] K. Suzuki, X. Li, T. Toda, F. Nagasawa, K. Murakoshi
"Plasmon-Accelerated Water Oxidation at Ni-Modified Au Nanodimers on TiO2 Single Crystals"
ACS Energy Lett. 6, 4374-4382 (2021).
DOI: 10.1021/acsenergylett.1c02163
[4] T. Fukushima, H. Hasebe, K. Murakoshi
“Theoretical Study on Proton Permeation Ability of Modified Single-Layer Graphene"
Chem. Lett., 50, 1604-1606 (2021).
DOI: 10.1246/cl.210285
[3] T. Heiderscheit, S. Oikawa, S. Sanders, H. Minamimoto, E. Searles, C. Landes, K. Murakoshi, A. Manjavacas, S. Link
“Tuning Electrogenerated Chemiluminescence Intensity Enhancement Using Hexagonal Lattice Arrays of Gold Nanodisks"
J. Phys. Chem. Lett., 12, 2516–2522 (2021).
DOI: 10.1021/acs.jpclett.0c03564
[2] H. Minamimoto, T. Toda, K. Murakoshi
“Spatial Distribution of Active Sites for Plasmon-Induced Chemical Reactions Triggered by Well-Defined Plasmon Modes"
Nanoscale, 13, 1784-1790 (2021).
DOI: 10.1039/D0NR07958H
[1] H. Minamimoto, F. Kato, K. Murakoshi
“Surface-Enhanced Raman Scattering Probe for Molecules Strongly Coupled with Localized Surface Plasmon under Electrochemical Potential Control"
Journal of Raman Spectroscopy, 52, 431-438 (2021). (invited paper)
DOI: 10.1002/jrs.6004
2020年
[9] Y. Wang, H. Minamimoto, R. Zhou, K. Murakoshi
“In-situ Monitoring of Electronic Structure in Modal Strong Coupling Electrode under Enhanced Plasmonic Water Oxidation"
J. Phys. Chem. C, 125, 1754-1760 (2020).
DOI: 10.1021/acs.jpcc.0c10088
[8] S. Naka, T. Shoji, S. Fujii, K. Ueno, Y. Wakisaka, K. Murakoshi, T. Mizoguchi, H. Tamiaki, Y. Tsuboi
“Thermo-Plasmonic Trapping of Living Cyanobacteria on a Gold Nanopyramidal Dimer Array: Implications for Plasmonic Biochips"
ACS Appl. Nano Mater., 3, 10067-10072 (2020).
DOI: 10.1021/acsanm.0c02071
[7] X. Shi, X. Li, T. Toda, T. Oshikiri, K. Ueno, K. Suzuki, K. Murakoshi, H. Misawa
“Interfacial Structure Modulated Plasmon-Induced Water Oxidation on Strontium Titanate”
ACS Applied Energy Materials, 3, 5675-5683 (2020).
DOI: 10.1021/acsaem.0c00648
[6] S. Oikawa, H. Minamimoto, A. Ohnuki, K. Murakoshi
“Ultra-Fine Electrochemical Tuning of Hybridized Plasmon Modes for Ultimate Light Confinement”
Nanoscale, 12, 11593-11600 (2020).
DOI: 10.1039/D0NR02218G
[5] D. Sato, H. Minamimoto, K. Murakoshi
“Plasmon-Induced Hydrogen Evolution Reaction on p-Type Semiconductor Electrode with Ag Nanodimer Structures”
Chem. Lett., 49, 806-808 (2020).
DOI: 10.1246/cl.200259
[4] K. Suzuki, X. Li, Y. Wang, F. Nagasawa, K. Murakoshi
“Active Intermediates in Plasmon-Induced Water Oxidation at Au Nanodimer Structures on a Single Crystal of TiO2”
ACS Energy Letters, 5, 1252-1259 (2020).
DOI: 10.1021/acsenergylett.0c00478
[3] T. Fukushima, A. Miyauchi, N. Oyamada, H. Minamimoto, T. Motegi, K. Murakoshi
“Visualization of Molecular Trapping at Plasmonic Metal Nanostructure by Surface-Enhanced Raman Scattering Imaging”
J. Nanophotonics, 14, 026001(1-11) (2020).
DOI: 10.1117/1.JNP.14.026001
[2] H. Minamimoto, K. Yasuda, R. Zhou, X. Li, S. Yasuda, K. Murakoshi
“Potential Energy Shift of the Fermi Level at Plasmonic Structures for Light-Energy Conversion Determined by Graphene-Based Raman Measurements”
J. Chem. Phys., 152, 124702(1-10) (2020).
DOI: 10.1063/1.5143560
[1] T. Shoji, K. Itoh, J. Saitoh, N. Kitamura, T. Yoshii, K. Murakoshi, Y. Yamada, T. Yokoyama, H. Ishihara, Y. Tsuboi
“Plasmonic Manipulation of DNA using a Combination of Optical and Thermophoretic Forces: Separation of Different-Sized DNA from Mixture Solution”
Scientific Reports, 10, 3349, 1-10 (2020).
DOI: 10.1038/s41598-020-60165-5
2019年
[8] J. Zhang, R. Zhou, S. Yasuda, H. Minamimoto, K. Murakoshi
"Nonzero Wavevector Excitation of Graphene by Localized Surface Plasmon"
Nano Lett. 19 (11), 7887-7894 (2019)
DOI : 10.1021/acs.nanolett.9b02947
[7] N. Oyamada, H. Minamimoto, K. Murakoshi
“In-situ Observation of Unique Bi-analyte Molecular Behaviors at the Gap of A Single Metal Nanodimer Structure via Electrochemical Surface-Enhanced Rama Scattering Measurements”
J. Phys. Chem. C, 123, 40, 24740-24745 (2019).
DOI: 10.1021/acs.jpcc.9b07361
Selected as Cover Art of the Issue.
[6] X. Li, P. D. McNaughter, P. O'Brien, H. Minamimoto, K. Murakoshi
“Photoelectrochemical Formation of Polysulfide at PbS QD-Sensitized Plasmonic Electrodes”
J. Phys. Chem. Lett. 10, 5357-5363 (2019).
DOI: 10.1021/acs.jpclett.9b02045
[5] N. Oyamada, H. Minamimoto, Y. Wakisaka, K. Murakoshi
“Determination of Molecular Orientation in Bi-analyte Mono-molecule Layer through Electrochemical Surface-Enhanced Raman Scattering Measurements”
Chem. Lett. 48, 820-823 (2019).
DOI: 10.1246/cl.190282
[4] J. Zhang, R. Zhou, H. Minamimoto, K. Murakoshi
“Plasmon-induced Metal Restructuring and Graphene Oxidation Monitored by Surface-enhanced Raman Spectroscopy”
Applied Materials Today, 15, 372-376 (2019).
DOI: 10.1016/j.apmt.2019.02.018
[3] H. Minamimoto, R. Osaka, K. Murakoshi
“In-situ Observation of Isotopic Hydrogen Evolution Reactions using Electrochemical Mass Spectroscopy to Evaluate Surface Morphological Effect”
Electrochimica Acta, 304, 87-93 (2019).
DOI: 10.1016/j.electacta.2019.02.088
* Special Issue of 22nd Topical ISE Meeting in Tokyo
[2] J. Kim, T. Fukushima, R. Zhou, K. Murakoshi
“Revealing High Oxygen Evolution Catalytic Activity of Fluorine-Doped Carbon in Alkaline Media”
Materials, 12, 211 (1-8) (2019).
DOI: 10.3390/ma12020211
[1] T. Fukushima, K. Yasuda, H. Hasebe, R. Zhou, H. Minamimoto, K. Murakoshi
“Modulation of Graphene/Au(111) Interaction by Electrocatalytic Hydrogen Evolution Reaction”
J. Phys.: Conf. Ser., 1220(1), 012016 (2019). 【Proceeding for EXCON 2018】
DOI: 10.1088/1742-6596/1220/1/012016
2018年
[8] J. Zhang, H. Minamimoto, S.Oikawa, T. Toda, X. Li, K. Murakoshi
“Thermal Effect on Plasmon-Induced Electron Transfer System under Intense Pulsed Laser Illumination”
Chem. Lett., 47, 953-955 (2018).
DOI: 10.1246/cl.180354
[7] H. Minamimoto, S. Oikawa, T. Hayashi, A. Shibazaki, X. Li, K. Murakoshi
“Electrochemical Fine Tuning of the Plasmonic Properties of Au Lattice Structures”
J. Phys. Chem. C, 122(25), 14162-14167 (2018).
DOI: 10.1021/acs.jpcc.8b01495
*Invited paper for Prashant V. Kamat Festschrift issue
[6] X. Li, P.D. McNaughter, P. O'Brien, H. Minamimoto, K. Murakoshi
“Plasmonically Enhanced Electromotive Force of Narrow Band Gap Quantized PbS Dots Based Photovoltaics”
Phys. Chem. Chem. Phys., 20, 14818-14827 (2018).
DOI: 10.1039/C8CP00767E
[5] J. Kim, R. Zhou, K. Murakoshi, S. Yasuda
“Advantage of Semi-ionic Bonding in Fluorine-doped Carbon Materials for the Oxygen Evolution Reaction in Alkaline Media”
RSC Adv., 8, 14152-1416 (2018).
DOI: 10.1039/c8ra01636d
[4] R. Zhou, S. Yasuda, H. Minamimoto, K. Murakoshi
“Sensitive Raman Probe of Electronic Interaction between Monolayer Graphene and Substrate under Electrochemical Potential Control”
ACS Omega, 3(2), 2322–2328 (2018).
DOI: 10.1021/acsomega.7b01928
[3] X. Li, H. Minamimoto, K. Murakoshi
“Electrochemical Surface-Enhanced Raman Scattering Measurement on Ligand Capped PbS Quantum Dots at Gap of Au Nanodimer”
Spectrochim. Acta, Part A, 197, 244-250 (2018).
DOI: 10.1016/j.saa.2018.02.020
[2] F. Kato, H. Minamimoto, F. Nagasawa, Y. Yamamoto, T. Itoh, K. Murakoshi
“Active Tuning of Strong Coupling States between Dye Excitons and Localized Surface Plasmons via Electrochemical Potential Control”
ACS Photon., 5(3), 788-796 (2018).
DOI: 10.1021/acsphotonics.7b00841
[1] S. Oikawa, H. Minamimoto, X. Li, K. Murakoshi
“Nanoscale Control of Plasmon-active Metal Nanodimer Structures via Electrochemical Metal Dissolution Reaction”
Nanotechnol., 29(4), 045702 (2018).
DOI: 10.1088/1361-6528/aa9e78
2017年
[7] S. Yasuda, T. Yoshii, S. Chiashi, S. Maruyama, K. Murakoshi
“Plasmon-Induced Selective Oxidation Reaction at Single-Walled Carbon Nanotubes”
ACS Appl. Mater. Interfaces, 9(44), 38992-38998 (2017).
DOI: 10.1021/acsami.7b07636
[6] S. Yasuda, R. Takahashi, R. Osaka, R. Kumagai, Y. Miyata, S. Okada, Y. Hayamizu, K. Murakoshi
“Out-of-Plane Strain Induced in a Moiré Superstructure of Monolayer MoS2 and MoSe2 on Au(111)”
Small, 13(31), 1700748-1-1700748-8 (2017).
DOI: 10.1002/smll.201700748
[5] A. Mototsuji, T. Shoji, Y. Wakisaka, K. Murakoshi, H. Yao, Y. Tsuboi
“Plasmonic Optical Trapping of Nanometer-Sized J- /H- Dye Aggregates as Explored by Fluorescence Microspectroscopy”
Opt. Expr., 25(12), 13617-13625 (2017).
DOI: 10.1364/OE.25.013617
[4] S. Oikawa, H. Minamimoto, K. Murakoshi
“Reversible Electrochemical Tuning of Optical Property of Single Au Nano-bridged Structure via Electrochemical Under Potential Deposition”
Chem. Lett., 46(8), 1148-1150 (2017).
DOI: 10.1246/cl.170427
[3] H. Minamimoto, F. Kato, F. Nagasawa, M. Takase, K. Murakoshi
“Electrochemical Control of Strong Coupling States Between Localized Surface Plasmons and Molecule Excitons for Raman Enhancement”
Faraday Discuss., 205, 261-269 (2017).
DOI: 10.1039/C7FD00126F
[2] Y. Yonezawa, H. Minamimoto, F. Nagasawa, M. Takase, S. Yasuda, K. Murakoshi
“In-situ Electrochemical Surface-Enhanced Raman Scattering Observation of Molecules Accelerating the Hydrogen Evolution Reaction”
J. Electroanal. Chem., 800, 7-12 (2017).
DOI: 10.1016/j.jelechem.2017.04.049
※Special issue for Prof. M. Osawa.
[1] T. Shoji, D. Sugo, F. Nagasawa, K. Murakoshi, N. Kitamura, Y. Tsuboi
“Highly Sensitive Detection of Organic Molecules on the Basis of a Poly(N‑isopropylacrylamide) Microassembly Formed by Plasmonic Optical Trapping”
Anal. Chem., 89(1), 532-537 (2017).
DOI: 10.1021/acs.analchem.6b04024
2016年
[5] S. Yasuda, S. Hoshina, S. Chiashi, S. Maruyama, K. Murakoshi
“Electronic Structure Characterization of Individual Single-Walled Carbon Nanotube by in-situ Electrochemical Surface-Enhanced Raman Scattering Spectroscopy”
Nanoscale, 8(45), 19093-19098 (2016).
DOI: 10.1039/c6nr05209f
[4] H. Minamimoto, T. Toda, R. Futashima, X. Li, K. Suzuki, S. Yasuda, K.Murakoshi
“Visualization of Active Sites for Plasmon-Induced Electron Transfer Reactions using Photoelectrochemical Polymerization of Pyrrole”
J. Phys. Chem. C, 120(29), 16051-16058 (2016).
DOI: 10.1021/acs.jpcc.5b12727
[3] S. Yasuda, A. Furuya, Y. Uchibori, J. Kim, K. Murakoshi
“Iron-Nitrogen-Doped Vertically Aligned Carbon Nanotube Electrocatalyst for the Oxygen Reduction Reaction”
Adv. Funct. Mater., 26(5), 738-744 (2016).
DOI: 10.1002/adfm.201503613
[2] S. Sato, K. Murakoshi, K. Ikeda
“Photoelectrochemical Behavior of Homo- and Hetero-Dimers of Metalloporphyrins”
Chem. Lett., 45(2), 125-127 (2016).
DOI: 10.1246/cl.151001
[1] S. Sato, K. Namba, K. Hara, A. Fukuoka, K. Murakoshi, K. Uosaki, K. Ikeda
“Kinetic Behavior of Catalytic Active Sites Connected with a Conducting Surface Through Various Electronic Coupling”
J. Phys. Chem. C, 120(4), 2159-2165 (2016).
DOI: 10.1021/acs.jpcc.5b09364
2015年
[5] X. Li, K. Suzuki, T. Toda, S. Yasuda, K. Murakoshi
“Plasmonic Enhancement of Photoenergy Conversion in Visible Light Region Using PbS Quantum Dots Coupled with Au Nanoparticles”
J. Phys. Chem. C, 119, 22092-22101 (2015).
DOI: 10.1021/acs.jpcc.5b04693
[4] S. Yasuda, R. Kumagai, K. Nakashima, K. Murakoshi
“Electrochemical Potential Stabilization of Reconstructed Au(111) Structure by Monolayer Coverage with Graphene”
J. Phys. Chem. Lett., 6, 3403-3409 (2015).
DOI: 10.1021/acs.jpclett.5b01488
[3] K. Ueno, T. Oshikiri, K. Murakoshi, H. Inoue, H. Misawa
“Plasmon-Enhanced Light Energy Conversion using Gold Nanostructured Oxide Semiconductor Photoelectrodes”
Pure Appl. Chem., 87(6), 547-555 (2015).
DOI: 10.1515/pac-2014-1120
[2] J. Kim, A. Shawky, S. Yasuda, K. Murakoshi
“Selective Synthesis of Graphitic Carbon and Polyacetylene by Electrochemical Reduction of Halogenated Carbons in Ionic Liquid at Room Temperature”
Electrochim. Acta, 176, 388-393 (2015).
DOI: 10.1016/j.electacta.2015.06.144
[1] K. Ikeda, S. Uchiyama, M. Takase, K. Murakoshi
“Hydrogen-Induced Tuning of Plasmon Resonances in Palladium-Silver Layered Nanodimer Arrays”
ACS Photon., 2(1), 66-72 (2015).
DOI: 10.1021/ph500242c
2014年
[6] S. Yasuda, A. Furuya, K. Murakoshi
“Control of Two-Dimensional Molecular Structure by Cooperative Halogen and Hydrogen Bonds”
RSC Adv., 4(102), 58567-58572 (2014).
DOI: 10.1039/c4ra10235e- [5] T. Motegi, B. Takimoto, H. Nabika, Kei Murakoshi
“Molecule Manipulation at Electrified Interfaces Using Metal Nanogates”
Electrochem., 82(9), 712-719 (2014).
DOI: 10.5796/electrochemistry.82.712 
[4] T. Motegi, H. Nabika, Y. Fu, L. Chen, Y. Sun, J. Zhao, K. Murakoshi
“Effective Brownian Ratchet Separation by a Combination of Molecular Filtering and a Self-Spreading Lipid Bilayer System”
Langmuir, 30 (25), 7496-7501 (2014).
DOI: 10.1021/la500943k
[3] Y. Zhong, K. Ueno, Y. Mori, X. Shi, T. Oshikiri, K. Murakoshi, H. Inoue, H. Misawa
“Plasmon-Assisted Water Splitting Using Two Sides of the Same SrTiO3 Single-Crystal Substrate: Conversion of Visible Light to Chemical Energy”
Angew. Chem., Int. Ed., 53(39), 10350-10354 (2014).
DOI: 10.1002/anie.201404926
[2] T. Suzuki, Y. Uchimura, F. Nagasawa, T. Takeda, H. Kawai, R Katoono, K. Fujiwara, K. Murakoshi, T. Fukushima, A. Nagaki, J. Yoshida
“Expandability of Ultralong C–C Bonds: Largely Different C1–C2 Bond Lengths Determined by Low-Temperature X-Ray Structural Analyses on Pseudopolymorphs of 1,1-Bis(4-fluorophenyl)-2,2-bis(4-methoxyphenyl)pyracene.”
Chem. Lett., 43(1), 86-88(2014).
DOI: 10.1246/cl.130872
[1] F. Nagasawa, M. Takase, K. Murakoshi
“Raman Enhancement via Polariton States Produced by Strong Coupling Between Localized Surface Plasmon and Dye Excitons at Metal Nano-Gap”
J. Phys. Chem. Lett., 5, 14-19 (2014).
DOI: 10.1021/jz402243a